A single pulse shock tube has been designed and constructed in order to achieve extremely high pressures and temperatures to facilitate gas-phase chemical kinetic experiments. Postshock pressures of greater than 1000 atmospheres have been obtained. Temperatures greater than 1400 K have been achieved and, in principle, temperatures greater than 2000 K are easily attainable. These high temperatures and pressures permit the investigation of hydrocarbon species pyrolysis and oxidation reactions. Since these reactions occur on the time scale of 0.5–2 ms the shock tube has been constructed with an adjustable length driven section that permits variation of reaction viewing times. For any given reaction viewing time, samples can be withdrawn through a specially constructed automated sampling apparatus for subsequent species analysis with gas chromatography and mass spectrometry. The details of the design and construction that have permitted the successful generation of very high-pressure shocks in this unique apparatus are described. Additional information is provided concerning the diaphragms used in the high-pressure shock tube.
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July 2001
Research Article|
July 01 2001
Design of a high-pressure single pulse shock tube for chemical kinetic investigations Available to Purchase
R. S. Tranter;
R. S. Tranter
Department of Chemical Engineering, University of Illinois at Chicago, Chicago, Illinois 60607
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K. Brezinsky;
K. Brezinsky
Department of Chemical Engineering, University of Illinois at Chicago, Chicago, Illinois 60607
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D. Fulle
D. Fulle
Department of Chemical Engineering, University of Illinois at Chicago, Chicago, Illinois 60607
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R. S. Tranter
K. Brezinsky
D. Fulle
Department of Chemical Engineering, University of Illinois at Chicago, Chicago, Illinois 60607
Rev. Sci. Instrum. 72, 3046–3054 (2001)
Article history
Received:
February 13 2001
Accepted:
April 23 2001
Citation
R. S. Tranter, K. Brezinsky, D. Fulle; Design of a high-pressure single pulse shock tube for chemical kinetic investigations. Rev. Sci. Instrum. 1 July 2001; 72 (7): 3046–3054. https://doi.org/10.1063/1.1379963
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