The absorption spectrum of a thin K 2 CuC l 3 film was studied in the spectral region of 2–6 eV and the temperature range of 90–333 K. The analysis of the spectrum revealed the cationic nature of excitons in the K 2 CuC l 3 compound. The exciton spectrum of K 2 CuC l 3 is interpreted based on transitions in the Cu+ ion. The one-dimensional character of excitons in K 2 CuC l 3 is determined from the temperature dependence of the broadening of the Г(T) intense long-wave exciton band A.

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