The van der Waals surfaces of the layered material α-MoTe2 and the high temperature phase β-MoTe2 were investigated by means of atomic force microscopy (AFM) and scanning tunneling microscopy/scanning tunneling spectroscopy (STM/STS). On both samples atomically resolved images of the surface structures were obtained. The combined STS/STM measurements of β-MoTe2 provide unambiguous evidence that the contribution from the subsurface layer dominates the tunneling current. Furthermore, from the combined AFM and STM data we arrive at a model for a new structure modification of this surface. This modification represents an interesting kinetically controlled intermediate state of the transition from β- to α-MoTe2.

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