The burgeoning interest in sub-wavelength metal optics is fueled by applications ranging from cancer therapy and proteomics to opto-electronics and novel photovoltaic materials. The optical properties of nanoscale metallic structures are determined not only by the electromagnetics of localized and propagating surface plasmons, but also by the details of metal nanoparticle size, shape and spatial arrangement, and dielectric environment. This paper presents several ways in which interesting plasmonic structures and applications are made possible by nanoscale materials synthesis and structuring techniques based on pulsed laser and electron-beam deposition, electron-beam lithography and focused ion-beam nanomachining. Examples include (1) using a focused ion beam to create arrays of subwavelength holes in which the extraordinary optical transmission effect can be switched; (2) fabricating gold::VO2 composite nanoparticles to measure the size dependence of the metal-insulator transition in vanadium dioxide using surface-enhanced Raman scattering; and (3) the construction of heterostructures in which excitons can be coupled to surface plasmons.

1.
S.
Maier
,
Plasmonics: Fundamentals and Applications
(
Springer
,
New York
,
2007
).
2.
C. F.
Bohren
,
D. R.
Huffman
,
Absorption and Scattering of Light by Small Particles
(
John Wiley and Sons
,
New York
,
2004
).
3.
T. W.
Ebbesen
,
H. J.
Lezec
,
H. F.
Ghaemi
,
T.
Thio
,
P. A.
Wolff
(
1998
)
Extraordinary optical transmission through sub-wavelength hole arrays
,
Nature
391
,
667
.
4.
C.
Genet
,
T. W.
Ebbesen
(
2007
)
Light in tiny holes
,
Nature
445
,
39
.
5.
H. F.
Ghaemi
,
T.
Thio
,
D. E.
Grupp
,
T. W.
Ebbesen
,
H. J.
Lezec
(
1998
)
Surface plasmons enhance optical transmission through subwavelength holes
,
Phys. Rev. B
58
,
6779
.
6.
H.
Ditlbacher
,
J. R.
Krenn
,
G.
Schider
,
A.
Leitner
,
F. R.
Aussenegg
(
2002
)
Two-dimensional optics with surface plasmon polaritons
,
Applied Physics Letters
81
,
1762
.
7.
S. A.
Darmanyan
,
A. V.
Zayats
(
2003
)
Light tunneling via resonant surface plasmon polariton states and the enhanced transmission of periodically nanostructured metal films: An analytical study
,
Phys. Rev. B
67
,
035424
.
8.
A.
Degiron
,
H. J.
Lezec
,
W. L.
Barnes
,
T. W.
Ebbesen
(
2002
)
Effects of hole depth on enhanced light transmission through subwavelength hole arrays
,
Appl. Phys. Lett.
81
,
4327
.
9.
M.
Imada
,
A.
Fujimori
,
Y.
Tokura
(
1998
)
Metal-insulator transitions
,
Reviews of Modern Physics
70
,
1039
.
10.
S.
Biermann
,
A.
Poteryaev
,
A. I.
Lichtenstein
,
A.
Georges
(
2005
)
Dynamical singlets and correlation-assisted Peierls transition in VO2
,
Phys. Rev. Lett.
94
,
026404
.
11.
M.
Rini
,
A.
Cavalleri
,
R. W.
Schoenlein
,
R.
Lopez
,
L. C.
Feldman
,
R. F.
Haglund
,
L. A.
Boatner
,
T. E.
Haynes
(
2005
)
Photoinduced phase transition in VO2 nanocrystals: ultrafast control of surface-plasmon resonance
,
Optics Letters
30
,
558
.
12.
J. Y.
Suh
,
R.
Lopez
,
L. C.
Feldman
,
R. F.
Haglund
(
2004
)
Semiconductor to metal phase transition in the nucleation and growth of VOnanoparticles and thin films
,
J. Appl. Phys.
96
,
1209
.
13.
H. W.
Verleur
,
A. S.
Barker
,
C. N.
Berglund
(
1968
)
Optical Properties of VO2 between 0.25 and 5 eV
,
Physical Review
172
,
788
.
14.
K. L.
van der Molen
,
F. B.
Segerink
,
N. F.
van Hulst
,
L.
Kuipers
(
2004
)
Influence of hole size on the extraordinary transmission through subwavelength hole arrays
,
Appl. Phys. Lett.
85
,
4316
.
15.
D. S.
Kim
,
S. C.
Hohng
,
V.
Malyarchuk
,
Y. C.
Yoon
,
Y. H.
Ahn
,
K. J.
Yee
,
J. W.
Park
,
J.
Kim
,
Q. H.
Park
,
C.
Lienau
(
2003
)
Microscopic origin of surface-plasmon radiation in plasmonic band-gap nanostructures
,
Phys. Rev. Lett.
91
,
143901
.
16.
S. G.
Tikhodeev
,
A. L.
Yablonskii
,
E. A.
Muljarov
,
N. A.
Gippius
,
T.
Ishihara
(
2002
)
Quasiguided modes and optical properties of photonic crystal slabs
,
Phys. Rev. B
66
,
045102
.
17.
E. U.
Donev
,
J. Y.
Suh
,
F.
Villegas
,
R.
Lopez
,
R. F.
Haglund
,
L. C.
Feldman
(
2006
)
Optical properties of subwavelength hole arrays in vanadium dioxide thin films
,
Phys. Rev. B
73
,
201401
.
18.
E. D.
Palik
,
Handbook of optical constants of solids
(
Academic Press
,
Orlando
,
1985
).
19.
A.
Cavalleri
,
T.
Dekorsy
,
H. H. W.
Chong
,
J. C.
Kieffer
,
R. W.
Schoenlein
(
2004
)
Evidence for a structurally-driven insulator-to-metal transition in VO2: A view from the ultrafast timescale
,
Physical Review B
70
,
161102
.
20.
Y. F.
Zhang
,
R. E.
Russo
,
S. S.
Mao
(
2005
)
Quantum efficiency of ZnO nanowire nanolasers
,
Applied Physics Letters
87
,
043106
.
21.
H.
Zhou
,
M.
Wissinger
,
J.
Fallert
,
R.
Hauschild
,
F.
Stelzl
,
C.
Klingshirn
,
H.
Kalt
(
2007
)
Ordered, uniform-sized ZnO nanolaser arrays
,
Applied Physics Letters
91
,
181112
.
22.
S. J.
Pearton
,
D. P.
Norton
,
K.
Ip
,
Y. W.
Heo
,
T.
Steiner
(
2005
)
Recent progress in processing and properties of ZnO
,
Progress in Materials Science
50
,
293
.
23.
X. L.
Wu
,
G. G.
Siu
,
C. L.
Fu
,
H. C.
Ong
(
2001
)
Photoluminescence and cathodoluminescence studies of stoichiometric and oxygen-deficient ZnO films
,
Applied Physics Letters
78
,
2285
.
24.
C. W.
Lai
,
J.
An
,
H. C.
Ong
(
2005
)
Surface-plasmon-mediated emission from metal-capped ZnO thin films
,
Applied Physics Letters
86
.
25.
H. Y.
Lin
,
Y. F.
Chen
(
2006
)
Giant enhancement of luminescence induced by second-harmonic surface plasmon resonance
,
Applied Physics Letters
88
,
101914
.
26.
J. M.
Lin
,
H. Y.
Lin
,
C. L.
Cheng
,
Y. F.
Chen
(
2006
)
Giant enhancement of bandgap emission of ZnO nanorods by platinum nanoparticles
,
Nanotechnology
17
,
4391
.
27.
P. H.
Cheng
,
D. S.
Li
,
D.
Yang
(
2008
)
Influence of substrates in ZnO devices on the surface plasmon enhanced light emission
,
Optics Express
16
,
8896
.
28.
P. H.
Cheng
,
D. S.
Li
,
Z. Z.
Yuan
,
P. L.
Chen
,
D. R.
Yang
(
2008
)
Enhancement of ZnO light emission via coupling with localized surface plasmon of Ag island film
,
Appl. Phys. Lett.
92
,
041119
.
29.
M. K.
Lee
,
T. G.
Kim
,
W.
Kim
,
Y. M.
Sung
(
2008
)
Surface plasmon resonance (SPR) electron and energy transfer in noble metal-zinc oxide composite nanocrystals
,
Journal of Physical Chemistry C
112
,
10079
.
30.
A.
Neogi
,
C. W.
Lee
,
H. O.
Everitt
,
T.
Kuroda
,
A.
Tackeuchi
,
E.
Yablonovitch
(
2002
)
Enhancement of spontaneous recombination rate in a quantum well by resonant surface plasmon coupling
,
Phys. Rev. B
66
,
153305
.
31.
B. J.
Lawrie
,
R. F.
Haglund
,
R.
Mu
(
2009
)
Enhancement of ZnO photoluminescence by localized and propagating surface plasmons
,
Optics Express
17
,
2565
.
32.
H. Y.
Lin
,
C. L.
Cheng
,
Y. Y.
Chou
,
L. L.
Huang
,
Y. F.
Chen
,
K. T.
Tsen
(
2006
)
Enhancement of band gap emission stimulated by defect loss
,
Optics Express
14
,
2372
.
33.
R. F.
Haglund
,
B. J.
Lawrie
,
R.
Mu
(
2010
)
Coupling of photoluminescent centers in ZnO to localized and propagating surface plasmons
,
Thin Solid Films
518
,
4637
4643
.
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