Photoassisted molecular‐beam epitaxy (PAMBE), in which the substrate is illuminated during film growth has been successfully employed to prepare n‐type CdTe:In and p‐type CdTe:Sb films. The n‐type layers exhibit large electron mobilities at low temperatures. Field effect transistors have been fabricated from selected CdTe:In layers grown by PAMBE which show good device characteristics. The p‐type CdTe:Sb films exhibit bright photoluminescence of excitonic origin at low temperatures. At 300 K, hole mobilities of 81 cm2/V s and carrier concentrations in excess of 1018 cm3 have been achieved by the PAMBE technique.

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