We perform experiments on jammed suspensions of microgels with different constituent properties to determine their stress relaxation behavior on flow cessation. We observe that the stress relaxes through a two-step process: A rapid initial relaxation where internal stresses are trapped followed by a much slower decay. Trapped internal stresses are related to the solvent viscosity, particle elasticity, and volume fraction through a universal scaling. The second slower relaxation of the internal stress is characterized by a single exponential decay, which is independent of the preshear stress and relatively insensitive to the material properties of the microgel suspension. Particle-scale simulations are used to understand the microscopic mechanisms which drive the amplitude and the kinetics of the stress relaxation as well as the local particle dynamics in each regime. The rapid initial relaxation occurs through ballistic particle motion, where the number of contacts and average compression return to their static values but the asymmetry of the pair distribution function remains as a signature of the internal stress.

1.
Abraham
,
S.
, and
P.
Harrowell
, “
The origin of persistent shear stress in supercooled liquids
,”
J. Chem. Phys.
137
,
014506
(
2012
).
2.
Ballauff
,
M.
,
J. M.
Brader
,
S. U.
Egelhaaf
,
M.
Fuchs
,
J.
Horbach
,
N.
Koumakis
,
M.
Krüger
,
M.
Laurati
,
K. J.
Mutch
,
G.
Petekidis
,
M.
Siebenbürger
,
Th.
Voigtmann
, and
J.
Zausch
, “
Residual stresses in glasses
,”
Phys. Rev. Lett.
110
,
215701
(
2013
).
3.
Bandyopadhyay
,
R.
,
D.
Liang
,
H.
Yardimci
,
D. A.
Sessoms
,
M. A.
Borthwick
,
S. G. J.
Mochrie
,
J. L.
Harden
, and
R. L.
Leheny
, “
Evolution of particle-scale dynamics in an aging clay suspensions
,”
Phys. Rev. Lett.
93
,
228302
(
2004
).
4.
Bandyopadhyay
,
R.
,
P. H.
Mohan
, and
Y. M.
Joshi
, “
Stress relaxation in aging soft colloidal glasses
,”
Soft Matter
6
,
1462
1466
(
2010
).
5.
Bonnecaze
,
R. T.
, and
M.
Cloitre
, “
Micromechanics of soft particle glasses
,”
Adv. Polym. Sci.
236
,
117
161
(
2010
).
6.
Borrega
,
R.
,
M.
Cloitre
,
I.
Betremieux
,
B.
Ernst
, and
L.
Leibler
, “
Concentration dependence of the low-shear viscosity of polyelectrolyte micro-networks: From hard spheres to soft microgels
,”
Europhys. Lett.
47
,
729
735
(
1999
).
7.
Brujic
,
J.
, “
Measuring the coordination number and entropy of a 3D jammed emulsion packing by confocal microscopy
,”
Phys. Rev. Lett.
98
,
248001
(
2007
).
8.
Chung
,
B.
,
S.
Ramakrishnan
,
R.
Bandyopadhyay
,
D.
Liang
,
C. F.
Zukoski
,
J. L.
Harden
, and
R. L.
Leheny
, “
Microscopic dynamics of recovery in sheared depletion gels
,”
Phys. Rev. Lett.
96
,
228301
(
2006
).
9.
Cianci
,
G. C.
,
R. E.
Courtland
, and
E. R.
Weeks
, “
Correlations of structure and dynamics in an aging colloidal glass
,”
Solid State Commun.
139
,
599
604
(
2006
).
10.
Cipelletti
,
L.
, and
L.
Ramos
, “
Slow dynamics in glasses, gels and foams
,”
Curr. Opin. Colloid Interface Sci.
7
,
228
234
(
2002
).
11.
Cipelletti
,
L.
,
L.
Ramos
,
S.
Manley
,
E.
Pitard
,
D. A.
Weitz
,
E. E.
Pashkovski
, and
M.
Johansson
, “
Universal non-diffusive slow dynamics in aging soft matter
,”
Faraday Discuss.
123
,
237
251
(
2003
).
12.
Cipelletti
,
L.
,
S.
Manley
,
R. C.
Ball
, and
D. A.
Weitz
, “
Universal aging features in the restructuring of fractal colloidal gels
,”
Phys. Rev. Lett.
84
,
2275
2278
(
2000
).
13.
Cloitre
,
M.
,
R.
Borrega
,
F.
Monti
, and
L.
Leibler
, “
Glassy dynamics and flow properties of soft colloidal pastes
,”
Phys. Rev. Lett.
90
,
068303
(
2003a
).
14.
Cloitre
,
M.
,
R.
Borrega
,
F.
Monti
, and
L.
Leibler
, “
Structure and flow of polyelectrolyte microgels: From suspensions to glasses
,”
C.R. Phys.
4
,
221
230
(
2003b
).
15.
Cloitre
,
M.
,
R.
Borrega
, and
L.
Leibler
, “
Rheological aging and rejuvenation in microgel pastes
,”
Phys. Rev. Lett.
85
,
4819
4822
(
2000
).
16.
Damman
,
P.
,
S.
Gabriele
,
S.
Coppée
,
S.
Desprez
,
D.
Villers
,
T.
Vilmin
,
E.
Raphaël
,
M.
Hamieh
,
S. Al
Akhrass
, and
G.
Reiter
, “
Relaxation of residual stress and reentanglement of polymers in spin-coated films
,”
Phys. Rev. Lett.
99
,
036101
(
2007
).
17.
Derec
,
C.
,
G.
Ducouret
,
A.
Ajdari
, and
F.
Lequeux
, “
Aging and nonlinear rheology in suspensions of polyethylene oxide-protected silica particles
,”
Phys. Rev. E
67
,
061403
(
2003
).
18.
Donev
,
A.
,
S.
Torquato
, and
F. H.
Stillinger
, “
Pair correlation function characteristics of nearly jammed disordered and ordered hard-sphere packings
,”
Phys. Rev. E
71
,
011105
(
2005
).
19.
Dzuy
,
N. Q.
, and
D. V.
Boger
, “
Yield stress measurement for concentrated suspensions
,”
J. Rheol.
27
,
321
349
(
1983
).
20.
Fernandez-Cuesta
,
I.
,
X.
Borrisé
,
A.
Retolaza
,
S.
Merino
,
D.-A.
Mendels
,
O.
Hansen
,
A.
Kristensen
, and
F.
Pérez-Murano
, “
Determination of stress build-up during nanoimprint process in triangular polymer structures
,”
Microelectron. Eng.
85
,
838
841
(
2008
).
21.
Freidin
,
A. S.
, and
A. B.
Sholokhova
, “
Internal stress relaxation in polymer systems
,”
Polym. Mechan.
2
,
151
153
(
1966
).
22.
Fritsch
,
S.
,
M.
Fuchs
, and
Th.
Voigtmann
, “
Mode-coupling analysis of residual stresses in colloidal glasses
,”
Soft Matter
10
,
4822
4832
(
2014
).
23.
Green
,
D. J.
,
R.
Tandon
, and
V. M.
Sglavo
, “
Crack arrest and multiple cracking in glass through the use of designed residual stress profiles
,”
Science
283
,
1295
1297
(
1999
).
24.
Hanley
,
H. J. M.
,
J. C.
Rainwater
, and
S.
Hess
, “
Shear-induced angular-dependence of the liquid pair correlation-function
,”
Phys. Rev. A
36
,
1795
1802
(
1987
).
25.
Lacasse
,
M.-D.
,
G. S.
Grest
,
D.
Levine
,
T. G.
Mason
, and
D. A.
Weitz
, “
Model for elasticity of compressed emulsions
,”
Phys. Rev. Lett.
76
,
3448
3451
(
1996
).
26.
Lieleg
,
O.
,
J.
Kayser
,
G.
Brambilla
,
L.
Cipelletti
, and
A. R.
Bausch
, “
Slow dynamics and internal stress relaxation in bundled cytoskeletal networks
,”
Nature Mater.
10
,
236
242
(
2011
).
27.
Liu
,
K. K.
,
D. R.
Williams
, and
B. J.
Briscoe
, “
The large deformation of a single micro-elastomeric sphere
,”
J. Phys. D: Appl. Phys.
31
,
294
303
(
1998
).
28.
Lubachevsky
,
B. D.
, and
F. H.
Stillinger
, “
Geometric properties of random disk packings
,”
J. Stat. Phys.
60
,
561
583
(
1990
).
29.
Mazoyer
,
S.
,
L.
Cipelletti
, and
L.
Ramos
, “
Origin of the slow dynamics and the aging of a soft glass
,”
Phys. Rev. Lett.
97
,
238301
(
2006
).
30.
Micoulaut
,
M.
, “
The deep effect of topology on glass relaxation
,”
Physics
6
,
72
(
2013
).
31.
Mohan
,
L.
,
C.
Pellet
,
M.
Cloitre
, and
R.
Bonnecaze
, “
Local mobility and microstructure in periodically sheared soft particle glasses and their connection to macroscopic rheology
,”
J. Rheol.
57
,
1023
1046
(
2013a
).
32.
Mohan
,
L.
,
M.
Cloitre
, and
R.
Bonnecaze
, “
Active microrheology of soft particle glasses
,”
J. Rheol.
58
,
1465
1482
(
2014
).
33.
Mohan
,
L.
,
R. T.
Bonnecaze
, and
M.
Cloitre
, “
Microscopic origin of internal stresses in jammed soft particle suspensions
,”
Phys. Rev. Lett.
111
,
268301
(
2013b
).
34.
Monti
,
F.
, “
Microrhéologie de suspensions colloïdales non ergodiques: Relaxations locales, dynamiques lentes: vieillissement
,” Ph.D. thesis,
Université Pierre et Marie Curie, Paris
,
2010
.
35.
Morris
,
J. F.
, and
B.
Katyal
, “
Microstructure from simulated Brownian suspension flows at large shear rate
,”
Phys. Fluids
14
,
1920
1937
(
2002
).
36.
Narita
,
T.
,
C.
Beauvais
,
P.
Hébraud
, and
F.
Lequeux
, “
Dynamics of concentrated colloidal suspensions during drying—Aging
,
rejuvenation and overaging
,”
Eur. Phys. J. E
14
,
287
292
(
2004
).
37.
Negi
,
A.
, and
C.
Osuji
, “
Dynamics of a colloidal glass during stress-mediated structural arrest
,”
Europhys. Lett.
90
,
28003
(
2010a
).
38.
Negi
,
A. S.
, and
C. O.
Osuji
, “
Dynamics of internal stresses and scaling of strain recovery in an aging colloidal gel
,”
Phys. Rev. E
80
,
010404
(
2009
).
39.
Negi
,
A. S.
, and
C. O.
Osuji
, “
Physical aging and relaxation of residual stresses in a colloidal glass following flow cessation
,”
J. Rheol.
54
,
943
958
(
2010b
).
40.
O'Hern
,
C. S.
,
L. E.
Silbert
,
A. J.
Liu
, and
S. R.
Nagel
, “
Jamming at zero temperature and zero applied stress: The epitome of disorder
,”
Phys. Rev. E
68
,
011306
(
2003
).
41.
Petersen
,
C.
,
C.
Heldmann
, and
D.
Johannsmann
, “
Internal stresses during film formation of polymer latices
,”
Langmuir
15
,
7745
7751
(
1999
).
42.
Plimpton
,
S. J.
, “
Fast parallel algorithms for short-range molecular dynamics
,”
Comput. Phys.
117
,
1
19
(
1995
).
43.
Ramos
,
L.
, and
L.
Cipelletti
, “
Ultraslow dynamics and stress relaxation in the aging of a soft glassy system
,”
Phys. Rev. Lett.
87
,
245503
(
2001
).
44.
Ramos
,
L.
, and
L.
Cipelletti
, “
Intrinsic aging and effective viscosity in the slow dynamics of a soft glass with tunable elasticity
,”
Phys. Rev. Lett.
94
,
158301
(
2005
).
45.
Reiter
,
G.
,
M.
Hamieh
,
P.
Damman
,
S.
Sclavons
,
S.
Gabriele
,
T.
Vilmin
, and
E.
Raphaël
, “
Residual stresses in thin polymer films cause rupture and dominate early stages of dewetting
,”
Nature Mater.
4
,
754
758
(
2005
).
46.
Seth
,
J. R.
,
C.
Locatelli-Champagne
,
F.
Monti
,
R. T.
Bonnecaze
, and
M.
Cloitre
, “
How do soft particle glasses yield and flow near solid surfaces?
,”
Soft Matter
8
,
140
148
(
2012
).
47.
Seth
,
J. R.
,
L.
Mohan
,
C.
Locatelli-Champagne
,
M.
Cloitre
, and
R. T.
Bonnecaze
, “
A micromechanical model to predict the flow of soft particle glasses
,”
Nature Mater.
10
,
838
843
(
2011
).
48.
Seth
,
J. R.
,
M.
Cloitre
, and
R. T.
Bonnecaze
, “
Elastic properties of soft particle pastes
,”
J. Rheol.
50
,
353
376
(
2006
).
49.
Seth
,
J. R.
,
M.
Cloitre
, and
R. T.
Bonnecaze
, “
Influence of short-range forces on wall-slip in microgel pastes
,”
J. Rheol.
52
,
1241
1268
(
2008
).
50.
Struik
,
L. C. E.
,
Internal Stresses, Dimensional Instabilities and Molecular Orientations in Plastics
(
Wiley
,
Brisbane
,
1990
).
51.
Takeshi
,
O.
, and
K.
Sekimoto
, “
Internal stress in a model elastoplastic fluid
,”
Phys. Rev. Lett.
95
,
108301
(
2005
).
52.
Tomozawa
,
M.
,
A.
Koike
, and
S. R.
Ryu
, “
Exponential structural relaxation of a high purity silica glass
,”
J. Non-Cryst. Solids
354
,
4685
4690
(
2008
).
53.
Wang
,
S. Q.
,
S.
Ravindranath
,
P.
Boukany
,
M.
Olechnowicz
,
R. P.
Quirk
,
A.
Halasa
, and
J.
Mays
, “
Nonquiescent relaxation in entangled polymer liquids after step shear
,”
Phys. Rev. Lett.
97
,
187801
(
2006
).
54.
Welch
,
R. C.
,
J. R.
Smith
,
M.
Potuzak
,
X.
Guo
,
B. F.
Bowden
,
T. J.
Kiczenski
,
D. C.
Allan
,
E. A.
King
,
A. J.
Ellison
, and
J. C.
Mauro
, “
Dynamics of glass relaxation at room temperature
,”
Phys. Rev. Lett.
110
,
265901
(
2013
).
55.
Zhang
,
Y.
,
W. H.
Wang
, and
A. L.
Greer
, “
Making metallic glasses plastic by control of residual stress
,”
Nature Mater.
5
,
857
860
(
2006
).
You do not currently have access to this content.