We report on the substitution of silver nanoparticles' inks by silver microparticle dispersions as a material for the production of printable silver tracks by laser melting. This approach is promising, because it helps to reduce the production costs of such silver tracks. Though silver dispersions used as materials for laser melting mostly contain polyvinylpyrrolidone as a stabilizer, which results in the appearance of an undesired balling effect of silver during laser melting, the authors test stabilizers differing in molecular weight and functionality. The resulting differences in colloidal and physicochemical properties are investigated and related to the final silver layer quality.

1.
R.
Venkata Krishna Rao
,
K.
Venkata Abhinav
,
P. S.
Karthik
, and
S. P.
Singh
, “
Conductive silver inks and their applications in printed and flexible electronics
,”
RSC Adv.
5
,
77760
77790
(
2015
).
2.
A.
Kamyshny
and
S.
Magdassi
, “
Conductive nanomaterials for printed electronics
,”
Small
10
,
3515
3535
(
2014
).
3.
A.
Russo
,
B. Y.
Ahn
,
J. J.
Adams
,
E. B.
Duoss
,
J. T.
Bernhard
, and
J. A.
Lewis
, “
Pen-on-paper flexible electronics
,”
Adv. Mater.
23
,
3426
3430
(
2011
).
4.
B. Y.
Ahn
and
J. A.
Lewis
, “
Amphiphilic silver particles for conductive inks with controlled wetting behaviour
,”
Mater. Chem. Phys.
148
,
686
691
(
2014
).
5.
B.-J.
de Gans
,
P. C.
Duineveld
, and
U. S.
Schubert
, “
Inkjet printing of polymers: State of the art and future developments
,”
Adv. Mater.
16
,
203
213
(
2004
).
6.
A.
Kamyshny
,
M.
Ben-Moshe
,
S.
Aviezer
, and
S.
Magdassi
, “
Ink-jet printing of metallic nanoparticles and microemulsions
,”
Macromol. Rapid Commun.
26
,
281
288
(
2005
).
7.
J. T.
Muth
,
D. M.
Vogt
,
R. L.
Truby
,
Y.
,
Mengüc
,
D. B.
Kolesky
,
R. J.
Wood
, and
J. A.
Lewis
, “
Embedded 3D printing of strain sensors within highly stretchable elastomers
,”
Adv. Mater.
26
,
6307
6312
(
2014
).
8.
T.
Kumpulainen
,
J.
Pekkanan
,
J.
Valkama
,
J.
Laakso
,
R.
Tuokko
, and
M.
Mäntysalo
, “
Low temperature nanoparticle sintering with continuous wave and pulsed lasers
,”
Opt. Laser Technol.
43
,
570
576
(
2011
).
9.
Federal Ministry of Education and Research
, “
Status quo der Nanotechnologie in Deutschland
,”
Germany: nano.DE-Report
3 (
2013
), p.
35
.
10.
M. A.
El-Sayed
, “
Some interesting properties of metals confined in time and nanometer space of different shapes
,”
Acc. Chem. Res.
34
,
257
264
(
2001
).
11.
M.
Zenou
,
O.
Ermak
,
A.
Saar
, and
Z.
Kotler
, “
Laser sintering of copper nanoparticles
,”
J. Phys. D: Appl. Phys.
47
,
025501
(
2014
).
12.
K.
Maekawa
,
K.
Yamasaki
,
T.
Niizeki
,
M.
Mita
,
Y.
Matsuba
,
N.
Terada
, and
H.
Saito
, “
Laser sintering of silver nanoparticles for electronic use
,”
Mater. Sci. Forum
638–642
,
2085
2090
(
2010
).
14.
See http://www.edelmetall-handel.de/silberbarren-1000g-heraeus.html for Online-Shop for precious metals including daily exchange rates.
16.
I.
Yadroitsev
,
A.
Gusarov
,
I.
Yadroitsava
, and
I.
Smurov
, “
Single track formation in selective laser melting of metal powders
,”
J. Mater. Process. Technol.
210
,
1624
1631
(
2010
).
17.
Y.
Lin
,
E.
van Kerschaver
, and
K.
Cabanas-Holmen
, in
39th IEEE Photovoltaic Specialists Conference
(
2013
).
18.
B.
Gökce
,
S.
Barcikowski
,
P.
Behrens
,
U.
Fritsching
,
I.
Kelbassa
,
R.
Poprawe
,
C.
Esen
,
A.
Ostendorf
, and
B.
Voit
, “
Prozessadaptierte Materialien für die Photonik
,”
Photonik
1
,
24
28
(
2015
).
19.
B.
Gökce
,
S.
Barcikowski
,
S.
Behrens
,
U.
Fritsching
,
I.
Kelbasse
,
R.
Poprawe
,
C.
Esen
,
A.
Ostendorf
, and
B.
Voit
, “
Materials for photonics
,”
Laser Photonics
1
,
6
10
(
2016
).
20.
B.
Wiley
,
Y.
Sun
,
B.
Mayers
, and
Y.
Xia
, “
Shape-controlled synthesis of metal nanostructures: The case of silver
,”
Chem. Eur. J.
11
,
454
463
(
2005
).
21.
S.
Silber
,
E.
Reuther
,
A.
Nawracala
,
T.
Mangel
,
H.
Leitner
, and
G.
Albrecht
, “
Dispergiermittel zur Herstellung von wässrigen Pigmentpasten
,” European patent (Germany)
EP1142972
(26 March
2001
).
22.
M.
Vielkind
,
I.
Kampen
, and
A.
Kwade
, “
Zinc oxide nanoparticles in bacterial growth medium: optimized dispersion and growth inhibition of Pseudomonas putida
,”
Adv. Nanopart.
2
,
287
293
(
2013
).
23.
F.
Sen
,
Y.
Karatas
,
M.
Gulcan
, and
M.
Zahmakiran
, “
Amylamine stabilized platinum(0) nanoparticles: active and reusable nanocatalyst in the room temperature dehydrogenation of dimethyleamine-borane
,”
RSC Adv.
4
,
1526
1531
(
2014
).
24.
A.
Ostendorf
,
M.
Goede
, and
S.
Barcikowski
, “
Putting fundamentals on multiphase material balance of laser based cutting of polymers and natural fibre composites to practical use
,”
Proc. SPIE
4831
,
1
4
(
2003
).
You do not currently have access to this content.