Ferroelastic 90° -domain dynamics in epitaxial (lead zirconium titanate, PZT) films is investigated using lateral and vertical piezoelectric force microscopies. The PZT film consists of out-of-plane polarized -domains separated by a cross-hatch network of in-plane polarized -domains. When an electric field is applied across the PZT film, the -domains are rearranged on the nanoscale. Depending on the direction of the electric field, this results either in larger or more fragmented -domains. Both lateral and vertical piezoelectric force signals demonstrate the importance of ferroelastic -domain movement since their dynamics will determine the final polarization retention time and stability of ferroelectric capacitors.
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