A simplified method to calculate the electronic partition functions and the corresponding thermodynamic properties of atomic species is presented and applied to C(I) up to C(VI) ions. The method consists in reducing the complex structure of an atom to three lumped levels. The ground level of the lumped model describes the ground term of the real atom, while the second lumped level represents the low lying states and the last one groups all the other atomic levels. It is also shown that for the purpose of thermodynamic function calculation, the energy and the statistical weight of the upper lumped level, describing high-lying excited atomic states, can be satisfactorily approximated by an analytic hydrogenlike formula. The results of the simplified method are in good agreement with those obtained by direct summation over a complete set (i.e., including all possible terms and configurations below a given cutoff energy) of atomic energy levels. The method can be generalized to include more lumped levels in order to improve the accuracy.

1.
M.
Capitelli
,
D.
Giordano
, and
G.
Colonna
,
Phys. Plasmas
15
,
082115
(
2008
).
2.
K.
Singh
,
G.
Singh
, and
R.
Sharma
,
Phys. Plasmas
17
,
072309
(
2010
).
3.
R.
Sharma
,
G.
Singh
, and
K.
Singh
,
Phys. Plasmas
18
,
083510
(
2011
).
4.
W. Z.
Wang
,
M. Z.
Rong
,
J. D.
Yan
,
A. B.
Murphy
, and
J. W.
Spencer
,
Phys. Plasmas
18
,
113502
(
2011
).
5.
D.
Bernardi
,
V.
Colombo
,
G. G. M.
Coppa
, and
A.
D'Angola
,
Eur. J. Phys. D
14
,
337
(
2001
).
6.
G.
Colonna
,
A.
D'Angola
, and
M.
Capitelli
,
Phys. Plasmas
19
,
072115
(
2012
).
7.
R.
Gaudiuso
,
M.
Dell'Aglio
,
O.
De Pascale
,
G.
Senesi
, and
A.
De Giacomo
,
Sensors
10
,
7434
(
2010
).
8.
H.
Hahn
and
N.
Omenetto
,
Appl. Spectrosc.
64
,
335A
(
2010
).
9.
C.
Aragón
and
J. A.
Aguilera
,
Spectrochim. Acta, Part B
63
,
893
(
2008
).
10.
L. J.
Radziemski
,
Lasers-Induced Plasmas and Applications
(
CRC Press
,
1989
).
11.
D. G.
Hummer
and
D.
Mihalas
,
Astrophys. J.
331
,
794
(
1988
).
12.
D.
Mihalas
,
W.
Daeppen
, and
D. G.
Hummer
,
Astrophys. J.
331
,
815
(
1988
).
13.
W.
Daeppen
,
D.
Mihalas
,
D. G.
Hummer
, and
B. W.
Mihalas
,
Astrophys. J.
332
,
261
(
1988
).
14.
M. R.
Zaghloul
,
Phys. Plasmas
17
,
122903
(
2010
).
16.
H. R.
Griem
,
Principles of Plasma Spectroscopy
(
Cambridge University Press
,
1997
).
17.
G.
Ecker
and
W.
Weizel
,
Ann. Phys.
452
,
126
(
1956
).
18.
G.
Ecker
and
W.
Kröll
,
Phys. Fluids
6
,
62
(
1963
).
19.
H.
Margenau
and
M.
Lewis
,
Rev. Mod. Phys.
31
,
569
(
1959
).
20.
K. S.
Drellishak
,
D. P.
Aeschliman
, and
A. B.
Cambel
,
Phys. Fluids
8
,
1590
(
1965
).
21.
M.
Capitelli
and
E.
Molinari
,
J. Plasma Phys.
4
,
335
(
1970
).
22.
M.
Capitelli
,
G.
Colonna
,
D.
Giordano
,
L.
Marraffa
,
A.
Casavola
,
P.
Minnelli
,
D.
Pagano
,
L. D.
Pietanza
, and
F.
Taccogna
, “
Tables of internal partition functions and thermodynamic properties of high-temperature mars-atmosphere
,” Technical Report STR-246 (
European Space Agency
,
2005
).
23.
M.
Capitelli
,
G.
Colonna
,
D.
Giordano
,
L.
Marraffa
,
A.
Casavola
,
P.
Minnelli
,
D.
Pagano
,
L. D.
Pietanza
, and
F.
Taccogna
,
J. Spacecr. Rockets
42
,
980
(
2005
).
24.
M.
Capitelli
,
D.
Bruno
,
G.
Colonna
,
C.
Catalfamo
, and
A.
Laricchiuta
,
J. Phys. D: Appl. Phys.
42
,
194005
(
2009
).
25.
M.
Capitelli
,
G.
Colonna
, and
A.
D'Angola
,
Fundamental Aspects of Plasma Chemical Physics: Thermodynamics
(
Springer
,
2012
).
26.
C. E.
Moore
,
Atomic Energy Levels (Hydrogen though Vanadium), Circular of the National Bureau of Standards 467, Vol. I
(
National Bureau of Standards, U.S. Government Printing Office
,
Washington, DC
,
1949
).
27.
C. E.
Moore
,
Atomic Energy Levels (Chromium through Niobium), Circular of the National Bureau of Standards 467, Vol II
(
National Bureau of Standards, U.S. Government Printing Office
,
Washington, DC
,
1952
).
28.
C. E.
Moore
,
Atomic Energy Levels (Molybdenum through Lanthanum and Hafnium through Actinium), Circular of the National Bureau of Standards 467 Vol. III
(
National Bureau of Standards, U.S. Government Printing Office
,
Washington, DC
,
1958
).
29.
A.
Kramida
,
Y.
Ralchenko
,
J.
Reader
, and
NIST ASD Team
,
NIST Atomic Spectra Database (version 5.0)
,
National Institute of Standards and Technology
,
Gaithersburg, MD
(
2012
).
30.
M. J.
Hagyard
, “
Calculation of astrophysical partition functions
,” Technical Memorandum TM X-53984 (NASA, George C. Marshall Space Flight Center, Alabama 35812,
1970
).
32.
D.
Kremp
,
M.
Schlanges
, and
W. D.
Kraeft
,
Quantum Statistics of Nonideal Plasmas, Springer Series on Atomic, Optical, and Plasma Physics Vol. 25
(
Springer
,
2005
).
33.
G.
Colonna
and
M.
Capitelli
,
Spectrochim. Acta, Part B
64
,
863
(
2009
).
34.
G.
D'Ammando
,
G.
Colonna
,
L. D.
Pietanza
, and
M.
Capitelli
,
Spectrochim. Acta, Part B
65
,
603
(
2010
).
35.
O.
Cardona
,
E.
Simmoneau
, and
L.
Crivellari
,
Rev. Mex. Fis.
51
,
476
(
2005
).
36.
O.
Cardona
,
E.
Simmoneau
, and
L.
Crivellari
,
Astrophys. J.
690
,
1378
(
2009
).
37.
O.
Cardona
,
M.
Martínez-Arroyo
, and
M. A.
López-Castillo
,
Astrophys. J.
711
,
239
(
2010
).
38.
S.
Gordon
and
B. J.
McBride
, “
Computer program for calculation of complex chemical equilibrium compositions, rocket performance, incident and reflected shocks, and chapman-joguet detonations
,” Tech. Rep. SP-273 (
NASA
,
1976
).
39.
B. J.
McBride
,
S.
Gordon
, and
M. A.
Reno
, “
Coefficients for calculating thermodynamic and transport properties of individual species
,” Technical Memorandum TM-4513 (
NASA
,
1993
).
40.
L. V.
Gurvich
,
I. V.
Veyts
,
C. B.
Alcock
, and
V. S.
Iorish
,
Thermodynamic Properties of Individual Substances
(
CRC
,
Boca Raton, FL
,
1994
).
41.
H. W.
Drawin
and
P.
Felenbok
,
Data for Plasmas in Local Thermodynamic Equilibrium
(
Gauthier-Villars
,
1965
).
42.
J. D.
Hey
,
Y. T.
Lie
,
D.
Rusbüldt
, and
E.
Hintz
,
Contrib. Plasm. Phys.
34
,
725
(
1994
).
43.
J. D.
Hey
,
C. C.
Chu
,
S.
Brezinsek
,
Ph.
Mertens
, and
B.
Unterberg
,
J. Phys. B
35
,
1525
(
2002
).
44.
M.
Capitelli
and
E.
Ficocelli
,
J. Plasma Phys.
5
,
115
(
1971
).
45.
L. J.
Curtis
,
Atomic Structure and Lifetimes—A Conceptual Approach
(
Cambridge University Press
,
2003
).
46.
A.
D'Angola
,
G.
Colonna
,
C.
Gorse
, and
M.
Capitelli
,
Eur. J. Phys. D
46
,
129
(
2008
).
47.
A.
D'Angola
,
G.
Colonna
,
C.
Gorse
, and
M.
Capitelli
,
Eur. J. Phys. D
65
,
453
(
2011
).
48.
C.
Park
,
Nonequilibrium Hypersonic Aerothermodynamics
(
Wiley
,
1990
).
49.
H. C.
Le
,
D. E.
Zeitoun
, and
J. D.
Parisse
,
Phys. Rev. E
62
,
4152
(
2000
).
50.
D.
Bruno
,
A.
Laricchiuta
,
M.
Capitelli
, and
C.
Catalfamo
,
Phys. Plasmas
14
,
022303
(
2007
).
51.
M.
Capitelli
,
R.
Celiberto
,
C.
Gorse
,
A.
Laricchiuta
,
D.
Pagano
, and
P.
Traversa
,
Phys. Rev. E
69
,
026412
(
2004
).
You do not currently have access to this content.