InxGa1−xP layers lattice matched and lattice mismatched to GaAs substrates have been grown by metalorganic chemical vapor deposition (MOCVD). Deep level transient spectroscopy, double crystal x‐ray diffraction, and current–voltage measurement were employed to characterize InxGa1−xP layers and InxGa1−xP/GaAs heterojunctions. We have observed a shallow electron trap located at EC−60 meV in InxGa1−xP layers with x<0.469, and a deep electron trap at EC−0.85 eV with x≳0.532. However, no deep levels were detected in InxGa1−xP (0.469<x<0.532) layers. The deep levels, if they exist, have a concentration of less than 5×1011 cm−3 which is the lowest deep level concentration reported so far in MOCVD grown InxGa1−xP materials. This is also the first observation in which lattice mismatches ranging from −0.125% to +0.224% (0.469<x <0.532) do not generate deep levels in MOCVD grown InxGa1−xP.

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