This is the third part of the volume devoted to solubility data for the rare earth metal (REM) fluorides in water and in aqueous ternary and multicomponent systems. It covers experimental results of trivalent fluorides of Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu (so-called heavy lanthanides), since no quantitative data on solubilities of TbF4 and YbF2 (the most stable compounds at these valencies) are available. The related literature has been covered through the end of 2014. Compilations of all available papers with the solubility data are introduced for each REM fluoride with a corresponding critical evaluation. Every such assessment contains a collection of all solubility results in aqueous solution, a selection of suggested solubility data, a solubility equation, and a brief discussion of the multicomponent systems. Only simple fluorides (no complexes or double salts) are treated as the input substances in this report. General features of the systems, such as nature of the equilibrium solid phases, solubility as a function of temperature, influence of ionic strength, solution pH, mixed solvent medium on the solubility, quality of the solubility results, and the solubility as a function of REM atomic number, have already been presented in Part 1 of the volume.
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June 2015
Research Article|
June 08 2015
IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 3. Heavy Lanthanides (Gd–Lu) Available to Purchase
Special Collection:
Solubility Reference Data Collection
Tomasz Mioduski;
Tomasz Mioduski
a)
Institute of Nuclear Chemistry and Technology
, 03195 Warszawa, Poland
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Cezary Gumiński;
Cezary Gumiński
b)
Department of Chemistry,
University of Warsaw
, 02093 Warszawa, Poland
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Dewen Zeng
Dewen Zeng
c)
College of Chemistry and Chemical Engineering,
Central South University
, Changsha 410083, People’s Republic of China
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Tomasz Mioduski
a)
Institute of Nuclear Chemistry and Technology
, 03195 Warszawa, Poland
Cezary Gumiński
b)
Department of Chemistry,
University of Warsaw
, 02093 Warszawa, Poland
Dewen Zeng
c)
College of Chemistry and Chemical Engineering,
Central South University
, Changsha 410083, People’s Republic of China
J. Phys. Chem. Ref. Data 44, 023102 (2015)
Article history
Received:
March 26 2015
Accepted:
March 27 2015
Citation
Tomasz Mioduski, Cezary Gumiński, Dewen Zeng; IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 3. Heavy Lanthanides (Gd–Lu). J. Phys. Chem. Ref. Data 1 June 2015; 44 (2): 023102. https://doi.org/10.1063/1.4918371
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