Infrared laser excitation has been utilized to excite part of a molecular beam of NO to a single well‐defined quantum state, NO(v=1, J=3/2, Ω=1/2), which is scattered from a cleaved LiF(100) surface. Laser spectroscopic detection techniques then allow the determination of rotational and electronic distributions as well as state‐specific angular and velocity distributions for scattering from a single initial vibrational‐rotational state.

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