The stable shapes and structure formation in prestretched threads of a weak soft polymer gel with permanent cross-links under the action of capillary forces are studied theoretically here. Two cases are considered: when the thread is formed from a drop of gel located between the surfaces after they are moved apart and when it is fixed at the ends. In the first case, we identified three stages of the thread relaxation, characterized by highly different times and associated with the formation of the filament, its lateral compression accompanied by the release of solvent at its surface, and diffusion of the solvent to the terminal droplets. A general linear stability analysis is carried out for threads of any diameter and degree of prestretch, taking into account the effects of elasticity, interactions and inertia, and the corresponding dispersion relations are obtained. The thermodynamically stable beads-on-a-string structures are studied as well and a diagram of the state of the gel thread is presented. It reveals several regimes of different internal structures of gel threads along with phase transitions between them.
Skip Nav Destination
Article navigation
March 2025
Research Article|
February 11 2025
Capillary instability of a stretched polymer gel thread
Andrey V. Subbotin
;
Andrey V. Subbotin
a)
a)Author to whom correspondence should be
addressed; electronic mail: [email protected]
Search for other works by this author on:
Alexander N. Semenov
Alexander N. Semenov
3
Institut Charles Sadron, CNRS-UPR
22, Universite de Strasbourg
, 23 rue du Loess, BP 84047, 67034
Strasbourg Cedex 2, France
Search for other works by this author on:
a)Author to whom correspondence should be
addressed; electronic mail: [email protected]
J. Rheol. 69, 159–181 (2025)
Article history
Received:
July 07 2024
Accepted:
January 22 2025
Citation
Andrey V. Subbotin, Alexander N. Semenov; Capillary instability of a stretched polymer gel thread. J. Rheol. 1 March 2025; 69 (2): 159–181. https://doi.org/10.1122/8.0000898
Download citation file:
Pay-Per-View Access
$40.00
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
93
Views
Citing articles via
Linear viscoelasticity of nanocolloidal suspensions from probe rheology molecular simulations
Dinesh Sundaravadivelu Devarajan, Rajesh Khare
Dilatancy and pressures in suspensions
Jeffrey F. Morris
Normal stress rheometry of polymer melts with partitioned plate fixtures
Benke Li, Antonios Mavromanolakis, et al.
Related Content
Wave propagation in prestretched polymer nanofibers
J. Appl. Phys. (January 2010)
Improved electromechanical behavior in castable dielectric elastomer actuators
Appl. Phys. Lett. (February 2013)
Propagation of fundamental Lamb modes along the non-principal axes of strain-stiffened soft compressible plates: A numerical investigation
J. Acoust. Soc. Am. (February 2023)
A novel electro-active bushing based on dielectric elastomer and circular double-V auxetic structure
AIP Advances (December 2019)
Stretchable wavy metal interconnects
J. Vac. Sci. Technol. A (July 2004)