Due to its inherent versatility and advantageous operating characteristics, the high power diode laser (HPDL) is being recognised as an appropriate tool for many engineering tasks. This work details the characteristics and feasibility of a technique to remove industrial epoxy grout using a 120W HPDL. The highest removal rate was achieved with an O2 process gas owing to the high reactive nature of the gas. A threshold power density of approximately 300 W/cm2 was found to exist below which removal did not occur. Furthermore, the minimum interaction time, below which there was no removal of epoxy tile grout, was found to be approximately 0.5 s. The maximum theoretical removal rate that may be achievable using the HPDL was calculated as being 66 mm2/s. A microstructural analysis revealed significant differences in the epoxy grout surface structure before and after the HPDL radiation. The surface of the HPDL-treated samples exhibited a collection of grouped particles with pores and gaps, whereas the untreated samples displayed a continuous monostructured plane surface. Energy dispersive X-ray (EDX) and X-ray diffraction (XRD) analyses revealed changes in the chemical composition of the epoxy grout after the HPDL radiation. In particular, CaO and CO2 were found in the HPDL treated samples resulting from decomposition of CaCO3 (limestone). In addition, SiO2 that existed in the un-treated epoxy grout material was not detected after HPDL processing due to the compound verification. A thermogravimetric and differential thermal analysis (TG-DTA) identified a sequence of thermal history for the epoxy grout which therefore allowed the prediction of the reactions that occur in the epoxy grout due to HPDL interaction.

1.
Li
L
,
Lawrence
J
,
Spencer
JT.
Proceedings of SPIE 1997
:
Laser and Optics in Manufacturing
,
1997
, Vol.
3097
p.
600
611
2.
Peligrad
AA
,
Schmidt
MJJ
,
Li
L
,
Spencer
J T.
Optics & Laser Technology
2000
;
32
:
49
57
.
3.
Li
L
,
Lawrence
J
,
Spencer
JT.
Processing of ICALEO 96
:
LIA Laser Material Processing
,
1996
, Vol.
81
E p.
38
47
.
4.
Gilbert
G.
Proceeding of the Institute of Physics: Quantum Electronics Group Meeting
,
Direct Applications of High Power Laser Diode
,
London, UK
, Vol.
1
,
1995
.
5.
Spalding
IJ.
Non-metallic materials: an introduction
,
Proceedings of Applied Laser Tooling
,
O.D.D.
Soares
/
M.
Perez-Amor
ed.,
1987
. p.
81
94
.
6.
Powell
J
,
I.A.
Menzies
IA,
Scheyvaerts
PF
,
Steen
WM
, CO2 laser cutting of non-metallic materials,
laser in Manufacturing
.
Bedford, U.K
.:
IFS publications ltd.
,
1987
, p.
69
82
.
7.
Academician
B
,
Bakradze
VN
,
Glotov
EP
,
Danilychev
VA
,
Meparishvili
GV
,
Modebadze
OE
,
Khachapuridze
TS
,
Yugov
VI
.
Sov. Phy. Dokl.
1986
;
31
(
2
):
172
173
.
8.
Lawrence
J
,
Li
L
,
Spencer
JT.
The 15th International Congress on Application of Lasers and Electro Optics (ICALEO ’96): Material Processing
,
Detroit, MI., USA
,
1996
, Vol.
81 A
,
1996
, p.
105
114
.
9.
Pires
M
,
Ferreira
A
,
Ribeiro
M
,
Teixeira
R
,
Rodrigues
C.
Proceedings of SPIE
:
Laser Technologies in Industries
Vol.
952
,
1998
, p.
622
625
.
10.
Kumar
M
,
Biawas
AK
,
Sriniwas
K
,
Nath
AK.
Proceedings of SPIE
: Vol.
2374
,
1995
, p.
34
39
11.
Sugita
K
,
Mori
M
,
Fujioka
T.
Concrete Eng.
1986
;
24
:
13
.
12.
Yoshizawa
H
,
Wignarajah
S
,
Saito
H.
Trans. Japan Welding Soc
1989
;
20
:
31
.
13.
Sugimoto
K
,
Wignarajah
S
,
Nagasi
K
,
Yasu
S.
Proc. of ICALEO ’90
:
Laser Materials Processing
,
Boston, USA
,
1990
. p.
302
.
14.
Borodina
TI
,
Valyano
GE
,
Ibragimov
NI
,
Pakhomov
EP
,
Romanov
AI
,
Smirnova
LG
,
Khabibulaev
PK
.
J. Phys. and Chem. of Mater. Treatment
1995
;
25
:
541
.
15.
Wignarajah
S
,
Sugimoto
K
,
Nagai
K.
Proc. of ICALEO ’92
:
Laser Materials Processing
,
Orlando, USA
,
1992
. p.
383
.
16.
Lawrence
J.
The characteristics and Feasibility of a two stage ceramic tile grout sealing process using a high power diode laser
” April
1999
, UMIST Manchester
17.
Lawrence
J
,
Li
L.
Proc. of ICALEO ’99
:
Laser Materials Processing
,
Orlando, USA
,
1999
. p.
334
.
18.
Lawrence
J
,
Li
L.
Mater. Sci. Eng. A
2000
;
284
:
93
.
19.
Lawrence
J
,
Li
L.
Mater. Sci. Eng. A
2000
;
287
:
25
.
20.
Lawrence
J
,
Li
L.
J. Laser Apps.
2000
;
72
:
8
.
21.
Lawrence
J
,
Li
L.
The 18th International Congress on Application of Laser and Electro-Optics (ICALEO, 99’)
:
Materials Processing
,
San Diego, CA., USA
,
1999
. Vol
87
B, p.
108
117
.
22.
Savina
M
,
Xu
Z
,
Wong
Y
,
Pellin
M
,
Leong
K.
Journal of Laser Application
1999
; Vol.
11
No.
6
:
284
287
.
23.
Sugimoto
K
,
Wignarajah
S
,
Nagase
K
,
Yasu
S
,
Kimura
K
,
Kasuya
M
,
Kureha
S.
Proceedings of ICALEO 1990: Laser Material Processing
,
Boston, MA
,
1990
. Vol.
71
, p.
302
312
.
24.
Cooper
MI
,
Emmony
DC
,
Larson
J.
The Journal of Photographic Science
1992
;
40
:
55
57
.
25.
Cooper
MI
,
Emmony
DC
,
Larson
J.
Optics and Laser Technology
1995
;
27
(
1
):
69
73
.
26.
Cooper
MI
,
Emmony
DC
,
Larson
J.
The Journal of Photographic Science
1992
;
40
:
55
57
.
27.
Cooper
MI
,
Emmony
DC
,
Larson
J.
Optics & Laser Technology
1995
;
27
(
1
):
69
73
.
28.
Lazzarini
L
,
Asmus
JF.
Bulletin of AIC
1973
;
13
:
23
46
.
29.
Asmus
JF
,
Zetler
MJ.
Lithoclastia
1976
;
1
:
23
45
.
30.
Ready
JF
, Industrial Applications of Lasers, 2nd ed.
San Diego; London
;
Academic Press
,
1977
.
31.
Johnston
EP
,
Shannon
G
,
Steen
WM
,
Jones
DR
,
Spencer
JT.
Proceedings of ICALEO ’98
:
Orlando, Florida
, November 12-19, Vol.
85
Section A,
1998
. p.
210
218
.
32.
Morishita
Y
,
Tanimoto
K
,
Komuro
T
,
Zaitsu
T.
Proceedings of ICONE 5: The 5th International Conference on Nuclear Engineering
, May 26-30,
Nice, France
,
1997
. p.
2609
33.
Schmidt
MJJ
,
Li
L
,
Spencer
JT.
Optics & Laser Technology
1999
;
31
(
2
):
171
80
.
34.
Minami
K
,
Lawrence
J
,
Li
L
,
Edwards
RE
,
Gale
AW.
Proceeding of E-MRS 2001: Symposium L
,
5-8 June
,
Strasbourg, France
,
2001
. (to be published)
35.
Abbott
DH
,
Albright
CE.
J. Laser Apps.
1994
;
6
:
69
.
36.
Bagger
C
,
Broden
G
,
Beske
E
,
Olsen
F.
Int. J. Joining of Mater.
1994
;
6
:
68
.
37.
Low
DKY
,
Li
L
,
Corfe
AG
.
J. Eng. Manuf.
2000
;
259
:
42
.
38.
Bever
B.
Encyclopaedia of materials Science and engineering
, Vol.
4
.
Massachusetts, USA
:
1986
, p.
1038
.
39.
Brydson
JA.
Plastics Materials
, sixth ed.
London
:
Butterworth, Heinemann
,
1995
, p.
404
.
40.
Hewlett
PC.
LEA’S chemistry of cement and concrete
, fourth ed.
London
:
Arnold
,
1988
, p. 228, 274,
305
307
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