Structural and spectroscopic data and the standard enthalpy of formation 298.15 K for C10H8, α‐C10H1D4, β‐C10H4D4 and C10D8 were reviewed. The selected values were utilized to calculate the ideal gas thermodynamic properties in the temperature range 0 to 1500 K, using the rigid rotor and harmonic oscillator model. The comparison between the third law entropies and the spectroscopically calculated entropies of C10H8 was studied. The agreement is satisfactory within the experimental uncertainties.

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