Finding ways to scribe Mo back conductor plays an important role in the fabrication and assembly of CIGS thin film solar cells. Using a femtosecond (fs) laser, we selectively removed the Mo thin films of 800 ∼850 nm thick on flexible Polyamide (PI) substrates. In particular, we studied the effect of laser fluence and laser scanning speed on the ablation quality. The single pulse ablation thresholds at various pulse durations were determined. Clean removal of the Mo layer was observed when laser fluence was above the threshold of 0.08-0.1 J/cm2. Furthermore, the morphologies and structure of the grooves were characterized using scanning electron microscope (SEM) and KLA Tencor P-16 Profiler. The femtosecond laser provides a unique scheme to ablate the metal layer on flexible substrates for the fabrication of thin film solar cells.

1.
Green
,
M.A.
,
Emery
,
K.
,
Hishikawa
,
Y.
and
Warta
,
W.
(
2011
)
Solar cell efficiency tables (version 37)
.
Progress in Photovoltaics: Research and Applications
,
19
(
1
),
84
92
.
2.
Powalla
,
M.
,
Cemernjak
,
M.
,
Eberhardt
,
J.
,
Kessler
,
F.
,
Kniese
,
R.
,
Mohring
,
H.D.
and
Dimmler
,
B.
(
2006
)
Large-area CIGS modules: Pilot line production and new developments
.
Solar Energy Materials and Solar Cells
,
90
(
18-19
),
3158
3164
.
3.
Hermann
,
J.
,
Benfarah
,
M.
,
Bruneau
,
S.
,
Axente
,
E.
,
Coustillier
,
G.
,
Itina
,
T.
,
Guillemoles
,
J.F.
and
Alloncle
,
P.
(
2006
)
Comparative investigation of solar cell thin film processing using nanosecond and femtosecond lasers
.
Journal of Physics D: Applied Physics
,
39
(
3
),
453
460
.
4.
Hermann
,
J.
,
Benfarah
,
M.
,
Coustillier
,
G.
,
Bruneau
,
S.
,
Axente
,
E.
,
Guillemoles
,
J.F.
,
Sentis
,
M.
,
Alloncle
,
P.
and
Itina
,
T.
(
2006
)
Selective ablation of thin films with short and ultrashort laser pulses
.
Applied Surface Science
,
252
(
13 SPEC. ISS
.),
4814
4818
.
5.
Hermann
,
J.
,
Benfarah
,
M.
,
Bruneau
,
S.
,
Axente
,
E.
,
Coustillier
,
G.
,
Itina
,
T.
,
Guillemoles
,
J.F.
and
Alloncle
,
P.
(
2006
)
Comparative investigation of solar cell thin film processing using nanosecond and femtosecond lasers
.
Journal of Physics D-Applied Physics
,
39
(
3
),
453
460
.
6.
Ruthe
,
D.
,
Zimmer
,
K.
and
Hoche
,
T.
(
2005
)
Etching of CuInSe2 thin films-comparison of femtosecond and picosecond laser ablation
.
Applied Surface Science
,
247
(
1-4
),
447
452
.
7.
Liu
,
J.M.
(
1982
)
Simple technique for measurements of pulsed Gaussian-beam spot sizes
.
Optics Letters
,
7
(
5
),
196
198
.
8.
Le Harzic
,
R.
,
Breitling
,
D.
,
Weikert
,
M.
,
Sommer
,
S.
,
Fohl
,
C.
,
Valette
,
S.
,
Donnet
,
C.
,
Audouard
,
E.
and
Dausinger
,
F.
(
2005
)
Pulse width and energy influence on laser micromachining of metals in a range of 100 fs to 5 ps
.
Applied Surface Science
,
249
(
1-4
),
322
331
.
9.
Perry
,
M.D.
,
Stuart
,
B.C.
,
Banks
,
P.S.
,
Feit
,
M.D.
,
Yanovsky
,
V.
and
Rubenchik
,
A.M.
(
1999
)
Ultrashort-pulse laser machining of dielectric materials
.
Journal of Applied Physics
,
85
(
9
),
6803
6810
.
10.
Le
,
H.R.
,
Huot
,
N.
,
Audouard
,
E.
,
Jonin
,
C.
,
Laporte
,
P.
,
Valette
,
S.
,
Fraczkiewicz
,
A.
and
Fortunier
,
R.
(
2002
)
Comparison of heat-affected zones due to nanosecond and femtosecond laser pulses using transmission electronic microscopy
.
Applied Physics Letters
,
80
(
21
),
3886
3886
.
11.
Wang
,
Z.B.
,
Hong
,
M.H.
,
Lu
,
Y.F.
,
Wu
,
D.J.
,
Lan
,
B.
and
Chong
,
T.C.
(
2003
)
Femtosecond laser ablation of polytetrafluoroethylene (Teflon) in ambient air
.
Journal of Applied Physics
,
93
(
10
),
6375
6380
.
12.
Park
,
M.
,
Chon
,
B.H.
,
Kim
,
H.S.
,
Jeoung
,
S.C.
,
Kim
,
D.
,
Lee
,
J.I.
,
Chu
,
H.Y.
and
Kim
,
H.R.
(
2006
)
Ultrafast laser ablation of indium tin oxide thin films for organic light-emitting diode application
.
Optics and Lasers in Engineering
,
44
(
2
),
138
146
.
13.
Aberle
,
A.G.
(
2009
)
Thin-film solar cells
.
Thin Solid Films
,
517
(
17
),
4706
4710
.
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