Until the 19th century, technology was essentially the domain of skilled artisans and constructors who relied on practical experience to design and build their machines. One of the first efforts to use physical theory to study the functioning of machines was undertaken by the French engineer Sadi Carnot. Motivated by the concern of the French about the superiority of British steam engines, he undertook a systematic study of the physical processes governing steam engines, resulting in his remarkable paper Reflexions sur la puissance motrice du feu (On the Motive Power of Heat) published in 1826. Among the earliest successes of this new science, thermodynamics, was the formulation of criteria describing how well real processes perform in comparison with an ideal model. Carnot showed that any engine, using heat from a hot reservoir at temperature Th to do work, has to transfer some heat to a reservoir at lower temperature T1, and that no engine could convert into work more of the heat taken in at Th than the fraction
known as the Carnot efficiency.
1.
M.
Mozurkewich
,
R. S.
Berry
,
Proc. Nat. Acad. Sci.
78
,
1986
(
1981
);
M.
Mozurkewich
,
R. S.
Berry
,
J. Appl. Phys.
53
,
34
(
1982
).
2.
J.
Wheatley
,
T.
Hofler
,
G. W.
Swift
,
A.
Migliori
,
Phys. Rev. Lett.
50
,
499
(
1983
).
3.
For a more theoretical review of many of the topics covered in this article, see B. Andresen, R. S. Berry, M. J. Ondrechen, P. Salamon, “Thermodynamics for Processes in Finite Time,” Acc. Chem. Res., in press.
4.
P.
Salamon
,
A.
Nitzan
,
B.
Andresen
,
R. S.
Berry
,
Phys. Rev. A
21
,
2115
(
1980
).
5.
P.
Salamon
,
B.
Andresen
,
R. S.
Berry
,
Phys. Rev. A
15
,
2094
(
1977
).
6.
J.
Geusic
,
E. O.
Schulz‐DuBois
,
H. E. D.
Scovil
,
Phys. Rev.
156
,
343
(
1967
).
7.
F.
Schlögl
,
Z. Phys.
191
,
81
(
1966
);
F.
Schlögl
,
Z. Phys.
198
,
559
(
1967
).
I.
Procaccia
,
R. D.
Levine
,
J. Chem. Phys.
65
,
3357
(
1976
).
8.
B.
Andresen
,
P.
Salamon
,
R. S.
Berry
,
J. Chem. Phys.
66
,
1571
(
1977
).
9.
F. L.
Curzon
,
B.
Ahlborn
,
Am. J. Phys.
43
,
22
(
1975
).
10.
P.
Salamon
,
A.
Nitzan
,
J. Chem. Phys.
74
,
3546
(
1981
).
11.
P.
Salamon
,
Y. B.
Band
,
O.
Kafri
,
J. Appl. Phys.
53
,
197
(
1982
).
12.
B.
Andresen
,
M. H.
Rubin
,
R. S.
Berry
,
J. Phys. Chem.
82
,
2704
(
1983
).
13.
P.
Salamon
,
R. S.
Berry
,
Phys. Rev. Lett.
51
,
1127
(
1983
).
14.
F.
Weinhold
,
J. Chem. Phys.
63
,
2479
(
1975
);
F.
Weinhold
,
J. Chem. Phys.
65
,
559
(
1976
).
15.
M. H.
Rubin
,
Phys. Rev. A
19
,
1272
,
1277
(
1979
).
16.
M. H.
Rubin
,
Phys. Rev. A
22
,
1741
(
1980
).
17.
M. J.
Ondrechen
,
B.
Andresen
,
M.
Mozurkewich
,
R. S.
Berry
,
Am. J. Phys.
49
,
681
(
1981
).
18.
Y. B.
Band
,
O.
Kafri
, and
P.
Salamon
,
J. Appl. Phys.
52
,
3745
(
1981
).
19.
M. J.
Ondrechen
,
R. S.
Berry
,
B.
Andresen
,
J. Chem. Phys.
72
,
5118
(
1980
);
M. J.
Ondrechen
,
B.
Andresen
,
R. S.
Berry
,
J. Chem. Phys.
73
,
5838
(
1980
).
This content is only available via PDF.
You do not currently have access to this content.