In 1999, Öttinger introduced a thermodynamically admissible reptation model incorporating chain stretching, anisotropic tube cross sections, double reptation, and the convective constraint release mechanism. In this paper, we describe and use a new high-order Fokker–Planck-based numerical method for the simulation of the Öttinger model in complex geometries. Evidence, in the case of startup homogeneous flows, of the significant CPU time advantage (for comparable levels of accuracy) of our method over a stochastic simulation [Fang et al. (2000)], is presented. For the confined cylinder benchmark problem, differences in the drag behavior observed between the Öttinger model and those of Doi and Edwards (1978a, 1978b, 1978c) and Mead et al. (1998) are explained in terms of double reptation and the differing relaxation spectra.
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March 2003
Research Article|
March 01 2003
Fokker–Planck simulations of fast flows of melts and concentrated polymer solutions in complex geometries
Alexei Lozinski;
Alexei Lozinski
LMF–ISE–FSTI, Ecole Polytechnique Fédérale de Lausanne, CH 1015 Lausanne, Switzerland
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Cédric Chauvière;
Cédric Chauvière
Division of Applied Mathematics, Brown University, Box F, Providence, Rhode Island 02912
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Jiannong Fang;
Jiannong Fang
GEOLEP–ICARE–FENAC, Ecole Polytechnique Fédérale de Lausanne, CH 1015 Lausanne, Switzerland
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Robert G. Owens
Robert G. Owens
LMF–ISE–FSTI, Ecole Polytechnique Fédérale de Lausanne, CH 1015 Lausanne, Switzerland
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Alexei Lozinski
Cédric Chauvière
Jiannong Fang
Robert G. Owens
LMF–ISE–FSTI, Ecole Polytechnique Fédérale de Lausanne, CH 1015 Lausanne, Switzerland
J. Rheol. 47, 535–561 (2003)
Article history
Received:
September 19 2002
Citation
Alexei Lozinski, Cédric Chauvière, Jiannong Fang, Robert G. Owens; Fokker–Planck simulations of fast flows of melts and concentrated polymer solutions in complex geometries. J. Rheol. 1 March 2003; 47 (2): 535–561. https://doi.org/10.1122/1.1545440
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