Complex oxides, comprising multiple metallic cations and oxygen, exhibit several intriguing and exploitable properties, including ferroelectricity (with spontaneously ordered electric dipole moments), ferromagnetism (with spontaneously ordered magnetic moments), and ferroelastics (with spontaneously ordered strain arrangements). As described by Nicola Spaldin, Sang-Wook Cheong, and Ramamoorthy Ramesh on page 38, experimentalists and theorists are learning how to make materials called multiferroics that combine two of those properties—ferroelectricity and magnetism—in a single phase. The coupling between multiferroics’ electric and magnetic properties is one active area of research; the materials’ interfaces, such as domain walls, also present fascinating physics.
The yttrium manganite (YMnO3) shown in this colored transmission electron microscope image is a multiferroic with a hexagonal crystal structure. Below a critical temperature, it undergoes a spontaneous structural instability that leads to three structural domains, each of which can support two directions of ferroelectric polarization. Against the background variations in the image,...
