Monomer precursor flow was introduced at an oblique angle to the substrate at two locations during the initiated chemical vapor deposition (iCVD) process using a branched nozzle inlet extension. The polymerization of methacrylic acid was systematically studied as a function of the nozzle length and the monomer flow rate. Our experimental data showed the evolution of two distinct symmetrical thickness profiles as the flow rate and nozzle length increased. The maximum thickness moved downstream along the axes of both nozzles as the flow rate and nozzle length increased. Computational models were used to study the effects of the nozzle length and the monomer flow rate on the velocity profile within the reactor. Increasing the monomer flow rate and the nozzle length resulted in increases in the velocity profile ranges and the movement of the location of the maximum velocity and local minimum velocity associated with the stagnation point. These velocity data provided insight for explaining the trends found in the experimental results. The data demonstrate the ability to use a branched nozzle inlet extension to control the location of polymer deposition during the iCVD process.
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Research Article|
March 15 2023
Branched nozzle oblique angle flow for initiated chemical vapor deposition Available to Purchase
Nicholas A. Welchert
;
Nicholas A. Welchert
(Conceptualization, Formal analysis, Investigation, Methodology, Project administration, Writing – original draft)
Mork Family Department of Chemical Engineering and Materials Science, University of Southern California
, 925 Bloom Walk, Los Angeles, California 90089
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Jay V. Swarup
;
Jay V. Swarup
(Formal analysis, Investigation, Methodology, Validation)
Mork Family Department of Chemical Engineering and Materials Science, University of Southern California
, 925 Bloom Walk, Los Angeles, California 90089
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Rohan S. Gupta
;
Rohan S. Gupta
(Investigation, Methodology)
Mork Family Department of Chemical Engineering and Materials Science, University of Southern California
, 925 Bloom Walk, Los Angeles, California 90089
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Malancha Gupta
Malancha Gupta
a)
(Conceptualization, Funding acquisition, Project administration, Supervision, Writing – review & editing)
Mork Family Department of Chemical Engineering and Materials Science, University of Southern California
, 925 Bloom Walk, Los Angeles, California 90089
Search for other works by this author on:
Nicholas A. Welchert
Jay V. Swarup
Rohan S. Gupta
Malancha Gupta
a)
Mork Family Department of Chemical Engineering and Materials Science, University of Southern California
, 925 Bloom Walk, Los Angeles, California 90089a)
Electronic mail: [email protected]
J. Vac. Sci. Technol. A 41, 033202 (2023)
Article history
Received:
November 13 2022
Accepted:
February 15 2023
Citation
Nicholas A. Welchert, Jay V. Swarup, Rohan S. Gupta, Malancha Gupta; Branched nozzle oblique angle flow for initiated chemical vapor deposition. J. Vac. Sci. Technol. A 12 May 2023; 41 (3): 033202. https://doi.org/10.1116/6.0002349
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