Rechargeable lithium-ion batteries (LIBs) are electrochemical energy-storage devices that are used in diverse applications ranging from small-sized consumer electronic devices to midsized electric vehicles to the large-scale electricity grid. In their basic form, an LIB cell contains two electrodes at which redox reactions occur during electrochemical cycling, an electrolyte that transports lithium-ions between the electrodes, and a separator that prevents the electrodes from contact with each other while allowing the movement of ions.

Commercial LIBs typically contain graphite as the electrochemically active material in the negative electrode. The graphite could be partially or fully replaced by silicon in next-generation, high energy density LIBs because the theoretical lithium storage capacity of silicon is about ten times greater than that of graphite. However, the commercialization of silicon-based electrodes has been hindered by the large volume changes (up to 320%) that result from the insertion/extraction of lithium-ions into/from silicon particles; graphite, in comparison, displays an ∼10% volume change. Additionally, the electrochemical alloying/dealloying with lithium fractures the silicon particles and increases their surface area, which in turn increases parasitic side-reactions that trap lithium-ions and degrades battery performance.

Various strategies are pursued to improve the performance and longevity of silicon-containing LIBs. Modifying the silicon particle surfaces to minimize reactivity with the electrolyte and maximize interactions with the polymer binder ranks high among these approaches. Utilizing coatings to enhance the electronic contact within the electrode matrix is especially important for silicon, given that these particles have an oxide surface layer that forms during material synthesis. Additionally, surface modification can also prevent H2 evolution reactions that occur during water-based electrode fabrication processes, which consume active material and, at large enough scales, can pose safety hazards (Ref. 1).

In this study, we report x-ray photoelectron spectroscopy data from various surface-modified silicon powders (Table I) obtained from a commercial vendor (Paraclete Energy, Inc.). The powders were produced by milling and contain Si particles with a mean diameter of ∼150 nm. Data are presented from Si particles coated with a thin carbonaceous layer (Si/C, Ref. 2) and from Si/C particles with additional coatings based on polyethylene glycol (PEG) (Ref. 3), polyvinylidene difluoride (PVdF) (Ref. 4), and perfluorooctene (PFO) (Ref. 5). Data from particles covered with only the native oxide layer (n-SiO, Ref. 6) are also reported here. Spectra from Si-based composite electrodes (Table II) based on the powders described above and containing carbon (for electronic conduction), graphite (for limiting the overall electrode expansion), and partially lithiated polyacrylic acid (LiPAA, for binding) are also included (Refs. 7–12). The LiPAA was prepared by titrating polyacrylic acid (PAA) with 1M LiOH in an aqueous solution; exchanging the protons with Li+ ions reduces coiling of the PAA polymer chains and improves their adhesion to the particles (Ref. 13).

TABLE I.

Si powders. C, F, O, and Si spectra were obtained from these powder materials.

PowderDescription
Si/C Si coated with 2.5 wt. % carbon 
Si/C/PEG Si coated with 2.5 wt. % carbon, further modified with 4 wt. % PEG 
Si/C/PVdF Si coated with 2.5 wt. % carbon, further modified with 4 wt. % PVdF 
Si/C/PFO Si coated with 2.5 wt. % carbon, further modified with 4 wt. % PFO 
n-SiO Si with native oxide layer 
PowderDescription
Si/C Si coated with 2.5 wt. % carbon 
Si/C/PEG Si coated with 2.5 wt. % carbon, further modified with 4 wt. % PEG 
Si/C/PVdF Si coated with 2.5 wt. % carbon, further modified with 4 wt. % PVdF 
Si/C/PFO Si coated with 2.5 wt. % carbon, further modified with 4 wt. % PFO 
n-SiO Si with native oxide layer 
TABLE II.

Anodes with Si (see Table I), graphite (Gr), carbon black (CB), and LiPAA.

ElectrodeSi type
(wt. %)
Gr
(wt. %)
CB
(wt. %)
LiPAA
(wt. %)
15Si/C Si/C, 15% 73 10 
70Si/C Si/C, 70% … 15 15 
90Si/C Si/C, 90% … … 10 
70Si/C/PEG Si/C/PEG, 70% … 15 15 
70Si/C/PVdF Si/C/PVdF, 70% … 15 15 
70Si/C/PFO Si/C/PFO, 70% … 15 15 
ElectrodeSi type
(wt. %)
Gr
(wt. %)
CB
(wt. %)
LiPAA
(wt. %)
15Si/C Si/C, 15% 73 10 
70Si/C Si/C, 70% … 15 15 
90Si/C Si/C, 90% … … 10 
70Si/C/PEG Si/C/PEG, 70% … 15 15 
70Si/C/PVdF Si/C/PVdF, 70% … 15 15 
70Si/C/PFO Si/C/PFO, 70% … 15 15 

XPS measurements of the powder and anode samples were made using a Kratos Axis Ultra x-ray photoelectron spectrometer (Kratos Analytical, Inc., Manchester, UK) using monochromatic Al Kα radiation (1486.6 eV). High-resolution spectra were collected from a single spot at an emission angle of 0° at a pass energy of 40 eV from a 0.7 × 0.3 mm2 area using the hybrid (electrostatic and magnetic immersion) lens mode. The samples were affixed onto the conductive sample holder with an insulating double-sided transparent tape. The sample holder was then loaded onto the grounded sample stage. The binding energy scale of the instrument was calibrated using the Cu 2p (932.6 eV) and Au 4f (84.0 eV) photoelectron lines. The binding energies were referenced to the bulk Si 2p signal at 99.3 eV. The pressure during analysis was ∼7 × 10−7 Pa.

XPS data collected from the raw powders are shown in Figs. 1–4. As these materials are surface-modified silicon particles, it was anticipated that there may be differences in the chemical/electronic nature of the surface of the particles between the various materials. Therefore, the bulk Si 2p signal is used as an energy reference instead of the more typical —CC—, —CH signal. The spectra show products of oxidation of the particle surfaces, which occur during synthesis, as well as the carbon coatings formed during the surface modification process.

FIG. 1.

C 1s spectral comparison of the silicon-based Si/C, Si/C/PEG, Si/C/PVdF, Si/C/PFO, and n-SiO powders.

FIG. 1.

C 1s spectral comparison of the silicon-based Si/C, Si/C/PEG, Si/C/PVdF, Si/C/PFO, and n-SiO powders.

Close modal
FIG. 2.

Si 2p spectral comparison of the silicon-based Si/C, Si/C/PEG, Si/C/PVdF, Si/C/PFO, and n-SiO powders.

FIG. 2.

Si 2p spectral comparison of the silicon-based Si/C, Si/C/PEG, Si/C/PVdF, Si/C/PFO, and n-SiO powders.

Close modal
FIG. 3.

O 1s spectral comparison of the silicon-based Si/C, Si/C/PEG, Si/C/PVdF, Si/C/PFO, and n-SiO powders.

FIG. 3.

O 1s spectral comparison of the silicon-based Si/C, Si/C/PEG, Si/C/PVdF, Si/C/PFO, and n-SiO powders.

Close modal
FIG. 4.

F 1s spectral comparison of the silicon-based Si/C/PVdF and Si/C/PFO powders.

FIG. 4.

F 1s spectral comparison of the silicon-based Si/C/PVdF and Si/C/PFO powders.

Close modal

A comparison of the C 1s spectra collected from the powder materials is shown in Fig. 1. Overall, the spectra of the raw powders have fairly similar peak shapes. All materials show intensities at ∼285.1 [—CC—, —CH], ∼286.7 [—C—O], and ∼289.3 [O—C=O] eV. Intensities at ∼283.3 [SiC (1 < x < 2)] are also observed for all powders, except n-SiO. The fluorine-containing Si/C/PVdF- and Si/C/PFO-based particles show additional intensity for the C 1s spectra at ∼286.7 [—C—O], ∼289.1 [O—C=O], and for Si/C/PFO only, 291.6 [—CF2CF3], and ∼294.0 [—CF2CF3] eV. The absence of intensity at 290.0 eV [—(CF2CH2)n—] in the Si/C/PVdF-based particles suggests that the PVdF has decomposed during the particle modification process. The expectation of a variation of the chemical/electronic nature of the surfaces of these materials is confirmed by evidence of small differences in the position of the —CC—, —CH signal.

The Si 2p regions from the powder materials are compared in Fig. 2. The Si/C, Si/C/PEG, and n-SiO powders show intensities at ∼99.3 [Si], ∼100.5 [SiOy (1 < y < 2)], ∼102.6 [SiCxOy], and ∼103.3 [SiO2] eV. The fluorine-containing Si/C/PFO powder shows additional intensity in the Si 2p spectra at 102.8 eV [SiFz (1 < z < 4) (Ref. 14)].

The O 1s spectra collected from the powder materials, shown in Fig. 3, indicate intensities at ∼532.2 [—C=O, O—C=O, SiOy] and ∼533.5 [—C—O] eV. As the PEG- and PFO-based powders are the only ones with a carbon/oxygen containing additive, it is presumed that the additional oxygen signal in the C 1s spectra is due to oxidation that occurred during the particle synthesis process.

A comparison of the F 1s spectra from the raw Si/C/PVdF and Si/C/PFO powders is shown in Fig. 4. Signals were observed at ∼686.7 [SiFz (Ref. 14), SiOaFb] and ∼688.7 [CF2CF3] eV. Si/C/PFO powder shows a signal at 685.2 [NaF] possibly due to processing of the powder. The presence of signal due to SiFz in both the Si 2p and F 1s spectra from the Si/C/PFO-based powders suggests a Si—PFO side reaction occurred during the modification process.

Figures 5–8 show XPS data collected from electrodes made using the surface-modified silicon particles described above. These spectra show not only the constituent elements of the surface-modified silicon particles but also the other components used to fabricate the electrodes. A comparison of the C 1s spectra collected from the electrodes is shown in Fig. 5. The C 1s spectra of electrodes fabricated with the Si/C and Si/C/PEG materials show signals at ∼282.8 [SiCx (1 < x < 2)], ∼283.9 [graphite and carbon black], ∼285.3 [—CC—, —CH], ∼287.2 [—C—O], and 289.2 [O—C=O] eV. Electrodes fabricated using Si/C/PVdF and Si/C/PFO particles show contributions at ∼289.0 [O—C=O] and 293.9 [—CF2CF3] eV (Si/C/PFO only).

FIG. 5.

C 1s spectral comparison of the 15Si/C-, 70Si/C-, 90Si/C-, 70Si/C/PEG-, 70Si/C/PVdF-, and 70Si/C/PFO-based electrodes.

FIG. 5.

C 1s spectral comparison of the 15Si/C-, 70Si/C-, 90Si/C-, 70Si/C/PEG-, 70Si/C/PVdF-, and 70Si/C/PFO-based electrodes.

Close modal
FIG. 6.

Si 2p spectral comparison of the 15Si/C-, 70Si/C-, 90Si/C-, 70Si/C/PEG-, 70Si/C/PVdF-, and 70Si/C/PFO-based electrodes.

FIG. 6.

Si 2p spectral comparison of the 15Si/C-, 70Si/C-, 90Si/C-, 70Si/C/PEG-, 70Si/C/PVdF-, and 70Si/C/PFO-based electrodes.

Close modal
FIG. 7.

O 1s spectral comparison of the 15Si/C-, 70Si/C-, 90Si/C-, 70Si/C/PEG-, 70Si/C/PVdF-, and 70Si/C/PFO-based electrodes.

FIG. 7.

O 1s spectral comparison of the 15Si/C-, 70Si/C-, 90Si/C-, 70Si/C/PEG-, 70Si/C/PVdF-, and 70Si/C/PFO-based electrodes.

Close modal
FIG. 8.

F 1s spectral comparison of the 70Si/C/PVdF- and 70Si/C/PFO-based electrodes.

FIG. 8.

F 1s spectral comparison of the 70Si/C/PVdF- and 70Si/C/PFO-based electrodes.

Close modal

The Si 2p regions collected from electrodes fabricated with the surface-modified silicon particles are shown in Fig. 6. As signal from silicon comes only from the surface-modified particles, the spectra appear to be fairly similar to those of raw powders. The Si/C, Si/C/PEG, and n-SiO materials show intensities at ∼99.3 [Si], ∼100.5 [SiOy (1 < y < 2)], ∼102.3 [SiCxOy], and ∼103.4 [SiO2] eV. The fluorine-containing Si/C/PVdF- and Si/C/PFO-based electrodes show additional intensity in the spectra at 102.3 [SiCxOy, SiFz (1 < z < 4) (Ref. 14)] and 103.3 [SiO2, SiOaFb] eV.

The O 1s spectra collected from the electrodes fabricated with the surface-modified silicon particles are shown in Fig. 7. These spectra also appear to be fairly similar to those of raw particles. The spectra indicate intensities at ∼532.3 [—C=O, O—C=O, SiOy] and ∼533.6 [—C—O] eV. The F 1s spectra from the electrodes are shown in Fig. 8. Both the Si/C/PVdF-based and the Si/C/PFO-based electrodes indicate signals at ∼685.6 [LiF] and ∼686.7 [SiOaFb] eV. The Si/C/PFO-based electrode shows an additional signal at 688.8 [CF2, CF3] eV.

Surface quantification of the raw silicon-modified particles and the electrodes is summarized in Table III. In general, the elemental composition trends are as expected. The high C content observed on the n-SiO powder suggests that the silicon is covered by a carbonaceous compound that is likely a residue of the milling process used to produce the particles.

TABLE III.

Surface compositions of the powder and anode samples measured by XPS.

SampleF
(at. %)
O
(at. %)
C
(at. %)
Si
(at. %)
Si/C … 21.7 42.0 36.3 
Si/C/PEG … 17.2 66.7 16.1 
Si/C/PVdF 3.8 17.1 51.0 28.1 
Si/C/PFO 15.3 14.2 44.3 26.1 
n-SiO … 21.6 51.2 27.2 
15% Si/C … 21.3 68.9 9.9 
70% Si/C … 25.7 52.3 22.0 
90% Si/C … 29.7 34.6 35.7 
70% Si/C/PEG … 27.0 45.5 27.5 
70% Si/C/PVdF 4.0 28.4 43.2 24.5 
70% Si/C/PFO 12.1 23.1 43.0 21.8 
SampleF
(at. %)
O
(at. %)
C
(at. %)
Si
(at. %)
Si/C … 21.7 42.0 36.3 
Si/C/PEG … 17.2 66.7 16.1 
Si/C/PVdF 3.8 17.1 51.0 28.1 
Si/C/PFO 15.3 14.2 44.3 26.1 
n-SiO … 21.6 51.2 27.2 
15% Si/C … 21.3 68.9 9.9 
70% Si/C … 25.7 52.3 22.0 
90% Si/C … 29.7 34.6 35.7 
70% Si/C/PEG … 27.0 45.5 27.5 
70% Si/C/PVdF 4.0 28.4 43.2 24.5 
70% Si/C/PFO 12.1 23.1 43.0 21.8 

Stainless steel based 2032-type coin cells were used for the electrochemical tests. The cells contained the electrodes as shown in Table II along with a Li-metal counter electrode, Celgard 2325 separator, and an electrolyte with 10 wt. % FEC added to a solution of 1.2M LiPF6 in EC:EMC (3:7, w/w), where LiPF6 is lithium hexafluorophosphate, EC is ethylene carbonate, EMC is ethyl methyl carbonate, and FEC is fluoroethyl carbonate. The electrochemical tests were conducted at 30 °C using a MACCOR Series 4000 test unit; the cells were cycled in the 1.0–0.1 V range at an ∼C/25 rate.

The first cycle lithiation and delithiation capacities and coulombic efficiencies are given in Table IV; the associated cycling plots are given in Fig. 9. The specific capacities are based on the weight of all electrochemically active materials (silicon, graphite, and carbon black) in the electrode. As expected, the 15Si/C cell has the lowest capacity (and the highest coulombic efficiency) as the electrode has the lowest silicon content. The 90Si/C composition has the lowest coulombic efficiency possibly due to silicon particle disconnection from the electron conduction network after initial lithiation; unlike others, this electrode does not contain carbon black, which enables electron percolation through the matrix. All cells containing the 70Si/C material displayed good performance; the PVdF modified sample has a lower delithiation capacity than the noncoated electrode, whereas the PFO and PEG modified samples display improved performance. We postulate that these capacity differences arise from dissimilarities in the composition of the solid electrolyte interphases (SEIs) formed during the electrochemical cycle. Figure 10 shows the differential capacity (dQ/dV) peak associated with electrolyte reduction during the first cycle and SEI formation; peaks are present for all samples, except 90Si/C. In all cases, the peak is centered in the 1.0–1.1 V range, which is characteristic of FEC reduction. The small variations in peak location and intensity suggest subtle differences in electrolyte reduction (and possibly SEI composition) for various samples. The apparent lack of an ∼1.0 V peak for the 90Si/C sample may be from increased polarization (and hence delayed solvent reduction) resulting from the absence of carbon black in the electrode.

FIG. 9.

Electrode potential changes during first lithiation/delithiation of half-cells (i.e., vs a Li counter electrode) with the 15Si/C, 70Si/C, 90Si/C, 70Si/C/PEG, 70Si/C/PVdF, and 70Si/C/PFO electrodes. The cells were cycled in the 1.0–0.1 V range at ∼C/25 rate and 30 °C. The specific capacity was calculated using the weight of all active components (silicon, carbon black, and graphite) in the electrode.

FIG. 9.

Electrode potential changes during first lithiation/delithiation of half-cells (i.e., vs a Li counter electrode) with the 15Si/C, 70Si/C, 90Si/C, 70Si/C/PEG, 70Si/C/PVdF, and 70Si/C/PFO electrodes. The cells were cycled in the 1.0–0.1 V range at ∼C/25 rate and 30 °C. The specific capacity was calculated using the weight of all active components (silicon, carbon black, and graphite) in the electrode.

Close modal
FIG. 10.

Differential capacity (dQ/dV) as a function of voltage during the first lithiation of half-cells (i.e., Li counter electrode) with the 15Si/C, 70Si/C, 90Si/C, 70Si/C/PEG, 70Si/C/PVdF, and 70Si/C/PFO electrodes. The peak observed at ∼1.0–1.1 V is not observed during subsequent lithiation cycles.

FIG. 10.

Differential capacity (dQ/dV) as a function of voltage during the first lithiation of half-cells (i.e., Li counter electrode) with the 15Si/C, 70Si/C, 90Si/C, 70Si/C/PEG, 70Si/C/PVdF, and 70Si/C/PFO electrodes. The peak observed at ∼1.0–1.1 V is not observed during subsequent lithiation cycles.

Close modal
TABLE IV.

First cycle capacities and coulombic efficiencies of electrodes with Si.

ElectrodeSi type
(wt. %)
Lithiation
(mAh/g)
Delithiation
(mAh/g)
Coulombic efficiency
(%)
15Si/C Si/C, 15% 527 460 87.3 
70Si/C Si/C, 70% 1606 1375 85.7 
90Si/C Si/C, 90% 1823 962 52.8 
70Si/C/PVdF Si/C/PVdF, 70% 1554 1264 81.3 
70Si/C/PFO Si/C/PFO, 70% 2218 1904 85.8 
70Si/C/PEG Si/C/PEG, 70% 2098 1721 82.1 
ElectrodeSi type
(wt. %)
Lithiation
(mAh/g)
Delithiation
(mAh/g)
Coulombic efficiency
(%)
15Si/C Si/C, 15% 527 460 87.3 
70Si/C Si/C, 70% 1606 1375 85.7 
90Si/C Si/C, 90% 1823 962 52.8 
70Si/C/PVdF Si/C/PVdF, 70% 1554 1264 81.3 
70Si/C/PFO Si/C/PFO, 70% 2218 1904 85.8 
70Si/C/PEG Si/C/PEG, 70% 2098 1721 82.1 

This work was carried out in part at the Materials Research Laboratory Central Research Facilities, University of Illinois. The authors acknowledge support from the Office of Vehicle Technologies at the U.S. Department of Energy (DOE). The electrodes examined in these studies were fabricated at Argonne's Cell Analysis, Modeling and Prototyping (CAMP) Facility, which is supported within the core funding of the Applied Battery Research (ABR) for Transportation Program. The authors are grateful to Jeff Norris of Paraclete Energy for providing the silicon materials. The manuscript has been cocreated by UChicago Argonne, LLC, Operator of Argonne National Laboratory. The U.S. Government retains for itself, and others acting on its behalf, a paid-up nonexclusive, irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly and display publicly, by or on behalf of the Government.

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