Polonium, with atomic number 84, is the only element with a simple cubic crystal structure, and new theoretical work by a team of scientists at the Academy of Sciences of the Czech Republic, Brno University of Technology, and Masaryk University explains why. In a solid piece of Po, the atoms sit at the corners of a cubic unit cell and nowhere else. Most other metallic elements, in contrast, have body-centered cubic, face-centered cubic, or hexagonally close-packed structure. Using state-of-the-art ab initio electronic structure calculations, the researchers have produced a detailed theoretical explanation for Po's unique crystal structure: It is the result of the complicated interplay of relativistic effects that become important in heavy atoms such as Po. In particular, they found that the mass–velocity effect, which describes the relativistic increase in mass of electrons traveling at speeds comparable to that of light, increases faster than the effect of spin–orbit coupling...
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1 August 2007
August 01 2007
Polonium's simple cubic structure Available to Purchase
Philip F. Schewe
Physics Today 60 (8), 24 (2007);
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Philip F. Schewe; Polonium's simple cubic structure. Physics Today 1 August 2007; 60 (8): 24. https://doi.org/10.1063/1.4796556
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