Electron beam lithography (EBL) requires conducting substrates to ensure pattern fidelity. However, there is an increasing interest in performing EBL on less well-conducting surfaces or even insulators, usually resulting in seriously distorted pattern formation. To understand the underlying charging phenomena, the authors use Monte Carlo simulations that include models for substrate charging, electron beam-induced current, and electric breakdown. Simulations of electron beam exposure of glass wafers are presented, exposing regular patterns which become distorted due to charge-induced beam deflection. The resulting displacements within the patterns are mapped and compared to experimental displacement maps obtained from patterns in PMMA resist on glass substrates. Displacements up to several hundreds of nanometers were observed at a primary beam energy of 50 keV. Also, various scan strategies were used to write the patterns, in the simulations as well as the experiments, revealing their strong effect on pattern distortion, in shape and in magnitude. A qualitative, in some cases even quantitative, good agreement was found between the simulations and the experiments, providing enough confidence in Monte Carlo simulations to predict charge-induced pattern displacement and shape distortion and to find smart scan strategies to minimize the effects of charging.

1.
I.
Charaev
,
A.
Dane
,
A.
Agarwal
, and
K. K.
Berggren
,
IEEE Trans. Appl. Supercond.
29
,
1
(
2019
).
2.
Y.
Chen
,
Microelectron. Eng.
135
,
57
(
2015
).
3.
A. E.
Grigorescu
and
C. W.
Hagen
,
Nanotechnology
20
,
292001
(
2009
).
4.
V. R.
Manfrinato
,
L.
Zhang
,
D.
Su
,
H.
Duan
,
R. G.
Hobbs
,
E. A.
Stach
, and
K. K.
Berggren
,
Nano Lett.
13
,
1555
(
2013
).
5.
V. R.
Manfrinato
 et al,
Nano Lett.
14
,
4406
(
2014
).
6.
M.
Rommel
and
B. A.
Nilsson
,
Microelectron. Eng.
155
,
29
(
2016
).
7.
K. D.
Cummings
,
J. Vac. Sci. Technol. B
7
,
1536
(
1989
).
8.
A.
Aassime
,
F.
Hamouda
,
I.
Richardt
,
F.
Bayle
,
V.
Pillard
,
P.
Lecoeur
,
P.
Aubert
, and
D.
Bouchier
,
Microelectron. Eng.
110
,
320
(
2013
).
9.
Ş
Tirpanci
,
D. E.
Bürgler
,
C. M.
Schneider
,
B.
Rameev
, and
B.
Aktaş
,
Microelectron. Eng.
140
,
33
(
2015
).
10.
B.
Leibold
,
J.
Butschke
,
L.
Bettin
,
D.
Beyer
,
M.
Irmscher
,
C.
Koepernik
,
R.
Plontke
,
A.
Vix
, and
P.
Voehringer
,
Proc. SPIE
5256
,
1034
(
2003
).
11.
R.
Abargues
,
U.
Nickel
, and
P. J.
Rodríguez-Cantó
,
Nanotechnology
19
, 125302 (
2008
).
12.
B. D.
Myers
and
V. P.
Dravid
,
Nano Lett.
6
,
963
(
2006
).
13.
J.
Joo
,
B. Y.
Chow
, and
J. M.
Jacobson
,
Nano Lett.
6
,
2021
(
2006
).
14.
R.
Pintus
,
S.
Podda
, and
M.
Vanzi
,
IEEE Trans. Instrum. Meas.
57
,
989
(
2008
).
15.
H.
Itoh
,
J. Vac. Sci. Technol. B
9
,
3039
(
1991
).
16.
J.
Zhang
,
M.
Fouad
,
M.
Yavuz
, and
B.
Cui
,
Microelectron. Eng.
88
,
2196
(
2011
).
17.
R. J.
Hawryluk
,
H. I.
Smith
,
A.
Soares
, and
A. M.
Hawryluk
,
J. Appl. Phys.
46
,
2528
(
1975
).
18.
J. J.
Hwu
and
D. C.
Joy
,
Scanning
21
,
264
(
1999
).
19.
J. J.
Hwua
,
Y.
Ko
, and
D. C.
Joyatb
,
Control
3998
,
239
(
2000
).
20.
Y.
Ko
,
J. J.
Ha
, and
C.
David
,
Proc. SPIE
3998
,
694
(
2000
).
21.
K. T.
Arat
,
T.
Klimpel
, and
C. W.
Hagen
,
Proc. SPIE
10585
, 43 (
2018
).
22.
K. T.
Arat
,
J.
Bolten
,
T.
Klimpel
, and
N.
Unal
,
Proc. of SPIE
9778
,
97780C
(
2016
).
23.
E.
Kieft
and
E.
Bosch
,
J. Phys. D Appl. Phys.
41
,
215310
(
2008
).
24.
T.
Verduin
, “Quantum noise effects in E-beam lithography and metrology” Ph. D. thesis (
Delft University of Technology
,
2016
).
25.
Y.
Lin
and
D. C.
Joy
,
Surf. Interface Anal.
37
,
895
(
2005
).
26.
K. D.
Cummings
,
J. Vac. Sci. Technol. B
8
,
1786
(
1990
).
27.
H. J.
Fitting
,
H.
Glaefeke
, and
W.
Wild
,
Phys. Status Solidi
43
,
185
(
1977
).
28.
N.
Cornet
,
D.
Goeuriot
,
C.
Guerret-Piécourt
,
D.
Juvé
,
D.
Tréheux
,
M.
Touzin
, and
H.-J.
Fitting
,
J. Appl. Phys.
103
,
064110
(
2008
).
29.
M.
Aktary
,
M.
Stepanova
, and
S. K.
Dew
,
J. Vac. Sci. Technol. B
24
,
768
(
2006
).
30.
Q.
Dai
,
S. Y.
Lee
,
S. H.
Lee
,
B. G.
Kim
, and
H. K.
Cho
,
Microelectron. Eng.
88
,
3054
(
2011
).
31.
J. J.
Ritsko
,
L. J.
Brillson
,
R. W.
Bigelow
, and
T. J.
Fabish
,
J. Chem. Phys.
69
,
3931
(
1978
).
32.
R. F.
Egerton
,
S.
Lazar
, and
M.
Libera
,
Micron
43
,
2
(
2012
).
33.
R. F.
Egerton
,
P.
Li
, and
M.
Malac
,
Micron
35
,
399
(
2004
).
34.
K.
Zuiderveld
,
Graphics Gems IV
, edited by
P. S.
Heckbert
(
Academic
,
San Diego
,
CA
,
1994
), pp.
474
485
.
35.
See supplementary material at https://doi.org/10.1116/1.5120631 for a file that contains a MATLAB script for analysis of SEM micro-graphs of the study.

Supplementary Material

You do not currently have access to this content.