An expandable molecular sponge

Zinc ions and some other metal ions can bind to three or four organic molecules at once. If those molecules are long and attach to zinc at both ends, it’s possible to create a metal-organic framework (MOF), an open sheet of linked molecules with ions at the vertices. And if those sheets bind to each other and stack in register, the result is a material whose columnar pores can store, catalyze, or otherwise usefully process small molecules. Matthew Rosseinsky and his coworkers at the University of Liverpool in the UK have made a MOF material, but with a new twist. For its linker, the Liverpool team used a dipeptide—that is, two peptide-bonded amino acids (glycine and alanine; see figure). The team made two versions of the material, one incorporating a solvent (a mix of water and methanol) and one not. X-ray diffraction and nuclear magnetic resonance spectroscopy revealed that...