On July 14, 2006, Tungurahua volcano in Ecuador initiated a dramatic eruptive sequence that caused the evacuation of villagers, the destruction of crops, and the reports of ash clouds above 15 km. Acoustic signals have been recorded by the prototype infrasound acoustic‐surveillance system (ASHE) currently operating in Ecuador. The infrasonic signals recorded by the ASHE included explosions, pyroclastic flows, and a sustained low frequency vibration of the ground. We present the features of the different types of eruption signals, and discuss the physics of eruptive processes and volcanic ash injection into the atmosphere. We also compare the July 2006 ash‐rich eruption sequence with the May 2006 eruptive episode, which injected very little ash into the atmosphere. Results are of significance for the future operational use of acoustic monitoring of volcanic activity for aviation safety.