Supersonic jets of gas-phase atoms and small molecules have enabled a variety of ultrafast and ultracold chemical studies. However, extension to larger, more complex neutral molecules proves challenging for two reasons: (i) Complex molecules, such as cis-stilbene, exist in a liquid or solid phase at room temperature and ambient pressure and (ii) a unidirectional flow of high-density gaseous beams of such molecules to the interaction region is required. No delivery system currently exists that can deliver dense enough molecular jets of neutral complex molecules without ionizing or exciting the target for use in gas-phase structural dynamics studies. Here, we present a novel delivery system utilizing Tesla valves, which generates more than an order-of-magnitude denser gaseous beam of molecules compared to a bubbler without Tesla valves at the interaction region by ensuring a fast unidirectional flow of the gaseous sample. We present combined experimental and flow simulations of the Tesla valve setup. Our results open new possibilities of studying large complex neutral molecules in the gas-phase with low vapor pressures in future ultrafast and ultracold studies.
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October 2021
Research Article|
October 19 2021
High density molecular jets of complex neutral organic molecules with Tesla valves
Moniruzzaman Shaikh
;
Moniruzzaman Shaikh
1
ICFO - Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology
, 08860 Castelldefels, Barcelona, Spain
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Xinyao Liu
;
Xinyao Liu
1
ICFO - Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology
, 08860 Castelldefels, Barcelona, Spain
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Kasra Amini
;
Kasra Amini
1
ICFO - Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology
, 08860 Castelldefels, Barcelona, Spain
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Tobias Steinle;
Tobias Steinle
1
ICFO - Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology
, 08860 Castelldefels, Barcelona, Spain
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Jens Biegert
Jens Biegert
a)
1
ICFO - Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology
, 08860 Castelldefels, Barcelona, Spain
2
ICREA
, Pg. Lluís Companys 23, 08010 Barcelona, Spain
a)Author to whom correspondence should be addressed: jens.biegert@icfo.eu
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a)Author to whom correspondence should be addressed: jens.biegert@icfo.eu
Rev. Sci. Instrum. 92, 104103 (2021)
Article history
Received:
June 23 2021
Accepted:
September 28 2021
Citation
Moniruzzaman Shaikh, Xinyao Liu, Kasra Amini, Tobias Steinle, Jens Biegert; High density molecular jets of complex neutral organic molecules with Tesla valves. Rev. Sci. Instrum. 1 October 2021; 92 (10): 104103. https://doi.org/10.1063/5.0060904
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