GaN/AlGaN, known as the third-generation semiconductor, is widely used in advanced power and RF devices. A precise and low-damage etch process is essential for the preparation of recessed-gate enhancement-mode GaN high electron mobility transistors. Atomic layer etching (ALE) offers novel opportunities during the ultraprecision manufacturing process by splitting etch process into a surface modification step and a modified layer removal step. In this work, two self-limiting AlGaN ALE systems (O2-BCl3 and chlorinate-argon) are reported in detail. The results of the two systems are analyzed and compared. This research provides a deep insight into the ALE mechanism of AlGaN and a broad cognition for applying ALE to engineering problems.
REFERENCES
1.
M. N.
Yoder
, IEEE Trans. Electron Devices
43
, 1633
(1996
). 2.
T.
Paskova
and K. R.
Evans
, IEEE J. Sel. Top. Quantum Electron.
15
, 1041
(2009
). 3.
S.
Zhu
, M.
Mizuno
, Y.
Kagawa
, and Y.
Mutoh
, Compos. Sci. Technol.
59
, 833
(1999
). 4.
J.
Du
, G.
Yu
, Y.
Jia
, Z.
Ni
, X.
Gao
, Y.
Song
, and F.
Wang
, Corros. Sci.
201
, 110263
(2022
). 5.
M.
Li
, G.
Li
, J.
Jiang
, Z. S.
Zhang
, X.
Dai
, and K. C.
Mai
, J. Mater. Sci. Technol.
31
, 331
(2015
). 6.
P. R.
Chalker
, Thin Solid Films
343
, 616
(1999
). 7.
A. S.
Strite
and H.
Morkoç
, J. Vac. Sci. Technol. B
10
, 1237
(1992
). 8.
J.
Eichler
and C.
Lesniak
, J. Eur. Ceram. Soc.
28
, 1105
(2008
). 9.
A. K.
Panda
, D.
Pavlidis
, and E.
Alekseev
, IEEE Trans. Electron Devices
48
, 820
(2001
). 10.
T.
Hashizume
, S.
Ootomo
, S.
Oyama
, M.
Konishi
, and H.
Hasegawa
, J. Vac. Sci. Technol. B
19
, 1675
(2001
). 11.
W.
Saito
, Y.
Takada
, M.
Kuraguchi
, K.
Tsuda
, I.
Omura
, T.
Ogura
, and H.
Ohashi
, IEEE Trans. Electron Devices
50
, 2528
(2003
). 12.
J. W.
Coburn
and H. F.
Winters
, J. Vac. Sci. Technol.
16
, 391
(1979
). 13.
I.
Adesida
, A.
Mahajan
, E.
Andideh
, M. A.
Khan
, D.
Olsen
, and J.
Kuznia
, Appl. Phys. Lett.
63
, 2777
(1993
). 14.
R.
Shul
et al, Appl. Phys. Lett.
69
, 1119
(1996
). 15.
K.
Fu
, Z.
He
, C.
Yang
, J.
Zhou
, H.
Fu
, and Y.
Zhao
, Appl. Phys. Lett.
121
, 092103
(2022
). 16.
H.
Fu
et al, Mater. Today
49
, 296
(2021
). 17.
K. J.
Kanarik
, T.
Lill
, E. A.
Hudson
, S.
Sriraman
, S.
Tan
, J.
Marks
, V.
Vahedi
, and R. A.
Gottscho
, J. Vac. Sci. Technol. A
33
, 020802
(2015
). 18.
H.-C.
Chiu
, C.-W.
Yang
, C.-H.
Chen
, J. S.
Fu
, and F.-T.
Chien
, Appl. Phys. Lett.
99
, 153508
(2011
). 19.
D.
Buttari
et al, Appl. Phys. Lett.
83
, 4779
(2003
). 20.
S. D.
Burnham
, K.
Boutros
, P.
Hashimoto
, C.
Butler
, D. W. S.
Wong
, M.
Hu
, and M.
Micovic
, Phys. Status Solidi C
7
, 2010
(2010
). 21.
F.
Le Roux
, N.
Possémé
, P.
Burtin
, S.
Barnola
, and A.
Torres
, Microelectron. Eng.
228
, 111328
(2020
). 22.
I. H.
Hwang
, H. Y.
Cha
, and K. S.
Seo
, Coatings
11
, 268
(2021
). 23.
T.
Ohba
, W.
Yang
, S.
Tan
, K. J.
Kanarik
, and K.
Nojiri
, Jpn. J. Appl. Phys.
56
, 06HB06
(2017
). 24.
C.
Kauppinen
, S. A.
Khan
, J.
Sundqvist
, D. B.
Suyatin
, S.
Suihkonen
, E. I.
Kauppinen
, and M.
Sopanen
, J. Vac. Sci. Technol. A
35
, 060603
(2017
). 25.
M.
Hasegawa
, T.
Tsutsumi
, A.
Tanide
, S.
Nakamura
, H.
Kondo
, K.
Ishikawa
, M.
Sekine
, and M.
Hori
, J. Vac. Sci. Technol. A
38
, 042602
(2020
). 26.
S.
Aroulanda
et al, J. Vac. Sci. Technol. A
37
, 041001
(2019
). 27.
C.
Mannequin
, C.
Vallée
, K.
Akimoto
, T.
Chevolleau
, C.
Durand
, C.
Dussarrat
, T.
Teramoto
, E.
Gheeraert
, and H.
Mariette
, J. Vac. Sci. Technol. A
38
, 032602
(2020
). 28.
S.
Ruel
et al, J. Vac. Sci. Technol. A
39
, 022601
(2021
). 29.
L.
Guan
, X.
Li
, D.
Che
, K.
Xu
, and S.
Zhuang
, J. Semicond.
43
, 113101
(2022
). 30.
C.
Mannequin
, C.
Vallée
, K.
Akimoto
, T.
Chevolleau
, C.
Durand
, C.
Dussarrat
, T.
Teramoto
, E.
Gheeraert
, and H.
Mariette
, J. Vac. Sci. Technol. A
38
, 032602
(2020
). 31.
K. G.
Crawford
, J.
Grant
, D. T.
Hemakumara
, X.
Li
, I.
Thayne
, and D. A.
Moran
, J. Vac. Sci. Technol. A
40
, 042601
(2022
). 32.
G.
Oehrlein
, D.
Metzler
, and C.
Li
, ECS J. Solid State Sci.
4
, N5041
(2015
). 33.
K. J.
Kanarik
, S.
Tan
, and R. A.
Gottscho
, J. Phys. Chem. Lett.
9
, 4814
(2018
). 34.
H.
Kim
, D.
Lee
, J.
Lee
, T.
Kim
, and G.
Yeom
, Vacuum
56
, 45
(2000
). 35.
F.
González-Posada
, J. A.
Bardwell
, S.
Moisa
, S.
Haffouz
, H.
Tang
, A. F.
Bra?A
, and E.
Mu?Oz
, Appl. Surf. Sci.
253
, 6185
(2007
). 36.
K. J.
Kanarik
et al, J. Vac. Sci. Technol. A
35
, 05C302
(2017
). 37.
H.
Kaufman
, J.
Cuomo
, and J.
Harper
, J. Vac. Sci. Technol.
21
, 725
(1982
). 38.
See supplementary material for the XPS data of the deposited layer (Ga 3d, Al 2p, B 1s, Cl 2p, N 1s, and O 1s).
39.
M.
Leszczynski
et al, Appl. Phys. Lett.
69
, 73
(1996
). 2023 Published under an exclusive license by the AVS.
2023
Author(s)
You do not currently have access to this content.