A simplified method to calculate the electronic partition functions and the corresponding thermodynamic properties of atomic species is presented and applied to C(I) up to C(VI) ions. The method consists in reducing the complex structure of an atom to three lumped levels. The ground level of the lumped model describes the ground term of the real atom, while the second lumped level represents the low lying states and the last one groups all the other atomic levels. It is also shown that for the purpose of thermodynamic function calculation, the energy and the statistical weight of the upper lumped level, describing high-lying excited atomic states, can be satisfactorily approximated by an analytic hydrogenlike formula. The results of the simplified method are in good agreement with those obtained by direct summation over a complete set (i.e., including all possible terms and configurations below a given cutoff energy) of atomic energy levels. The method can be generalized to include more lumped levels in order to improve the accuracy.
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March 2013
Research Article|
March 15 2013
A simplified approach to calculate atomic partition functions in plasmas Available to Purchase
Giuliano D'Ammando;
Giuliano D'Ammando
a)
1
Dipartimento di Chimica, Universitá di Bari
, Via Orabona 4, 70125 Bari, Italy
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Gianpiero Colonna;
Gianpiero Colonna
b)
2
CNR-IMIP
, Via Amendola 122/D, 70126 Bari, Italy
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Mario Capitelli
Mario Capitelli
c)
1
Dipartimento di Chimica, Universitá di Bari
, Via Orabona 4, 70125 Bari, Italy
2
CNR-IMIP
, Via Amendola 122/D, 70126 Bari, Italy
Search for other works by this author on:
Giuliano D'Ammando
1,a)
Gianpiero Colonna
2,b)
Mario Capitelli
1,2,c)
1
Dipartimento di Chimica, Universitá di Bari
, Via Orabona 4, 70125 Bari, Italy
2
CNR-IMIP
, Via Amendola 122/D, 70126 Bari, Italy
Phys. Plasmas 20, 032108 (2013)
Article history
Received:
November 27 2012
Accepted:
February 12 2013
Citation
Giuliano D'Ammando, Gianpiero Colonna, Mario Capitelli; A simplified approach to calculate atomic partition functions in plasmas. Phys. Plasmas 1 March 2013; 20 (3): 032108. https://doi.org/10.1063/1.4794286
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