Achieving accurate results in interior acoustic simulations relies on precise knowledge of the boundary properties of all interacting surfaces. Typically, the boundary admittance, which fully characterizes the acoustic properties of a surface, is determined under laboratory conditions such as the impedance tube. Yet, this approach has limitations, motivating the exploration of in situ methods to characterize materials in real-world conditions. In this work, we present a Bayesian approach to determine the acoustic boundary admittance in situ based on a limited number of measurement points. The method utilizes simulation-based inference, where a neural network is trained to approximate the posterior probability distributions of the unknown boundary admittances. The core of the approach is a finite element model used to generate sound pressure data, which also acts as the forward model during the inference process. Consequently, this technique is especially well-suited for applications involving pre-existing geometrical models, such as digital twin applications or model updating. By adopting simulation-based inference, we gain advantages over sampling-based Bayesian approaches, as it effectively handles complex and computationally expensive forward models.