Multi-oxidized thin films were fabricated by applying laser color marking technique on a stainless steel surface with laser irradiation using an YVO4 pulsed-laser at 30 kHz in atmospheric conditions. These multi-oxidized thin films emitted several colors including purple, violet, ultramarine, orange, and green. Using this technique, these mono-colors were produced on the surface according to the scanning repetition number and laser power. Results of XRD analyses for the colored areas showed several types of oxides consisting of FeO, Fe3O4, CrO, Cr2O3, Cr3O4, NiO, Ni2O3, NiCr2O4, and their mixed oxides, which consisted of oxygen vacancy structures. Each of these oxides has its original color for each composition and structure if the mono-phase area producing it shows clear mono-color corresponding to the composition and structure.

1.
Perez del Pino
,
A.
,
Fernandez-Pradas
,
J.M.
,
Serra
,
P.
, &
Morenza
,
J.L.
(
2004
)
Coloring of titanium through laser oxidation: comparative study with anodizing
.,
Surface Coating Technology
187
, 106112.
2.
Shinada
,
M.
,
Tanabe
,
I.
,
Takahashi
,
S.
, &
Itagaki
,
K.
(
2006
)
Trans. Jap. Soc. Mech. Eng.
,
72
,
235
. in Japanese.
3.
Bikiaris
,
D.
,
Sister
Daniilia
,
Sotiropoulou
,
S.
,
Katsimbiri
,
O.
,
Pavlidou
,
E.
,
Moutsatsou
,
A.P.
&
Chryssoulakis
,
Y.
Spectrochimica (
1999
)
Ochre-differentiation through micro-Raman and micro-FTIR spectroscopies: application on wall paintings at meteora and mount athos
,
Greece, Acta Part A
56
,
3
18
.
4.
Dumitrache
,
F.
,
Morjan
,
I.
,
Alexandrescu
,
R.
,
Ciupina
,
V.
,
Prodan
,
G.
,
Voicu
,
I.
,
Fleaca
,
C.
,
Albu
,
L.
,
Savoiu
,
M.
,
Popovici
,
E.
&
Soare
,
I.
(
2005
)
Iron-iron oxide core-shell nanoparticles synthesized by laser pyrolysis followed by superficial oxidation
,
Applied Surface Science
247
,
25
31
.
5.
Stefanic
,
G.
,
Didovic
,
M.
and
Music
,
S.
(
2007
)
The influence of thermal treatment on the phase development of ZrO2-NiO precursors
,
Journal of Molecular Structure
834-836
,
435
444
.
6.
Mullet
,
M.
,
Demoisson
,
F.
,
Humbert
,
B.
,
Michot
,
L. J.
&
Vantelon
,
D.
(
2007
)
Aqueous Cr(VI) reduction by pyrite: speciation and characterization of the solid phases by X-ray photoelectron, Raman and X-ray absorption spectroscopies
.
Geochimica et Cosmochimica Acta
71
,
3257
3271
.
7.
Ningshen
,
S.
,
Kamachi Mudali
,
U.
,
Mittal
,
V.K.
&
Khatak
,
H.S.
(
2007
)
Semiconducting and passive film properties of nitrogen-containing type 316 LN stainless steel
,
Corr. Science
49
,
481
496
8.
Kim
,
K.J.
,
Moon
,
D.W.
,
Lee
,
S.K.
&
Jung
,
K-H.
(
2000
)
Formation of a highly oriented FeO thin film by phase transition of Fe3O4 and Fe nanocrystallines
.
Thin Solid Films
,
360
,
118
121
.
9.
Harish
,
C.
,
Barshilia
,
N.
,
Selvakumar
,
B.
,
Deepthi
,
K.
&
Rajam
,
S.
(
2006
)
A comparative study of reactive direct current magnetron sputtered CrAlN and CrN coatings
,
Surface Coating Technology
201
,
2193
2201
.
10.
Sainio
,
J.
,
Aronniemi
,
M.
,
Pakarinen
,
O.
,
kauraala
,
K.
,
Airaksinen
,
S.
,
Krause
,
O.
&
Lahtinen
,
J.
(
2005
)
An XPS study of CrOx on a thin alumina film and in alumina supported catalysts
,
Applied Surface Science
,
252
,
1076
1083
.
11.
Cheng
,
J.
,
Cao
,
G.-P.
&
Yang
,
Y.-S.
(
2006
)
Characterization of sol-gel-derived NiOx xerogels as supercapacitors
,
Journal of Power Sources
159
,
734
741
.
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