GaN/AlGaN, known as the third-generation semiconductor, is widely used in advanced power and RF devices. A precise and low-damage etch process is essential for the preparation of recessed-gate enhancement-mode GaN high electron mobility transistors. Atomic layer etching (ALE) offers novel opportunities during the ultraprecision manufacturing process by splitting etch process into a surface modification step and a modified layer removal step. In this work, two self-limiting AlGaN ALE systems (O2-BCl3 and chlorinate-argon) are reported in detail. The results of the two systems are analyzed and compared. This research provides a deep insight into the ALE mechanism of AlGaN and a broad cognition for applying ALE to engineering problems.

1.
M. N.
Yoder
,
IEEE Trans. Electron Devices
43
,
1633
(
1996
).
2.
T.
Paskova
and
K. R.
Evans
,
IEEE J. Sel. Top. Quantum Electron.
15
,
1041
(
2009
).
3.
S.
Zhu
,
M.
Mizuno
,
Y.
Kagawa
, and
Y.
Mutoh
,
Compos. Sci. Technol.
59
,
833
(
1999
).
4.
J.
Du
,
G.
Yu
,
Y.
Jia
,
Z.
Ni
,
X.
Gao
,
Y.
Song
, and
F.
Wang
,
Corros. Sci.
201
,
110263
(
2022
).
5.
M.
Li
,
G.
Li
,
J.
Jiang
,
Z. S.
Zhang
,
X.
Dai
, and
K. C.
Mai
,
J. Mater. Sci. Technol.
31
,
331
(
2015
).
6.
7.
A. S.
Strite
and
H.
Morkoç
,
J. Vac. Sci. Technol. B
10
,
1237
(
1992
).
8.
J.
Eichler
and
C.
Lesniak
,
J. Eur. Ceram. Soc.
28
,
1105
(
2008
).
9.
A. K.
Panda
,
D.
Pavlidis
, and
E.
Alekseev
,
IEEE Trans. Electron Devices
48
,
820
(
2001
).
10.
T.
Hashizume
,
S.
Ootomo
,
S.
Oyama
,
M.
Konishi
, and
H.
Hasegawa
,
J. Vac. Sci. Technol. B
19
,
1675
(
2001
).
11.
W.
Saito
,
Y.
Takada
,
M.
Kuraguchi
,
K.
Tsuda
,
I.
Omura
,
T.
Ogura
, and
H.
Ohashi
,
IEEE Trans. Electron Devices
50
,
2528
(
2003
).
12.
J. W.
Coburn
and
H. F.
Winters
,
J. Vac. Sci. Technol.
16
,
391
(
1979
).
13.
I.
Adesida
,
A.
Mahajan
,
E.
Andideh
,
M. A.
Khan
,
D.
Olsen
, and
J.
Kuznia
,
Appl. Phys. Lett.
63
,
2777
(
1993
).
14.
R.
Shul
et al,
Appl. Phys. Lett.
69
,
1119
(
1996
).
15.
K.
Fu
,
Z.
He
,
C.
Yang
,
J.
Zhou
,
H.
Fu
, and
Y.
Zhao
,
Appl. Phys. Lett.
121
,
092103
(
2022
).
17.
K. J.
Kanarik
,
T.
Lill
,
E. A.
Hudson
,
S.
Sriraman
,
S.
Tan
,
J.
Marks
,
V.
Vahedi
, and
R. A.
Gottscho
,
J. Vac. Sci. Technol. A
33
,
020802
(
2015
).
18.
H.-C.
Chiu
,
C.-W.
Yang
,
C.-H.
Chen
,
J. S.
Fu
, and
F.-T.
Chien
,
Appl. Phys. Lett.
99
,
153508
(
2011
).
19.
D.
Buttari
et al,
Appl. Phys. Lett.
83
,
4779
(
2003
).
20.
S. D.
Burnham
,
K.
Boutros
,
P.
Hashimoto
,
C.
Butler
,
D. W. S.
Wong
,
M.
Hu
, and
M.
Micovic
,
Phys. Status Solidi C
7
,
2010
(
2010
).
21.
F.
Le Roux
,
N.
Possémé
,
P.
Burtin
,
S.
Barnola
, and
A.
Torres
,
Microelectron. Eng.
228
,
111328
(
2020
).
22.
I. H.
Hwang
,
H. Y.
Cha
, and
K. S.
Seo
,
Coatings
11
,
268
(
2021
).
23.
T.
Ohba
,
W.
Yang
,
S.
Tan
,
K. J.
Kanarik
, and
K.
Nojiri
,
Jpn. J. Appl. Phys.
56
,
06HB06
(
2017
).
24.
C.
Kauppinen
,
S. A.
Khan
,
J.
Sundqvist
,
D. B.
Suyatin
,
S.
Suihkonen
,
E. I.
Kauppinen
, and
M.
Sopanen
,
J. Vac. Sci. Technol. A
35
,
060603
(
2017
).
25.
M.
Hasegawa
,
T.
Tsutsumi
,
A.
Tanide
,
S.
Nakamura
,
H.
Kondo
,
K.
Ishikawa
,
M.
Sekine
, and
M.
Hori
,
J. Vac. Sci. Technol. A
38
,
042602
(
2020
).
26.
S.
Aroulanda
et al,
J. Vac. Sci. Technol. A
37
,
041001
(
2019
).
27.
C.
Mannequin
,
C.
Vallée
,
K.
Akimoto
,
T.
Chevolleau
,
C.
Durand
,
C.
Dussarrat
,
T.
Teramoto
,
E.
Gheeraert
, and
H.
Mariette
,
J. Vac. Sci. Technol. A
38
,
032602
(
2020
).
28.
S.
Ruel
et al,
J. Vac. Sci. Technol. A
39
,
022601
(
2021
).
29.
L.
Guan
,
X.
Li
,
D.
Che
,
K.
Xu
, and
S.
Zhuang
,
J. Semicond.
43
,
113101
(
2022
).
30.
C.
Mannequin
,
C.
Vallée
,
K.
Akimoto
,
T.
Chevolleau
,
C.
Durand
,
C.
Dussarrat
,
T.
Teramoto
,
E.
Gheeraert
, and
H.
Mariette
,
J. Vac. Sci. Technol. A
38
,
032602
(
2020
).
31.
K. G.
Crawford
,
J.
Grant
,
D. T.
Hemakumara
,
X.
Li
,
I.
Thayne
, and
D. A.
Moran
,
J. Vac. Sci. Technol. A
40
,
042601
(
2022
).
32.
G.
Oehrlein
,
D.
Metzler
, and
C.
Li
,
ECS J. Solid State Sci.
4
,
N5041
(
2015
).
33.
K. J.
Kanarik
,
S.
Tan
, and
R. A.
Gottscho
,
J. Phys. Chem. Lett.
9
,
4814
(
2018
).
34.
H.
Kim
,
D.
Lee
,
J.
Lee
,
T.
Kim
, and
G.
Yeom
,
Vacuum
56
,
45
(
2000
).
35.
F.
González-Posada
,
J. A.
Bardwell
,
S.
Moisa
,
S.
Haffouz
,
H.
Tang
,
A. F.
Bra?A
, and
E.
Mu?Oz
,
Appl. Surf. Sci.
253
,
6185
(
2007
).
36.
K. J.
Kanarik
et al,
J. Vac. Sci. Technol. A
35
,
05C302
(
2017
).
37.
H.
Kaufman
,
J.
Cuomo
, and
J.
Harper
,
J. Vac. Sci. Technol.
21
,
725
(
1982
).
38.
See supplementary material for the XPS data of the deposited layer (Ga 3d, Al 2p, B 1s, Cl 2p, N 1s, and O 1s).
39.
M.
Leszczynski
et al,
Appl. Phys. Lett.
69
,
73
(
1996
).

Supplementary Material

You do not currently have access to this content.