A new correlation for the viscosity of ethylbenzene is presented. The correlation is based upon a body of experimental data that has been critically assessed for internal consistency and for agreement with theory. It is applicable in the temperature range from the triple point to 673 K at pressures up to 110 MPa. The overall uncertainty of the proposed correlation, estimated as the combined expanded uncertainty with a coverage factor of 2, varies from 1% for the viscosity at atmospheric pressure to 5% for the highest temperatures and pressures of interest. Tables of the viscosity, generated by the relevant equations at selected temperatures and pressures and along the saturation line, are provided. Comparison of viscosity of xylene isomers indicated that at very high temperatures the viscosity correlation of para-xylene has higher uncertainty than previously postulated. Thus, in this work we also provide a revised viscosity correlation for p-xylene.
References
1.
Y.
Zhou
, J. T.
Wu
, and E. W.
Lemmon
, J. Phys. Chem. Ref. Data
41
, 023103
(2012
).2.
S. K.
Mylona
, K. D.
Antoniadis
, M. J.
Assael
, M. L.
Huber
, and R. A.
Perkins
, J. Phys. Chem. Ref. Data
43
, 043104
(2014
).3.
B. E.
Poling
, J. M.
Prausnitz
, and J. P.
O’Connell
, The Properties of Gases and Liquids
, 5th ed. (McGraw-Hill Companies
, New York
, 2001
).4.
C. L.
Yaws
, Transport Properties of Chemicals and Hydrocarbons
, 2nd ed. (Elsevier
, Oxford
, 2014
).5.
B.
Balogun
, N.
Riesco
, and V.
Vesovic
, J. Phys. Chem. Ref. Data
44
, 013103
(2015
).6.
F. L.
Cao
, X. Y.
Meng
, J. T.
Wu
, and V.
Vesovic
, J. Phys. Chem. Ref. Data
45
, 013103
(2016
).7.
F. L.
Cao
, X. Y.
Meng
, J. T.
Wu
, and V.
Vesovic
, J. Phys. Chem. Ref. Data
45
, 023102
(2016
).8.
V.
Vesovic
, W. A.
Wakeham
, G. A.
Olchowy
, J. V.
Sengers
, J. T. R.
Watson
, and J.
Millat
, J. Phys. Chem. Ref. Data
19
, 763
(1990
).9.
A.
Fenghour
, W. A.
Wakeham
, V.
Vesovic
, J. T. R.
Watson
, J.
Millat
, and E.
Vogel
, J. Phys. Chem. Ref. Data
24
, 1649
(1995
).10.
H. W.
Xiang
, A.
Laesecke
, and M. L.
Huber
, J. Phys. Chem. Ref. Data
35
, 1597
(2006
).11.
S. E.
Quiñones-Cisneros
, M. L.
Huber
, and U. K.
Deiters
, J. Phys. Chem. Ref. Data
41
, 023102
(2012
).12.
M. L.
Huber
, R. A.
Perkins
, A.
Laesecke
, D. G.
Friend
, J. V.
Sengers
, M. J.
Assael
, I. N.
Metaxa
, E.
Vogel
, R.
Mareš
, and K.
Miyagawa
, J. Phys. Chem. Ref. Data
38
, 101
(2009
).13.
E.
Vogel
, J.
Wilhelm
, C.
Küchenmeister
, and M.
Jaeschke
, High Temp. - High Pressures
32
, 73
(2000
).14.
E.
Vogel
, R.
Span
, and S.
Herrmann
, J. Phys. Chem. Ref. Data
44
, 043101
(2015
).15.
E.
Vogel
, C.
Küchenmeister
, E.
Bich
, and A.
Laesecke
, J. Phys. Chem. Ref. Data
27
, 947
(1998
).16.
E.
Vogel
, C.
Küchenmeister
, and E.
Bich
, Int. J. Thermophys.
21
, 343
(2000
).17.
E. K.
Michailidou
, M. J.
Assael
, M. L.
Huber
, and R. A.
Perkins
, J. Phys. Chem. Ref. Data
42
, 033104
(2013
).18.
E. K.
Michailidou
, M. J.
Assael
, M. L.
Huber
, I. M.
Abdulagatov
, and R. A.
Perkins
, J. Phys. Chem. Ref. Data
43
, 023103
(2014
).19.
M. L.
Huber
, A.
Laesecke
, and H. W.
Xiang
, Fluid Phase Equilib.
224
, 263
(2004
).20.
M. L.
Huber
, A.
Laesecke
, and R. A.
Perkins
, Energy Fuels
18
, 968
(2004
).21.
U.
Tariq
, A.
Jusoh
, N.
Riesco
, and V.
Vesovic
, J. Phys. Chem. Ref. Data
43
, 033101
(2014
).22.
S.
Avgeri
, M. J.
Assael
, M. L.
Huber
, and R. A.
Perkins
, J. Phys. Chem. Ref. Data
43
, 033103
(2014
).23.
S.
Avgeri
, M. J.
Assael
, M. L.
Huber
, and R. A.
Perkins
, J. Phys. Chem. Ref. Data
44
, 033101
(2015
).24.
25.
T. E.
Thorpe
and J. W.
Rodger
, Philos. Trans. R. Soc., A
185
, 397
(1894
).26.
T. E.
Thorpe
and J. W.
Rodger
, Philos. Trans. R. Soc., A
189
, 71
(1897
).27.
28.
A. E.
Dunstan
, T. P.
Hilditch
, and F. B.
Thole
, J. Chem. Soc.
103
, 133
(1913
).29.
J.
Timmermans
and F.
Martin
, J. Chim. Phys. Phys.-Chim. Biol.
23
, 747
(1926
).30.
A. W.
Schmidt
, G.
Hopp
, and V.
Schoeller
, Ber. Dtsch. Chem. Ges. B
72
, 1893
(1939
).31.
J. M.
Geist
and M. R.
Cannon
, Ind. Eng. Chem., Anal. Ed.
18
, 611
(1946
).32.
33.
34.
A. J.
Petro
and C. P.
Smyth
, J. Am. Chem. Soc.
79
, 6142
(1957
).35.
36.
A. J.
Barlow
, J.
Lamb
, and A. J.
Matheson
, Proc. R. Soc. A.
292
, 322
(1966
).37.
38.
39.
40.
H.
Kashiwagi
and T.
Makita
, Int. J. Thermophys.
3
, 289
(1982
).41.
F. G.
Abdullaev
and R. T.
Akhundov
, Izv. Vyssh. Uchebn. Zaved., Neft Gaz.
28
, 64
(1983
).42.
S.
Oswal
and M. V.
Rathnam
, Can. J. Chem.
62
, 2851
(1984
).43.
F. G.
Abdullaev
and T. S.
Akhundov
, Izv. Vyssh. Uchebn. Zaved., Neft Gaz.
28
, 52
(1985
).44.
S. F.
Al-Madfai
, A. M.
Awwad
, and K. A.
Jbara
, Thermochim. Acta
84
, 33
(1985
).45.
S. L.
Plaskunova
, I. M.
Shapovalova
, and B. P.
Serebryakov
, Azerb. Khim. Zh.
96
, 9
(1986
).46.
R. K.
Dewan
, C. M.
Gupta
, and S. K.
Mehta
, Z. Phys. Chem.
160
, 221
(1988
).47.
M.
Fermeglia
and R.
Lapasin
, J. Chem. Eng. Data
33
, 415
(1988
).48.
M. C. S.
Subha
and S. B.
Rao
, J. Chem. Eng. Data
33
, 404
(1988
).49.
V. K.
Rattan
, B. P. S.
Sethi
, S.
Singh
, and H.
Kaur
, Z. Phys. Chem.
162
, 47
(1989
).50.
R. P.
Singh
, C. P.
Sinha
, J. C.
Das
, and P.
Ghosh
, J. Chem. Eng. Data
34
, 335
(1989
).51.
A. F. A.
Asfour
, M. H.
Siddique
, and T. D.
Vavanellos
, J. Chem. Eng. Data
35
, 199
(1990
).52.
A.
Schumpe
and P.
Luhring
, J. Chem. Eng. Data
35
, 24
(1990
).53.
T. D.
Vavanellos
, A. F. A.
Asfour
, and M. H.
Siddique
, J. Chem. Eng. Data
36
, 281
(1991
).54.
U. G.
Krahn
and G.
Luft
, J. Chem. Eng. Data
39
, 670
(1994
).55.
G. S.
Chen
, Y. J.
Hou
, and H.
Knapp
, J. Chem. Eng. Data
40
, 1005
(1995
).56.
R. S.
Ramadevi
, P.
Venkatesu
, and M. V. P.
Rao
, J. Chem. Eng. Data
41
, 479
(1996
).57.
A. H.
Nhaesi
and A. F. A.
Asfour
, J. Chem. Eng. Data
45
, 991
(2000
).58.
J.
George
and N. V.
Sastry
, J. Chem. Eng. Data
48
, 977
(2003
).59.
R. C.
Katyal
, S.
Singh
, V. K.
Rattan
, P.
Kanda
, and S.
Acharya
, J. Chem. Eng. Data
48
, 1262
(2003
).60.
B. S.
Lark
, M.
Mehra
, S. L.
Oswal
, and N. Y.
Ghael
, Int. J. Thermophys
24
, 1475
(2003
).61.
S. L.
Oswal
, M. M.
Maisuria
, and R. L.
Gardas
, J. Mol. Liq.
108
, 199
(2003
).62.
S. L.
Oswal
, J. S.
Desai
, and S. P.
Ijardar
, Thermochim. Acta
423
, 29
(2004
).63.
V. K.
Rattan
, S.
Singh
, and B. P. S.
Sethi
, J. Chem. Eng. Data
49
, 1074
(2004
).64.
C. S.
Yang
, P. S.
Ma
, and Q.
Zhou
, J. Chem. Eng. Data
49
, 881
(2004
).65.
66.
G.
Knothe
and K. R.
Steidley
, Fuel
84
, 1059
(2005
).67.
A. H.
Nhaesi
and A. F. A.
Asfour
, J. Chem. Eng. Data
50
, 149
(2005
).68.
M. V.
Rathnam
, S.
Mohite
, and M. S. S.
Kumar
, J. Chem. Eng. Data
50
, 325
(2005
).69.
C. S.
Yang
, W. L.
Yu
, and P. S.
Ma
, J. Chem. Eng. Data
50
, 1197
(2005
).70.
W. A.
Al-Gherwi
, A. H.
Nhaesi
, and A. F. A.
Asfour
, J. Solution Chem.
35
, 455
(2006
).71.
J. A.
Al-Kandary
, A. S.
Al-Jimaz
, and A. H. M.
Abdul-Latif
, J. Chem. Eng. Data
51
, 99
(2006
).72.
R.
Baskaran
and T. R.
Kubendran
, J. Chem. Eng. Data
53
, 1956
(2008
).73.
C. Y.
Song
, H. Z.
Shen
, J. H.
Zhao
, L. C.
Wang
, and F. A.
Wang
, J. Chem. Eng. Data
53
, 1110
(2008
).74.
D.
Wankhede
, N.
Wankhede
, M.
Lande
, and B.
Arbad
, Phys. Chem. Liq.
46
, 319
(2008
).75.
M.
Dominguez-Perez
, C.
Franjo
, J.
Pico
, L.
Segade
, O.
Cabeza
, and E.
Jimenez
, Int. J. Thermophys.
30
, 1197
(2009
).76.
H. E. M.
El-Sayed
and A. F. A.
Asfour
, Int. J. Thermophys
30
, 1773
(2009
).77.
M. V.
Rathnam
, S.
Mohite
, and M. S.
Kumar
, J. Chem. Eng. Data
54
, 305
(2009
).78.
H.
Ikeuchi
, M.
Kanakubo
, S.
Okuno
, R.
Sato
, K.
Fujita
, M.
Hamada
, N.
Shoda
, K.
Fukui
, K.
Okada
, H.
Kanazawa
, A.
Iimori
, D.
Miyake
, T.
Takeda
, and G. P.
Sato
, J. Solution Chem.
39
, 1428
(2010
).79.
M. V.
Rathnam
, S.
Mohite
, and M. S. S.
Kumar
, J. Solution Chem.
39
, 1735
(2010
).80.
S. C.
Bhatia
, R.
Rani
, and R.
Bhatia
, J. Mol. Liq.
159
, 132
(2011
).81.
M.
Hasan
, A. B.
Sawant
, R. B.
Sawant
, and P. G.
Loke
, J. Chem. Thermodyn.
43
, 1389
(2011
).82.
M. V.
Rathnam
, S.
Mohite
, and M. S. S.
Kumar
, J. Solution Chem.
40
, 390
(2011
).83.
K.
Saravanakumar
, T. G.
Lavanya
, R.
Baskaran
, and T. R.
Kubendran
, Russ. J. Phys. Chem. A
86
, 568
(2012
).84.
E. W.
Barega
, E.
Zondervan
, and A. B.
de Haan
, J. Chem. Thermodyn.
63
, 31
(2013
).85.
H. E. M.
El-Sayed
and A. F. A.
Asfour
, J. Solution Chem.
42
, 136
(2013
).86.
D. J. L.
Prak
, J. S.
Cowart
, A. M.
McDaniel
, and P. C.
Trulove
, J. Chem. Eng. Data
59
, 3571
(2014
).87.
X. Y.
Meng
, X. Y.
Gu
, J. T.
Wu
, and V.
Vesovic
, J. Chem. Thermodyn.
95
, 116
(2016
).88.
I. F.
Golubev
, Viscosity of Gases and Gas Mixtures
(Israel Program for Scientific Translation
, 1970
).89.
NIST Standard Reference Database 85 NIST/TRC Table database Win Table, version 2003, National Institute of Standards and Technology, Gaithersburg, MD, 2003.
90.
M. J.
Assael
, M. L. V.
Ramires
, C. A.
Nieto de Castro
, and W. A.
Wakeham
, J. Phys. Chem. Ref. Data
19
, 113
(1990
).91.
T.
Jia
, F.
Cao
, and X.
Meng
, private communication.92.
Transport Properties of Fluids: Their Correlation Prediction and Estimation
, edited byJ.
Millat
, J. H.
Dymond
, and C. A.
Nieto de Castro
(Cambridge University Press
, Cambridge, UK
, 1996
).93.
E.
Vogel
and S.
Hendl
, Fluid Phase Equilib.
79
, 313
(1992
).94.
Experimental Thermodynamics Series Advances in Transport Properties
, edited by M. J.
Assael
, A. R. H.
Goodwin
, V.
Vesovic
, and W. A.
Wakeham
(The Royal Society of Chemistry
, Cambridge
, 2014
), Vol. IX
.95.
J. H.
Dymond
, N. F.
Glen
, and J. D.
Isdale
, Int. J. Thermophys.
6
, 233
(1986
).96.
S. K.
Mylona
, M. J.
Assael
, M. J. P.
Comuñas
, X.
Paredes
, F. M.
Gaciño
, J.
Fernández
, J. P.
Bazile
, C.
Boned
, J. L.
Daridon
, G.
Galliero
, J.
Pauly
, and K. R.
Harris
, J. Phys. Chem. Ref. Data
43
, 013104
(2014
).97.
T. S.
Akhundov
, S. M.
Ismail-Zade
, and A. D.
Tairov
, Izv. Vyssh. Uchebn. Zaved., Neft Gaz.
2
, 79
(1970
).98.
R. T.
Akhundov
, F. G.
Abdullaev
, and M. G.
Ramazanzade
, Izv. Vyssh. Uchebn. Zaved., Neft Gaz.
28
, 53
(1983
).99.
M. J.
Assael
, J. H.
Dymond
, M.
Papadaki
, and P. M.
Patterson
, Int. J. Thermophys.
13
, 269
(1992
).100.
F.
Ciota
, J. P. M.
Trusler
, and V.
Vesovic
, Fluid Phase Equilib.
363
, 239
(2014
).101.
1stOpt (First Optimization) V.1.5, 7D-Soft High Technology, Inc., Beijing, People’s Republic of China.
102.
V.
Vesovic
and W. A.
Wakeham
, Chem. Eng. Sci.
44
, 2181
(1989
).103.
D.
Royal
, V.
Vesovic
, J. P. M.
Trusler
, and W. A.
Wakeham
, Mol. Phys.
101
, 339
(2003
).104.
A. S.
de Wijn
, N.
Riesco
, G.
Jackson
, J. P. M.
Trusler
, and V.
Vesovic
, J. Chem. Phys.
136
, 074514
(2012
).105.
A. M.
Mamedov
, T. S.
Akhundov
, and A. D.
Tairov
, Izv. Akad. Nauka Azerb. SSR Seriia
3
, 66
(1968
).106.
107.
A. M.
Mamedov
, T. S.
Akhundov
, and A. D.
Tairov
, Razrab. Neft. Gazov. Mestorozhd.
225
(1975
).108.
J. H.
Dymond
and J.
Robertson
, Int. J. Thermophys.
6
, 21
(1985
).109.
L.
Serrano
, J. A.
Silva
, and F.
Favelo
, J. Chem. Eng. Data
35
, 288
(1990
).110.
A.
Et-Tahir
, C.
Boned
, B.
Lagourette
, and P.
Xans
, Int. J. Thermophys.
16
, 1309
(1995
).111.
N. C.
Exarchos
, M.
Tasioula-Margari
, and I. N.
Demetropoulos
, J. Chem. Eng. Data
40
, 567
(1995
).© 2017 AIP Publishing LLC for the National Institute of Standards and Technology.
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