Laser-induced resonant vibrational excitations of precursor molecules in multi-energy processing for diamond synthesis Available to Purchase

A wavelength-tunable CO₂ laser (spectrum range from 9.2 to 10.9 f.m) was applied in a multi-energy process for growing diamond crystals in open air. A pre-mixed C₂H₄/C₂H₂/O₂ gas was used as precursors for the diamond growth. Laser energy was coupled into the reactions through resonantly exciting the CHB2B-wagging mode of ethylene (C₂H₄) molecules by tuning the laser wavelength to 10.532 µm. Diamond growth rate and diamond quality were both promoted by the laser-induced resonant excitations. High-quality diamond crystals were grown on silicon substrates with a high growth rate of ∼139 µm/hr. Diamond crystals up to 5 mm in height and 1 mm in diameter were grown in open air in 36 hours. Sharp Raman peak at 1332 cm^-1 with a full width at half maximum value around 4.5cm^-1 and distinct X-ray diffraction spectra indicate the high quality of the diamond crystals.