X-ray free electron laser (XFEL) interaction with solids has been simulated to resolve simultaneously variable XFEL photon energy and x-ray spectral distribution of the target emission (2D-maps). It is discovered that the highly transient charge state distribution exhibits a characteristic target response due to the action of the sharply rising radiation field. Finally, we identify advantageous features for studies of dense plasma effects of two K-shell vacancy hollow ion x-ray emission excited via resonance excitation. These features and characteristics permit the global study of dense plasma effects via the simulation of the time-integrated joint distribution of pumped and fluorescence energies. It is shown that the simulation of these specific 2D-maps offers a global vision of the complex interplay between different processes or phenomena such as photoionization, resonance excitation, or ionization potential depression.
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