The mutual solubilities and related liquid–liquid equilibria for 37 ternary systems of C1–C3 alcohols with aliphatic hydrocarbons and water are exhaustively and critically reviewed. Reports of experimental determination of solubility that appeared in the primary literature prior to the end of 2012 are compiled. For 14 systems, sufficient data are available (two or more independent determinations) to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, an additional criterion was used for each of the evaluated systems. These systems include one binary miscibility gap in the hydrocarbon + water subsystem and another one can be in the methanol + hydrocarbon subsystem. The binary tie lines were compared with the recommended values published previously.
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September 2016
Research Article|
July 25 2016
IUPAC-NIST Solubility Data Series. 101. Alcohols + Hydrocarbons + Water. Part 2. C1–C3 Alcohols + Aliphatic Hydrocarbons Available to Purchase
Special Collection:
Solubility Reference Data Collection
Paweł Oracz;
Paweł Oracz
a)
Faculty of Chemistry,
Warsaw University
, 02-093 Warsaw, Poland
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Marian Góral;
Marian Góral
b)
Institute of Physical Chemistry,
Polish Academy of Sciences
, 01-224 Warsaw, Poland
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Barbara Wiśniewska-Gocłowska;
Barbara Wiśniewska-Gocłowska
c)
Institute of Physical Chemistry,
Polish Academy of Sciences
, 01-224 Warsaw, Poland
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David G. Shaw;
David G. Shaw
d)
Department of Chemistry,
University of Alaska
, Fairbanks, Alaska 99775, USA
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Andrzej Mączyński
Andrzej Mączyński
e)
Institute of Physical Chemistry,
Polish Academy of Sciences
, 01-224 Warsaw, Poland
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Paweł Oracz
a)
Faculty of Chemistry,
Warsaw University
, 02-093 Warsaw, Poland
Marian Góral
b)
Institute of Physical Chemistry,
Polish Academy of Sciences
, 01-224 Warsaw, Poland
Barbara Wiśniewska-Gocłowska
c)
Institute of Physical Chemistry,
Polish Academy of Sciences
, 01-224 Warsaw, Poland
David G. Shaw
d)
Department of Chemistry,
University of Alaska
, Fairbanks, Alaska 99775, USA
Andrzej Mączyński
e)
Institute of Physical Chemistry,
Polish Academy of Sciences
, 01-224 Warsaw, Poland
a)
Electronic mail: [email protected]
b)
Electronic mail: [email protected]
c)
Electronic mail: [email protected]
d)
Electronic mail: [email protected]
e)
Electronic mail: [email protected]
J. Phys. Chem. Ref. Data 45, 033102 (2016)
Article history
Received:
June 09 2016
Accepted:
June 13 2016
Connected Content
A companion article has been published:
IUPAC-NIST Solubility Data Series. 101. Alcohols + Hydrocarbons + Water Part 3. C1–C3 Alcohols + Aromatic Hydrocarbons
Citation
Paweł Oracz, Marian Góral, Barbara Wiśniewska-Gocłowska, David G. Shaw, Andrzej Mączyński; IUPAC-NIST Solubility Data Series. 101. Alcohols + Hydrocarbons + Water. Part 2. C1–C3 Alcohols + Aliphatic Hydrocarbons. J. Phys. Chem. Ref. Data 1 September 2016; 45 (3): 033102. https://doi.org/10.1063/1.4954793
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