Infants are able to match seen and heard speech even in non-native languages, and familiarization to audiovisual speech appears to affect subsequent auditory-only discrimination of non-native speech sounds (Danielson et al., 2013; 2014). However, the robustness of these behaviors appears to change rapidly within the first year of life. In this current set of studies, conducted with six-, nine-, and 10-month-old English-learning infants, we examine the developmental trajectory of audiovisual speech perception of non-native speech sounds. In the first place, we show that the tendency to detect a mismatch between heard and seen speech sounds in a non-native language changes across this short period in development, in tandem with the trajectory of auditory perceptual narrowing (Werker & Tees, 1984; Kuhl et al., 1992; inter alia). Furthermore, we demonstrate that infants’ familiarization to matching and mismatching audiovisual speech affects their auditory speech perception differently at various ages. While six-month-old infants’ auditory speech perception appears to be malleable in the face of prior audiovisual familiarization, this tendency declines with age. The current set of studies is one of the first to utilize traditional looking-time measurements while also employing pupillometry as a correlate of infants’ acoustic change detection (Hochmann & Papeo, 2014).