We focus on the characterization of dispersion processes in microchannels with fractal boundaries (and translational symmetry in the longitudinal direction) in the presence of laminar axial velocity field. This article extends the theory of laminar dispersion in finite-length channel flows at high Peclet numbers by analyzing the role of the fractal cross-section in the convection-dominated transport regime. In this regime, the properties of the dispersion boundary layer and the values of the scaling exponents controlling the dependence of the moment hierarchy on the Peclet number are determined by the local near-wall behavior of the axial velocity. Specifically, different scaling laws in the behavior of the moment hierarchy occur, depending whether the cross-sectional boundary is smooth or nonsmooth (e.g., presenting corner points or cusps). The limit case of a fractal boundary is analyzed in detail. Analytical and numerical results are presented for two fractal cross-sections (the classical Koch curve and the Koch snowflake) in the Stokes regime.

1.
H.
Brenner
and
D. A.
Edwards
,
Macrotransport Processes
(
Butterworth-Heinemann
,
Boston
,
1993
).
2.
L. G.
Leal
,
Advanced Transport Phenomena
(
Cambridge University Press
,
Cambridge
,
2007
).
3.
G.
Taylor
, “
Dispersion of soluble matter in solvent flowing slowly through a tube
,”
Proc. R. Soc. London, Ser. A
219
,
186
(
1953
).
4.
R.
Aris
, “
On the dispersion of a solute in a fluid flowing through a tube
,”
Proc. R. Soc. London, Ser. A
235
,
67
(
1956
).
5.
A.
Ajdari
,
N.
Bontoux
, and
H.
Stone
, “
Hydrodynamic dispersion in shallow microchannels: The effect of cross-sectional shape
,”
Anal. Chem.
78
,
387
(
2006
).
6.
N.
Bonthoux
,
A
Pepin
,
Y.
Chen
,
A.
Ajdari
, and
H.
Stone
,
Experimental characterization of hydrodynamic dispersion in shallow microchannels
,”
Lab Chip
6
,
930
(
2006
).
7.
D.
Dutta
,
A.
Ramachandran
, and
D. T.
Leighton
, Jr.
, “
Effect of channel geometry on solute dispersion in pressure-driven microfluidic systems
,”
Microfluid. Nanofluid.
2
,
275
(
2006
).
8.
D.
Dutta
and
D. T.
Leighton
, Jr.
, “
Dispersion reduction in open-channel liquid electrochromatographic columns via pressure-driven back flow
,”
Anal. Chem.
75
,
3352
(
2003
).
9.
H.
Zhao
and
H. H.
Bau
, “
Effect of secondary flows on Taylor–Aris dispersion
,”
Anal. Chem.
79
,
7792
(
2007
).
10.
S.
Datta
and
S.
Ghosal
, “
Dispersion due to wall interactions in microfluidic separation systems
,”
Phys. Fluids
20
,
012103
(
2008
).
11.
M.
Giona
,
A.
Adrover
,
S.
Cerbelli
, and
F.
Garofalo
, “
Laminar dispersion at high Peclet numbers in finite-length channels: Effects of the near-wall velocity profile and connection with the generalized Leveque problem
,”
Phys. Fluids
21
,
123601
(
2009
).
12.
Ch. -H.
Fischer
and
M.
Giersig
, “
Analysis of colloids VII. Wide-bore hydrodynamic chromatography, a simple method for the determination of particle size in the nanometer size regime
,”
J. Chromatogr. A
688
,
97
(
1994
).
13.
T.
Okada
,
M.
Harada
, and
T.
Kido
, “
Resolution of small molecules by passage through an open capillary
,”
Anal. Chem.
77
,
6041
(
2005
).
14.
M.
Harada
,
T.
Kido
,
T.
Masudo
, and
T.
Okada
, “
Solute distribution coupled with laminar flow in wide-bore capillaries: What can be separated without chemical or physical fields?
,”
Anal. Sci.
21
,
491
(
2005
).
15.
B.
Sapoval
, in
Fractals and Disordered Systems
, edited by
A.
Bunde
and
S.
Havlin
(
Springer-Verlag
,
Berlin
,
1996
).
16.
B. B.
Mandelbrot
,
The Fractal Geometry of Nature
(
Freeman
,
New York
,
1983
).
17.
J.
Feder
,
Fractals
(
Plenum
,
New York
,
1988
).
18.
W.
Ehrfeld
,
V.
Hessel
, and
H.
Lowe
,
Microreactors
(
Wiley-VCH
,
Weinheim
,
2000
).
19.
A.
Adrover
and
F.
Garofalo
, “
Scaling of the density of state of the weighted Laplacian in the presence of fractal boundaries
,”
Phys. Rev. E
81
,
027202
(
2010
).
20.
S.
Homolya
,
C. F.
Osborne
, and
I. D.
Svalbe
, “
Density of states for vibrations of fractal drums
,”
Phys. Rev. E
67
,
026211
(
2003
).
21.
A.
Leveque
, “
Les lois de la transmission de chaleur par convection. Annales des Mines ou Recueil de Mémoires sur l’Exploitation des Mines et sur les Sciences et les Arts qui s’y Rattachent
,”
Mmoires
13
,
201
(
1924
).
22.
H. A.
Stone
, “
Heat/mass transfer from surface films to shear flows at arbitrary Peclet numbers
,”
Phys. Fluids A
1
,
1112
(
1989
).
23.
A.
Adrover
, “
Laminar convective heat transfer across fractal boundaries
,”
Europhys. Lett.
90
,
14002
(
2010
).
24.
This can be simply viewed by observing that for Peeff1, i.e., within the region of occurrence of the Taylor–Aris regime, particle trajectories explore generically the entire cross-section of the channel. Conversely, for higher values of Peeff, a generic particle starting its trajectory at the inlet section does not explore the entire channel cross-section in its flight up to the outlet. This is a fortiori true for solute particles starting from close to the walls which correspond to the stagnation points of the axial velocity field. As Peeff increases, these particles tend to be confined in a thin layer close to the walls, and this “kinematic” localization close to the stagnation points determines the long-time properties of the outlet concentration profile, and ultimately the divergent scaling of the moment hierarchy.
25.
The value of ΓTA has been computed by solving the equation for the auxiliary variable 2f=(vz(x)Vm)/Vm equipped with zero flux boundary conditions at Σ, and then evaluating the spatial average over the cross-section ΓTA=<f(x)(vz(x)Vm)/Vm>.
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