We numerically investigate the rheological response of a noncoalescing multiple emulsion under a symmetric shear flow. We find that the dynamics significantly depends on the magnitude of the shear rate and on the number of the encapsulated droplets, two key parameters whose control is fundamental to accurately select the resulting nonequilibrium steady states. The double emulsion, for instance, attains a static steady state in which the external droplet stretches under flow and achieves an elliptical shape (closely resembling the one observed in a sheared isolated fluid droplet), while the internal one remains essentially unaffected. Novel nonequilibrium steady states arise in a multiple emulsion. Under low/moderate shear rates, for instance, the encapsulated droplets display a nontrivial planetarylike motion that considerably affects the shape of the external droplet. Some features of this dynamic behavior are partially captured by the Taylor deformation parameter and the stress tensor. Besides a theoretical interest on its own, our results can potentially stimulate further experiments, as most of the predictions could be tested in the lab by monitoring droplets’ shapes and position over time.
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January 2020
Research Article|
January 09 2020
Novel nonequilibrium steady states in multiple emulsions
A. Tiribocchi
;
A. Tiribocchi
1
Center for Life Nano Science@La Sapienza, Istituto Italiano di Tecnologia
, 00161 Roma, Italy
2
Istituto per le Applicazioni del Calcolo CNR
, via dei Taurini 19, Rome, Italy
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A. Montessori;
A. Montessori
2
Istituto per le Applicazioni del Calcolo CNR
, via dei Taurini 19, Rome, Italy
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S. Aime;
S. Aime
3
School of Engineering and Applied Sciences, Harvard University
, McKay 517, Cambridge, Massachusetts 02138, USA
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M. Milani;
M. Milani
3
School of Engineering and Applied Sciences, Harvard University
, McKay 517, Cambridge, Massachusetts 02138, USA
4
Université degli Studi di Milano
, via Celoria 16, 20133 Milano, Italy
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M. Lauricella
;
M. Lauricella
2
Istituto per le Applicazioni del Calcolo CNR
, via dei Taurini 19, Rome, Italy
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S. Succi
;
S. Succi
1
Center for Life Nano Science@La Sapienza, Istituto Italiano di Tecnologia
, 00161 Roma, Italy
2
Istituto per le Applicazioni del Calcolo CNR
, via dei Taurini 19, Rome, Italy
5
Institute for Applied Computational Science, John A. Paulson School of Engineering and Applied Sciences, Harvard University
, Cambridge, Massachusetts 02138, USA
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D. Weitz
D. Weitz
3
School of Engineering and Applied Sciences, Harvard University
, McKay 517, Cambridge, Massachusetts 02138, USA
6
Department of Physics, Harvard University
, Cambridge, Massachusetts 02138, USA
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Physics of Fluids 32, 017102 (2020)
Article history
Received:
November 04 2019
Accepted:
December 19 2019
Citation
A. Tiribocchi, A. Montessori, S. Aime, M. Milani, M. Lauricella, S. Succi, D. Weitz; Novel nonequilibrium steady states in multiple emulsions. Physics of Fluids 1 January 2020; 32 (1): 017102. https://doi.org/10.1063/1.5134901
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