We develop a two-stage computational method to assimilate linear viscoelastic material functions (LMFs), viz., stress relaxation modulus, creep compliance, and the complex modulus, by inferring a consensus discrete relaxation spectrum (DRS) that simultaneously fits all three LMFs. In the first stage, the DRS corresponding to the different LMFs is deduced independently, before they are combined heuristically to generate an initial guess for the consensus DRS. In the second stage, this initial guess is refined using nonlinear least squares regression. The effectiveness of this method for data fusion and validation is demonstrated by analyzing experimental data collected on two different polymer melt systems. We also investigate the performance of the method when the timescales probed by the LMFs do not overlap, or are limited to 4–6 decades, as is typically the case for thermorheologically complex materials. To explore these questions, we generate synthetic datasets by obscuring information from one of the experimental datasets. We find that the computational protocol works quite well. As expected, the quality of the inferred DRS is marginally impaired because information is suppressed.
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January 2025
Research Article|
November 14 2024
Assimilation of linear viscoelastic measurements by joint inference of relaxation spectrum
Sachin Shanbhag
;
Sachin Shanbhag
a)
1
Department of Scientific Computing, Florida State University
, Tallahassee, Florida 32306a)Author to whom correspondence should be addressed; electronic mail: sshanbhag@fsu.edu
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Ralm G. Ricarte
;
Ralm G. Ricarte
b)
2
Department of Chemical and Biomedical Engineering, Florida A&M University-Florida State University College of Engineering
, Tallahassee, Florida 32310
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Dana Ezzeddine
;
Dana Ezzeddine
2
Department of Chemical and Biomedical Engineering, Florida A&M University-Florida State University College of Engineering
, Tallahassee, Florida 32310
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Daniel Barzycki
Daniel Barzycki
2
Department of Chemical and Biomedical Engineering, Florida A&M University-Florida State University College of Engineering
, Tallahassee, Florida 32310
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a)Author to whom correspondence should be addressed; electronic mail: sshanbhag@fsu.edu
b)
Electronic mail: rricarte@eng.famu.fsu.edu
J. Rheol. 69, 1–14 (2025)
Article history
Received:
May 03 2024
Accepted:
October 21 2024
Citation
Sachin Shanbhag, Ralm G. Ricarte, Dana Ezzeddine, Daniel Barzycki; Assimilation of linear viscoelastic measurements by joint inference of relaxation spectrum. J. Rheol. 1 January 2025; 69 (1): 1–14. https://doi.org/10.1122/8.0000869
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