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recoupling and decoupling

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Book Cover Image
Series: AIPP Books, Principles
Published: October 2020
10.1063/9780735422209
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
10.1063/9780735422209_frontmatter
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
...Frontmatter solid state NMR recoupling and decoupling NMR spectroscopy PREFACE Over 60 years ago, Andrew and Lowe introduced magic angle spinning (MAS) to suppress dipolar interactions. Since then, numerous theoretical and experimental developments have sprouted around this operation. Now...
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
0
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
...: Application to heteronuclear decoupling ,” J. Chem. Phys.   111 ( 4 ), 1511 – 1519 ( 1999 ). 10.1063/1.479410 5 A.   Brinkmann , M.   Edén , and M. H.   Levitt , “ Synchronous helical pulse sequences in magic-angle spinning nuclear magnetic resonance: Double quantum recoupling...
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
0
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
.... C.   Nielsen , “ Broadband dipolar recoupling in the nuclear magnetic resonance of rotating solids: A compensated C7 pulse sequence ,” J. Chem. Phys.   108 ( 7 ), 2686 – 2694 ( 1998 ). 10.1063/1.475661 3 M.   Hohwy , C. M.   Rienstra , C. P.   Jaroniec , and R. G...
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
0
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
... 14 M.   Ernst , S.   Bush , A. C.   Kolbert , and A.   Pines , “ Second-order recoupling of chemical-shielding and dipolar-coupling tensors under spin decoupling in solid-state NMR ,” J. Chem. Phys.   105 ( 9 ), 3387 – 3397 ( 1996 ). 10.1063/1.472224 15 I...
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
0
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
...) ( Academic Press , 1976 ), p. 190 . 14 M.   Ernst , “ Heteronuclear spin decoupling in solid-state NMR under magic-angle sample spinning ,” J. Magn. Reson.   162 ( 1 ), 1 – 34 ( 2003 ). 10.1016/S1090-7807(03)00074-0 15 M.   Bak , J. T.   Rasmussen , and N...
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
10.1063/9780735422209_index
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
Images
C and R symmetry <span class="search-highlight">recoupling</span> pulse sequences. (a) The generic construction o...
Published: October 2020
FIG. 6.1 C and R symmetry recoupling pulse sequences. (a) The generic construction of a C symmetry sequence. Each C sequence occupies N rotor periods, comprising n C blocks. Each C block consists of a π/2–2π–3π/2 pulse group, where the middle 2π pulse carries a π phase shift relative to the π/2 and 3π/2 pulses. A subsequent C block carries an increment ϕ = 2π/n phase shift to its prior C block. (b) The generic construction of an R symmetry sequence. Each R sequence occupies 2N rotor periods, comprising n R blocks. Each R block consists of a ππ pulse group, where the second π pulse carries a π phase shift relative to the first π pulse. A subsequent R block carries an increment ϕ = 2π/n phase shift to its prior C block. (c) The SPC5 sequence comprises two sets of C sequences, each with five standard 3-pulse C blocks occupying two rotor periods. (d) The original C7 sequence comprises seven groups of two pulse C blocks occupying two rotor periods. (e) An example of SPC5 for the excitation of double quantum correlation along indirect dimension. Here, note that higher decoupling is employed during SPC5 periods, to ensure optimal conversion efficiency. More about this image found in C and R symmetry recoupling pulse sequences. (a) The generic construction o...
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
10.1063/9780735422209_006
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
... features along the indirect dimension, while they are dormant during direct detection dimension by MAS and decoupling. A variety of RF pulse sequences were designed for this purpose. In addition to artificially designed sequences, the recoupling effects exist intrinsically due to the interference effects...
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
0
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
0
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
10.1063/9780735422209_007
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
...Lee-Goldburg homonuclear and heteronuclear decoupling Floquet theory Overview of the Correlation Between the Spectral Resolution and Interactions Our prior discussion of recoupling has laid a good theoretical background for us to consider decoupling. These two topics are intimately related...
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
0
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
10.1063/9780735422209_001
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
10.1063/9780735422209_002
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
... decoupling and ssNMR recoupling sequences, such as in postC7 2 and SPC5. 3 One good trick used to help isolate the transmitter with large excitation RF pulses from the sensitive detection side is to use crossed diodes. Cross-diodes are constructed from a pair of silicon diodes anti...
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
10.1063/9780735422209_003
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
... resonance frequencies. It is impossible to set our spectrometer frequency to match all sites simultaneously. Hence, the presence of resonance offset is inevitable, and is a strong limiting factor for many recoupling and decoupling pulse sequences. So, what is the consequence of the resonance offset? Let us...
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
10.1063/9780735422209_004
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
..., or if the interaction is so weak that we can ignore it. However, they do not capture the complicated scenarios when interactions are present, as shown in Sec. 3.6. Numerous NMR pulse sequences and techniques, such as magic angle spinning (MAS), and a myriad of decoupling and recoupling sequences, have been designed...
Book Chapter
Series: AIPP Books, Principles
Published: October 2020
10.1063/9780735422209_005
EISBN: 978-0-7354-2220-9
ISBN: 978-0-7354-2221-6
..., 6 Mehring, 7 and Matti Maricq and Waugh, 8 and the Winterschool lecture notes (2008) in biomolecular ssNMR from C. P. Jaroniec: “Heteronuclear decoupling and recoupling,” and C. M. Rienstra: “Chemical shift anisotropy and multidimensional recoupling for uniformly labeled...
Images
Schematic plot for the characteristic current vs voltage curve of typical d...
Published: October 2020
FIG. 2.1 Schematic plot for the characteristic current vs voltage curve of typical diodes. The threshold and breakdown voltage values depend on the diode construction materials, and are not drawn to scale. More about this image found in Schematic plot for the characteristic current vs voltage curve of typical d...
Images
Quarter-wave cables and diodes are used in NMR circuit to achieve the desir...
Published: October 2020
FIG. 2.2 Quarter-wave cables and diodes are used in NMR circuit to achieve the desired impedance transformation between transmitter, probe, and receiver. (a) The voltage in the cable as a function of the length when the RF wavelength is comparable to the cable length. (b) Connection of cross-diode... More about this image found in Quarter-wave cables and diodes are used in NMR circuit to achieve the desir...