The low-temperature dependence of the heat capacity of acrylonitrile-butadiene-styrene (ABS) polymer and its composite with thermally reduced graphene oxide was studied. The existence of a so-called “boson peak” characteristic of orientational and structural glasses was demonstrated. The boson peak appears in the form of a local maximum in the heat capacity curve displayed as C/T3 vs T at Tmax = 3.52 K. It was found that for both ABS polymer and its composite, as well as for a number of other substances of a crystalline and amorphous nature, the manifestation of the anomaly of the boson peak in the heat capacity has a universal character that is described by an empirical function Δ*. The value of Δ* depends on the magnitude of the anomaly in the heat capacity and the temperature of the boson peak manifestation. Thus, this study provides new physical information about the possible causes of the boson peak appearance in disordered materials and indicates the universality of boson peak anomaly for substances with short- and long-range order.
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Research Article|
May 01 2023
Universal behavior of low-temperature heat capacity of acrylonitrile-butadiene-styrene thermoplastic polymer and its composite with graphene oxide Available to Purchase
Daria Szewczyk
;
Daria Szewczyk
1
Institute of Low Temperature and Structure Research, Polish Academy of Sciences
, Wrocław 50-422, Poland
2
Instituto Universitario de Ciencia de Materiales Nicolás Cabrera & Universidad Autónoma de Madrid
, Madrid 28049, Spain
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Alexander I. Krivchikov
;
Alexander I. Krivchikov
a)
1
Institute of Low Temperature and Structure Research, Polish Academy of Sciences
, Wrocław 50-422, Poland
3
B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine
, Kharkiv 61103, Ukraine
a)Author to whom correspondence should be addressed: [email protected]
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Maksym S. Barabashko
;
Maksym S. Barabashko
3
B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine
, Kharkiv 61103, Ukraine
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Alexander V. Dolbin
;
Alexander V. Dolbin
3
B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine
, Kharkiv 61103, Ukraine
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Nikolay A. Vinnikov
;
Nikolay A. Vinnikov
3
B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine
, Kharkiv 61103, Ukraine
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Razet Basnukaeva
;
Razet Basnukaeva
3
B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine
, Kharkiv 61103, Ukraine
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Grzegorz Chajewski
;
Grzegorz Chajewski
1
Institute of Low Temperature and Structure Research, Polish Academy of Sciences
, Wrocław 50-422, Poland
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Andrzej Jeżowski
Andrzej Jeżowski
1
Institute of Low Temperature and Structure Research, Polish Academy of Sciences
, Wrocław 50-422, Poland
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Daria Szewczyk
1,2
Alexander I. Krivchikov
1,3,a)
Maksym S. Barabashko
3
Alexander V. Dolbin
3
Nikolay A. Vinnikov
3
Razet Basnukaeva
3
Grzegorz Chajewski
1
Andrzej Jeżowski
1
1
Institute of Low Temperature and Structure Research, Polish Academy of Sciences
, Wrocław 50-422, Poland
2
Instituto Universitario de Ciencia de Materiales Nicolás Cabrera & Universidad Autónoma de Madrid
, Madrid 28049, Spain
3
B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine
, Kharkiv 61103, Ukraine
a)Author to whom correspondence should be addressed: [email protected]
Fiz. Nizk. Temp. 49, 649–657 (May 2023)
Low Temp. Phys. 49, 593 (2023)
Article history
Received:
March 27 2023
Citation
Daria Szewczyk, Alexander I. Krivchikov, Maksym S. Barabashko, Alexander V. Dolbin, Nikolay A. Vinnikov, Razet Basnukaeva, Grzegorz Chajewski, Andrzej Jeżowski; Universal behavior of low-temperature heat capacity of acrylonitrile-butadiene-styrene thermoplastic polymer and its composite with graphene oxide. Low Temp. Phys. 1 May 2023; 49 (5): 593–. https://doi.org/10.1063/10.0017821
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