A continuous model is derived for the dynamics of two immiscible fluids with moving contact lines and insoluble surfactants based on thermodynamic principles. The continuum model consists of the Navier-Stokes equations for the dynamics of the two fluids and a convection-diffusion equation for the evolution of the surfactant on the fluid interface. The interface condition, the boundary condition for the slip velocity, and the condition for the dynamic contact angle are derived from the consideration of energy dissipations. Different types of energy dissipations, including the viscous dissipation, the dissipations on the solid wall and at the contact line, as well as the dissipation due to the diffusion of surfactant, are identified from the analysis. A finite element method is developed for the continuum model. Numerical experiments are performed to demonstrate the influence of surfactant on the contact line dynamics. The different types of energy dissipations are compared numerically.
Skip Nav Destination
Article navigation
June 2014
Research Article|
June 05 2014
Derivation of a continuum model and the energy law for moving contact lines with insoluble surfactants
Zhen Zhang;
Zhen Zhang
a)
1Department of Mathematics,
National University of Singapore
, Singapore 119076
Search for other works by this author on:
Shixin Xu;
Shixin Xu
b)
1Department of Mathematics,
National University of Singapore
, Singapore 119076
Search for other works by this author on:
Weiqing Ren
Weiqing Ren
c)
1Department of Mathematics,
National University of Singapore
, Singapore 1190762
Institute of High Performance Computing
, Agency for Science, Technology and Research, Singapore 138632
Search for other works by this author on:
a)
Electronic mail: matzz@nus.edu.sg
b)
Electronic mail: matxs@nus.edu.sg
c)
Author to whom correspondence should be sent. Electronic mail: matrw@nus.edu.sg
Physics of Fluids 26, 062103 (2014)
Article history
Received:
March 19 2014
Accepted:
May 20 2014
Citation
Zhen Zhang, Shixin Xu, Weiqing Ren; Derivation of a continuum model and the energy law for moving contact lines with insoluble surfactants. Physics of Fluids 1 June 2014; 26 (6): 062103. https://doi.org/10.1063/1.4881195
Download citation file:
Pay-Per-View Access
$40.00
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Citing articles via
On Oreology, the fracture and flow of “milk's favorite cookie®”
Crystal E. Owens, Max R. Fan (范瑞), et al.
Fluid–structure interaction on vibrating square prisms considering interference effects
Zengshun Chen (陈增顺), 陈增顺, et al.
A unified theory for bubble dynamics
A-Man Zhang (张阿漫), 张阿漫, et al.
Related Content
Deformation and breakup of a stretching liquid bridge covered with an insoluble surfactant monolayer
Physics of Fluids (February 2006)
Spreading of droplet with insoluble surfactant on corrugated topography
Physics of Fluids (September 2014)
Influence of surfactant solubility on the deformation and breakup of a bubble or capillary jet in a viscous fluid
Physics of Fluids (July 2009)
Thermodynamically consistent description of the hydrodynamics of free surfaces covered by insoluble surfactants of high concentration
Physics of Fluids (October 2012)
Long wave instability on the parallel shear flows in the presence of insoluble surfactant
AIP Conf. Proc. (November 2020)