In this work, atomic layer etching (ALE) of thin film Ga-polar GaN(0001) is reported in detail using sequential surface modification by Cl2 adsorption and removal of the modified surface layer by low energy Ar plasma exposure in a standard reactive ion etching system. The feasibility and reproducibility of the process are demonstrated by patterning GaN(0001) films by the ALE process using photoresist as an etch mask. The demonstrated ALE is deemed to be useful for the fabrication of nanoscale structures and high electron mobility transistors and expected to be adoptable for ALE of other materials.

1.
C. M.
Huard
,
Y.
Zhang
,
S.
Sriraman
,
A.
Paterson
,
K. J.
Kanarik
, and
M. J.
Kushner
,
J. Vac. Sci. Technol., A
35
,
031306
(
2017
).
2.
D.
Hisamoto
 et al.,
IEEE Trans. Electron Devices
47
,
2320
(
2000
).
3.
K. T.
Park
 et al.,
IEEE J. Solid-State Circuits
50
,
204
(
2015
).
4.
K. J.
Kanarik
,
T.
Lill
,
E. A.
Hudson
,
S.
Sriraman
,
S.
Tan
,
J.
Marks
,
V.
Vahedi
, and
R. A.
Gottscho
,
J. Vac. Sci. Technol., A
33
,
020802
(
2015
).
5.
T.
Faraz
,
F.
Roozeboom
,
H.
Knoops
, and
W.
Kessels
,
ECS J. Solid State Sci. Technol.
4
,
N5023
(
2015
).
6.
M. N.
Yoder
, U.S. patent 4756794 A (12 July
1988
).
7.
Y.
Aoyagi
,
K.
Shinmura
,
K.
Kawasaki
,
T.
Tanaka
,
K.
Gamo
,
S.
Namba
, and
I.
Nakamoto
,
Appl. Phys. Lett.
60
,
968
(
1992
).
8.
G. S.
Oehrlein
,
D.
Metzler
, and
C.
Li
,
ECS J. Solid State Sci. Technol.
4
,
N5041
(
2015
).
9.
M. J.
Cooke
,
ECS J. Solid State Sci. Technol.
4
,
N5001
(
2015
).
10.
A.
Goodyear
and
M.
Cooke
,
J. Vac. Sci. Technol., A
35
,
01A105
(
2017
).
11.
D.
Metzler
 et al.,
J. Vac. Sci. Technol., A
34
,
01B102
(
2016
).
12.
W.
Yang
,
T.
Ohba
,
S.
Tan
,
K. J.
Kanarik
,
J.
Marks
, and
K.
Nojiri
, U.S. patent 15/173,358 (8 December
2016
).
13.
J.
Lemettinen
,
C.
Kauppinen
,
M.
Rudzinski
,
A.
Haapalinna
,
T.
Tuomi
, and
S.
Suihkonen
,
Semicond. Sci. Technol.
32
,
045003
(
2017
).
14.
W.
Saito
,
Y.
Takada
,
M.
Kuraguchi
,
K.
Tsuda
, and
I.
Omura
,
IEEE Trans. Electron Devices
53
,
356
(
2006
).
15.
T.
Egawa
,
G.-Y.
Zhao
,
H.
Ishikawa
,
H.
Umeno
, and
T.
Jimbo
,
IEEE Trans. Electron Devices
48
,
603
(
2001
).
16.
W.
Lanford
,
T.
Tanaka
,
Y.
Otoki
, and
I.
Adesida
,
Electron. Lett.
41
,
449
(
2005
).
17.
F.
Khan
,
V.
Kumar
, and
I.
Adesida
,
Electrochem. Solid-State Lett.
5
,
G8
(
2002
).
18.
W.-K.
Wang
,
Y.-J.
Li
,
C.-K.
Lin
,
Y.-J.
Chan
,
G.-T.
Chen
, and
J.-I.
Chyi
,
IEEE Electron Device Lett.
25
,
52
(
2004
).
19.
Z. Y.
Al Balushi
 et al.,
Nat. Mater.
15
,
1166
(
2016
).
20.
K. J.
Kanarik
 et al.,
J. Vac. Sci. Technol., A
35
,
05C302
(
2017
).
21.
T.
Ohba
,
W.
Yang
,
S.
Tan
,
K.
Kanarik
, and
K.
Nojiri
,
Jpn. J. Appl. Phys., Part 1
56
,
06HB06
(
2017
).
22.
T.
Lang
,
M.
Odnoblyudov
,
V.
Bougrov
,
S.
Suihkonen
,
M.
Sopanen
, and
H.
Lipsanen
,
J. Cryst. Growth
292
,
26
(
2006
).
23.
H.
Amano
,
N.
Sawaki
,
I.
Akasaki
, and
Y.
Toyoda
,
Appl. Phys. Lett.
48
,
353
(
1986
).
24.
G. D.
Sherpa
and
A.
Ranjan
,
J. Vac. Sci. Technol., A
35
,
01A102
(
2017
).
25.
M.
Leszczynski
 et al.,
Appl. Phys. Lett.
69
,
73
(
1996
).
26.
Y.-H.
Lai
,
C.-T.
Yeh
,
J.-M.
Hwang
,
H.-L.
Hwang
,
C.-T.
Chen
, and
W.-H.
Hung
,
J. Phys. Chem. B
105
,
10029
(
2001
).
27.
S.
Pearton
,
R.
Shul
, and
F.
Ren
,
MRS Internet J. Nitride Semicond. Res.
5
,
e11
(
2000
).
28.
K.
Harafuji
and
K.
Kawamura
,
Jpn. J. Appl. Phys.
49
,
08JE03
(
2010
).
29.
K.
Harafuji
and
K.
Kawamura
,
Jpn. J. Appl. Phys., Part 1
47
,
1536
(
2008
).
30.
M.
Sandberg
,
M. R.
Vissers
,
J. S.
Kline
,
M.
Weides
,
J.
Gao
,
D. S.
Wisbey
, and
D. P.
Pappas
,
Appl. Phys. Lett.
100
,
262605
(
2012
).
31.
A.
Aydemir
and
T.
Akin
,
J. Micromech. Microeng.
22
,
074004
(
2012
).
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