The effect of geometrical confinement on the deformation and orientation of single droplets during steady-state shear flow is investigated microscopically in a counterrotating device. The model system consists of poly(dimethyl siloxane) droplets of varying sizes and viscosities in a poly(isobutylene) matrix. The experimental results are first compared with the predictions of the model by Maffettone and Minale [J. Non-Newtonian Fluid Mech.78, 227241 (1998)] for bulk flow. For all viscosity ratios, deviations from the Maffettone and Minale model start to occur at a droplet diameter to gap spacing ratio of the order of 0.4. The droplet deformation increases and the droplets orient more towards the flow direction as a consequence of confinement. At low viscosity ratios, the deviations remain small, whereas at high viscosity ratios, larger deviations from bulk behavior are observed. The observations are also compared with the theory of Shapira and Haber [Int. J. Multiphase Flow16, 305321 (1990)] which includes the influence of wall effects on deformation. The Shapira and Haber model is modified by replacing the Taylor model as bulk reference by the Maffettone and Minale model. Good agreement between theory and experimental results is found for a wide range of viscosity ratios.

1.
Cristini
,
V.
,
S.
Guido
,
A.
Alfani
,
J.
Blawzdziewicz
, and
M.
Loewenberg
, “
Drop breakup and fragment size distribution in shear flow
,”
J. Rheol.
47
,
1283
1298
(
2003
).
2.
de Bruijn
,
R. A.
, “
Deformation and breakup of droplets in simple shear flows
,” Ph.D. thesis,
Eindhoven University of Technology
,
1989
.
3.
Grace
,
H. P.
, “
Dispersion phenomena in high viscosity immiscible fluid systems and application of static mixers as dispersion devices in such systems
,”
Chem. Eng. Commun.
14
,
225
277
(
1982
).
4.
Grizzuti
,
N.
, and
O.
Bifulco
, “
Effects of coalescence and breakup on the steady-state morphology of an immiscible polymer blend in shear flow
,”
Rheol. Acta
36
,
406
415
(
1997
).
5.
Guido
,
S.
, and
M.
Simeone
, “
Binary collision of drops in simple shear flow by computer-assisted video optical microscopy
,”
J. Fluid Mech.
357
,
1
20
(
1998
).
6.
Guido
,
S.
, and
F.
Greco
, “
Dynamics of a liquid drop in a flowing immiscible liquid
,”
Rheol. Rev.
2004
,
99
142
(
2004
).
7.
Hayashi
,
R.
,
M.
Takahashi
,
H.
Yamane
,
H.
Jinnai
, and
H.
Watanabe
, “
Dynamic interfacial properties of polymer blends under large step strains: shape recovery of a single droplet
,”
Polymer
42
,
757
764
(
2001
).
8.
Kobayashi
,
H.
, and
M. J.
Owen
, “
Surface properties of fluorosilicones
,”
Trends Polym. Sci.
3
,
330
335
(
1995
).
9.
Link
,
D. R.
,
S. L.
Anna
,
D. A.
Weitz
, and
H. A.
Stone
, “
Geometrically mediated breakup of drops in microfluidic devices
,”
Phys. Rev. Lett.
92
,
054503
054506
(
2004
).
10.
Maffettone
,
P. L.
, and
M.
Minale
, “
Equation of change for ellipsoidal drops in viscous flows
,”
J. Non-Newtonian Fluid Mech.
78
,
227
241
(
1998
).
11.
Maffettone
,
P. L.
, and
M.
Minale
, “
Erratum to Equation of change for ellipsoidal drops in viscous flows
,” [J. Non-Newtonian Fluid Mech. 78, 227–241 (1998)]
J. Non-Newtonian Fluid Mech.
84
,
105
106
(
1999
).
12.
Migler
,
K. B.
, “
String formation in sheared polymer blends: coalescence, breakup and finite size effects
,”
Phys. Rev. Lett.
86
,
1023
1026
(
2001
).
13.
Minale
,
M.
,
P.
Moldenaers
, and
J.
Mewis
, “
Effect of shear history on the morphology of immiscible polymer blends
,”
Macromolecules
30
,
5470
5475
(
1997
).
14.
Ottino
,
J. M.
,
P.
De Roussel
,
S.
Hansen
, and
D. V.
Khakhar
, “
Mixing and dispersion of viscous fluids and powdered solids
,”
Adv. Chem. Eng.
25
,
105
204
(
1999
).
15.
Pathak
,
J. A.
,
M. C.
Davis
,
S. D.
Hudson
, and
K. B.
Migler
, “
Layered droplet microstructures in sheared emulsions: finite-size effects
,”
J. Colloid Interface Sci.
255
,
391
402
(
2002
).
16.
Pathak
,
J. A.
, and
K. B.
Migler
, “
Droplet-string deformation and stability during microconfined shear flow
,”
Langmuir
19
,
8667
8674
(
2003
).
17.
Rallison
,
J. M.
, “
The deformation of small viscous drops and bubbles in shear flows
,”
Annu. Rev. Fluid Mech.
16
,
45
66
(
1984
).
18.
Shapira
,
M.
, and
S.
Haber
, “
Low Reynolds number motion of a droplet in shear flow including wall effects
,”
Int. J. Multiphase Flow
16
,
305
321
(
1990
).
19.
Sibillo
,
V.
,
G.
Pasquariello
,
M.
Simeone
,
V.
Cristini
, and
S.
Guido
, “
Drop deformation in microconfined shear flow
,”
Phys. Rev. Lett.
97
,
054502
(
2006
).
20.
Sigillo
,
I.
,
L.
di Santo
,
S.
Guido
, and
N.
Grizzuti
, “
Comparative measurements of interfacial tension in a model polymer blend
,”
Polym. Eng. Sci.
37
,
1540
1549
(
1997
).
21.
Stone
,
H. A.
, “
Dynamics of drop deformation and breakup in viscous fluids
,”
Annu. Rev. Fluid Mech.
26
,
65
102
(
1994
).
22.
Stone
,
H. A.
,
A. D.
Stroock
, and
A.
Ajdari
, “
Engineering flows in small devices: microfluidics toward a lab-on-a-chip
,”
Annu. Rev. Fluid Mech.
36
,
381
411
(
2004
).
23.
Taylor
,
G. I.
, “
The viscosity of a fluid containing small drops of another fluid
,”
Proc. R. Soc. London, Ser. A
138
,
41
48
(
1932
).
24.
Tucker
,
C. L.
, and
P.
Moldenaers
, “
Microstructural evolution in polymer blends
,”
Annu. Rev. Fluid Mech.
34
,
177
210
(
2002
).
25.
Utada
,
A. S.
,
E.
Lorenceau
,
D. R.
Link
,
P. D.
Kaplan
,
H. A.
Stone
, and
D. A.
Weitz
, “
Monodisperse double emulsions generated from a microcapillary device
,”
Science
308
,
537
541
(
2005
).
26.
Vananroye
,
A.
,
P.
Van Puyvelde
, and
P.
Moldenaers
, “
Structure development in confined polymer blends: steady-state shear flow and relaxation
,”
Langmuir
22
,
2273
2280
(
2006a
).
27.
Vananroye
,
A.
,
P.
Van Puyvelde
, and
P.
Moldenaers
, “
Effect of confinement on droplet breakup in sheared emulsions
,”
Langmuir
22
,
3972
3974
(
2006b
).
28.
Vananroye
,
A.
,
P.
Van Puyvelde
, and
P.
Moldenaers
, “
Morphology development during microconfined flow of viscous emulsions
,”
Appl. Rheol.
16
,
242
247
(
2006c
).
29.
Vinckier
,
I.
,
P.
Moldenaers
, and
J.
Mewis
, “
Relationship between rheology and morphology of model blends in steady shear flow
,”
J. Rheol.
40
,
613
631
(
1996
).
30.
Yamane
,
H.
,
M.
Takahashi
,
R.
Hayashi
,
K.
Okamoto
,
H.
Kashihara
, and
T.
Masuda
, “
Observation of deformation and recovery of poly(isobutylene) droplet in a poly(isobutylene)/poly(dimethyl siloxane) blend after application of step shear strain
,”
J. Rheol.
42
,
567
580
(
1998
).
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