The studies of the growth mechanism of aluminide coatings by chemical vapor deposition (CVD) is an important prerequisite for optimizing the thermal protection properties of aluminide coatings and improving the CVD process parameters; however, the current research on the growth mechanism of CVD aluminide coatings on nickel-based alloys is relatively limited, and there is a lack of systematic studies in this area. In this work, aluminide coatings were prepared on the surface of nickel-based superalloys by the CVD method, and elemental diffusion and microstructure effects between coating and substrate at different deposition temperatures and times, as well as the growth kinetics and formation mechanism of CVD aluminide coatings were investigated. The results showed that the coating prepared on the surface of K444 nickel-based high-temperature alloy by CVD was an externally diffused aluminide coating with a bilayer structure: the outer layer of the coating was the β-NiAl phase. The interdiffusion layer was mainly composed of nickel-aluminum compounds, carbides, and topologically close-packed phase. The growth of the CVD aluminide coating was mainly controlled by the grain boundary diffusion mechanism.
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July 2023
Research Article|
May 31 2023
Studies on the growth mechanism of aluminide coating on K444 alloy surface by chemical vapor deposition Available to Purchase
Weijun Mo
;
Weijun Mo
(Conceptualization, Data curation, Investigation, Methodology, Validation, Writing – original draft, Writing – review & editing)
1
Special Glass Key Laboratory of Hainan Province, School of Materials Science and Engineering, Hainan University
, Haikou 570228, China
2
Key Laboratory of Marine New Materials and Related Technology, Zhejiang Key Laboratory of Marine Materials and Protection Technology, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences
, Ningbo 315201, China
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Mingpeng Shao;
Mingpeng Shao
(Investigation, Validation)
2
Key Laboratory of Marine New Materials and Related Technology, Zhejiang Key Laboratory of Marine Materials and Protection Technology, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences
, Ningbo 315201, China
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Yong Wu;
Yong Wu
(Funding acquisition, Investigation, Project administration, Validation)
3
Wuhan Research Institute of Materials Protection
, Wuhan 430030, China
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Qingyun Sun;
Qingyun Sun
(Investigation, Validation)
3
Wuhan Research Institute of Materials Protection
, Wuhan 430030, China
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Siyao Xia;
Siyao Xia
(Investigation, Validation)
3
Wuhan Research Institute of Materials Protection
, Wuhan 430030, China
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Feng Wen
;
Feng Wen
a)
(Conceptualization, Data curation, Funding acquisition, Project administration, Supervision, Writing – review & editing)
1
Special Glass Key Laboratory of Hainan Province, School of Materials Science and Engineering, Hainan University
, Haikou 570228, China
a)Author to whom correspondence should be addressed: [email protected]
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Yongxin Wang
Yongxin Wang
b)
(Conceptualization, Data curation, Funding acquisition, Project administration, Supervision, Writing – review & editing)
2
Key Laboratory of Marine New Materials and Related Technology, Zhejiang Key Laboratory of Marine Materials and Protection Technology, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences
, Ningbo 315201, China
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Weijun Mo
1,2
Mingpeng Shao
2
Yong Wu
3
Qingyun Sun
3
Siyao Xia
3
Feng Wen
1,a)
Yongxin Wang
2,b)
1
Special Glass Key Laboratory of Hainan Province, School of Materials Science and Engineering, Hainan University
, Haikou 570228, China
2
Key Laboratory of Marine New Materials and Related Technology, Zhejiang Key Laboratory of Marine Materials and Protection Technology, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences
, Ningbo 315201, China
3
Wuhan Research Institute of Materials Protection
, Wuhan 430030, China
a)Author to whom correspondence should be addressed: [email protected]
b)
Electronic mail: [email protected]
J. Vac. Sci. Technol. A 41, 043103 (2023)
Article history
Received:
March 08 2023
Accepted:
April 28 2023
Citation
Weijun Mo, Mingpeng Shao, Yong Wu, Qingyun Sun, Siyao Xia, Feng Wen, Yongxin Wang; Studies on the growth mechanism of aluminide coating on K444 alloy surface by chemical vapor deposition. J. Vac. Sci. Technol. A 1 July 2023; 41 (4): 043103. https://doi.org/10.1116/6.0002654
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