The structure and microhardness of Cu-0.3 at. % Mo vacuum condensates obtained at different deposition rates, both in the initial state and after isothermal annealings carried out up to 800 °C, were studied in the work. It has been established that molybdenum has a dispersing effect on the grain structure of the copper matrix, which consists of the blocking effect of monoatomic molybdenum adsorption layers formed on the surface of growing copper grains during the condensation of a two-component vapor. The structure of Cu-0.3 at. % Mo condensates demonstrates increased thermal stability, retaining the size of the original grain upon annealing up to 800 °C. The thermal stabilization of the grain structure of condensates is explained by the influence of grain-boundary segregations of molybdenum atoms and particles, which reduce the free energy of grain boundaries and the rate of their migration.

1.
V. G.
Grechanyuk
,
N. I.
Grechanyuk
,
V. O.
Chornovol
,
A. V.
Kozyrev
,
V. I.
Gots
,
A. V.
Matsenko
,
V. A.
Kulichenko
,
T. D.
Grabina
, and
Yu. I.
Kozyreva
, “
Сopper and molybdenum-based nanocrystalline materials
,”
Metal. Nov. Tekhn.
44
,
927
(
2022
).
2.
M.
Zhadko
,
O.
Sobol
,
G.
Zelenskaya
, and
A.
Zubkov
,
Methods for Calculating the Grain Boundary Adsorption Capacity of Nanostructured Copper Based Condensates, Design, Simulation, Manufacturing: The Innovation Exchange
(
Springer
,
Cham
,
2018
).
3.
D.
Raabe
,
M.
Herbig
,
S.
Sandlöbes
,
Y.
Li
,
D.
Tytko
,
M.
Kuzmina
,
D.
Ponge
, and
P.-P.
Choi
, “
Grain boundary segregation engineering in metallic alloys: A pathway to the design of interfaces,”
Curr. Opin. Solid State Mater. Sci.
18
,
253
(
2014
).
4.
L. S.
Palatnik
,
M. Ya.
Fuks
, and
V. M.
Kosevich
,
Mechanism of Formation and Structure of Condensed Films
(
Nauka
,
Moscow
,
1972
).
5.
B. A.
Movchan
and
A. V.
Demchyshyn
, “
Investigation of structure and properties of thick vacuum condensates of nickel, titanium, tungsten, aluminum oxide, and zirconium dioxide
,”
Phys. Metals Metallogr.
28
,
653
(
1969
).
6.
N. I.
Grechanyuk
and
V. G.
Grechanyuk
, “
Dispersed and laminar volumetric nanocrystalline materials based on copper and molybdenum structure, properties, technology, application. information 1. structure and phase composition
,”
Electrometall. Today
1
,
42
(
2018
).
7.
W.
Bonfield
and
B. C.
Edwards
, “
Precipitation hardening in Cu 1.81 wt% Be 0.28 wt% Co: Part 1 continuous precipitation
,”
J. Mater. Sci.
9
,
398
(
1974
).
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