The etching characteristics of parylene-N in a remote microwave oxygen plasma have been studied. The etch rate was measured over a range of pressures from 0.4 to 2.0 Torr and oxygen flow rates from 25 to 125 sccm using an applied plasma power of 250 W. In order to describe the etching behavior of the polymer as a function of different process parameters, a model has been developed to predict the concentration of reactive species at the polymer surface. The model uses two different plasma physics models to predict the net molecular oxygen dissociation rate in the microwave plasma. The species concentrations at the plasma outlet are used as the inlet condition for a model of the afterglow region, which includes a delivery tube and an etching chamber. The afterglow region is modeled using momentum and mass conservation equations. The predicted atomic oxygen concentrations at the polymer surface are inserted into a simple etch rate model and an etch rate is calculated and compared to etch rate data. The best agreement between theory and experiment was found using a plasma physics model developed by the Joint Institute for Laboratory Astrophysics and an etch rate model that has a reaction order of 0.5 with respect to the oxygen atom concentration.
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September 2002
This content was originally published in
Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena
Research Article|
October 04 2002
Etching parylene-N using a remote oxygen microwave plasma Available to Purchase
Russell Callahan;
Russell Callahan
Department of Chemical and Materials Engineering, Arizona State University, Tempe, Arizona 85287-6006
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Gregory Raupp;
Gregory Raupp
Department of Chemical and Materials Engineering, Arizona State University, Tempe, Arizona 85287-6006
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Stephen Beaudoin
Stephen Beaudoin
Department of Chemical and Materials Engineering, Arizona State University, Tempe, Arizona 85287-6006
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Russell Callahan
Department of Chemical and Materials Engineering, Arizona State University, Tempe, Arizona 85287-6006
Gregory Raupp
Department of Chemical and Materials Engineering, Arizona State University, Tempe, Arizona 85287-6006
Stephen Beaudoin
Department of Chemical and Materials Engineering, Arizona State University, Tempe, Arizona 85287-6006
J. Vac. Sci. Technol. B 20, 1870–1877 (2002)
Article history
Received:
December 20 2001
Accepted:
June 24 2002
Citation
Russell Callahan, Gregory Raupp, Stephen Beaudoin; Etching parylene-N using a remote oxygen microwave plasma. J. Vac. Sci. Technol. B 1 September 2002; 20 (5): 1870–1877. https://doi.org/10.1116/1.1501584
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