This is the second part of the volume devoted to the evaluation of experimental solubility data for rare earth metal (REM) fluorides in water as well as in aqueous ternary and multicomponent systems. Fluorides of Ce, Pr, Nd, Pm, Sm, and Eu (so-called light lanthanides), as the main solutes, are covered in the present part, which has thorough coverage of the experimental literature through the end of 2012. The experimentally unknown solubility value for PmF3 in water was predicted by an interpolation of the solubility values for NdF3 and SmF3 at 298 K. General features of the systems, such as the nature of the equilibrium solid phases, solubility as a function of temperature, influence of ionic strength, pH, mixed solvent medium on the solubility, quality of the solubility results, and solubility as a function of REM atomic number, have already been presented in Part 1 of the volume.
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March 2015
Research Article|
January 30 2015
IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 2. Light Lanthanides (Ce–Eu) Available to Purchase
Special Collection:
Solubility Reference Data Collection
Tomasz Mioduski;
Tomasz Mioduski
a)
Institute of Nuclear Chemistry and Technology
, Warsaw 03195, Poland
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Cezary Gumiński;
Cezary Gumiński
b)
Department of Chemistry,
University of Warsaw
, Warsaw 02093, Poland
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Dewen Zeng
Dewen Zeng
c)
College of Chemistry and Chemical Engineering,
Central South University
, Changsha 410083, People’s Republic of China
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Tomasz Mioduski
a)
Institute of Nuclear Chemistry and Technology
, Warsaw 03195, Poland
Cezary Gumiński
b)
Department of Chemistry,
University of Warsaw
, Warsaw 02093, Poland
Dewen Zeng
c)
College of Chemistry and Chemical Engineering,
Central South University
, Changsha 410083, People’s Republic of China
J. Phys. Chem. Ref. Data 44, 013102 (2015)
Article history
Received:
October 21 2014
Accepted:
October 27 2014
Citation
Tomasz Mioduski, Cezary Gumiński, Dewen Zeng; IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 2. Light Lanthanides (Ce–Eu). J. Phys. Chem. Ref. Data 1 March 2015; 44 (1): 013102. https://doi.org/10.1063/1.4903362
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