In this article, the authors analyze the impact of germanium amorphization on the interface defect concentration of state of the art high-k metal gate metal-oxide-semiconductor field-effect transistors. The gate etch is a crucial process step for the high-k gate first integration approach. Germanium implantation is used to amorphize the annealed and, therefore, nanocrystalline hafnium silicon oxide. This ensures a well controlled wet etch removal. The quality of the gate oxide to the channel interface of the transistor samples is monitored by charge pumping. The influence of the damage caused by the germanium implant at the unprotected gate edge is analyzed for different gate stacks by measuring the gate induced drain leakage. The defect concentration at the gate edge can be reduced by adjusting the germanium amorphization energy.

1.
H. R.
Huff
 et al.,
Microelectron. Eng.
69
,
152
(
2003
).
2.
D.
Shamiryan
,
V.
Paraschiv
,
M.
Claes
, and
W.
Boullart
,
Proceedings of the NATO Advanced Research Workshop on Defects in Advanced High-k Dielectric Nanoelectronic Semiconductor Devices
, Russia,
2005
(unpublished), p.
331
.
3.
G.
Groeseneken
,
H. E.
Maes
,
N.
Beltran
, and
R. F.
De Keersmaecker
,
IEEE Trans. Electron Devices
31
,
42
(
1984
).
4.
T.
Hori
,
Dig. Tech. Pap. - Symp. VLSI Technol.
,
69
(
1990
).
5.
W. W.
Wang
,
K.
Akiyama
,
W.
Mizubayashi
,
T.
Nabatame
,
H.
Ota
, and
A.
Toriumi
,
J. Appl. Phys.
105
,
064108
(
2009
).
6.
C. -C.
Lu
,
K. -S.
Chang-Liao
,
C. -Y.
Lu
,
S. -C.
Chang
, and
T. -K.
Wang
,
Proceedings of the Semiconductor Device Research Symposium
(IEEE, New York,
2007
), p.
4422559
.
7.
P.
Masson
,
J. -L.
Autran
, and
J.
Brini
,
IEEE Electron Device Lett.
20
,
92
(
1999
).
8.
M. B.
Zahid
,
R.
Degraeve
,
J. F.
Zhang
, and
G.
Groeseneken
,
Microelectron. Eng.
84
,
1951
(
2007
).
9.
J. T.
Ryan
,
P. M.
Lenahan
,
G.
Bersuker
, and
P.
Lysaght
,
Appl. Phys. Lett.
90
,
173513
(
2007
).
10.
J. L.
Autran
,
B.
Bailand
, and
G.
Barbottin
,
Instabilities in Silicon Devices: New Insulators, Devices and Radiation Effects: Charge Pumping Techniques: Their Use for Diagnosis and Interface States in MOS Transistors
(
Elsevier
,
New York
,
1999
), Vol.
3
, Chap. 6, pp.
405
493
.
11.
J. -P.
Han
,
E. M.
Vogel
,
E. P.
Gusev
,
C.
D’Emic
,
C. A.
Richter
,
D. W.
Heh
, and
J. S.
Suehle
,
IEEE Electron Device Lett.
25
,
126
(
2004
).
12.
C. -T.
Sah
,
J. Y.-C.
Sun
, and
J. J.-T.
Tzou
,
J. Appl. Phys.
55
,
1525
(
1984
)
13.
O.
Ghobar
,
D.
Bauza
, and
B.
Guillaumot
,
Proceedings of the International Integrated Reliability Workshop
(IEEE, New York,
2007)
, p.
94
.
14.
F.
Gilibert
,
D.
Rideau
,
A.
Dray
,
F.
Agut
,
M.
Minondo
,
A.
Juge
,
P.
Masson
, and
R.
Bouchakour
,
IEICE Trans. Electron.
E88-C
,
829
(
2005
).
15.
I. -C.
Chen
,
C. W.
Teng
,
D. J.
Coleman
, and
A.
Nishimura
,
IEEE Electron Device Lett.
10
,
216
(
1989
).
16.
A.
Weber
, Ph.D. thesis,
Hamburg University of Technology
,
2007
.
You do not currently have access to this content.