The data on thermodynamic and molecular properties of the potassium, rubidium and cesium hydroxides have been collected, critically reviewed, analyzed, and evaluated. Tables of the thermodynamic properties , −(0), , of these hydroxides in the condensed and gaseous states have been calculated using the results of the analysis and some estimated values. The recommendations are compared with earlier evaluations given in the JANAF Thermochemical Tables and Thermodynamic Properties of Individual Substances. The properties considered are: the temperature and enthalpy of phase transitions and fusion, heat capacities, spectroscopic data, structures, bond energies, and enthalpies of formation at 298.15 K. The thermodynamic functions in solid, liquid, and gaseous states are calculated from =0 to 2000 K for substances in condensed phase and up to 6000 K for gases.
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July 1997
Research Article|
July 01 1997
Thermodynamic Properties of Alkali Metal Hydroxides. Part II. Potassium, Rubidium, and Cesium Hydroxides
L. V. Gurvich;
L. V. Gurvich
Thermocenter of the Russian Academy of Sciences, Izhorskaya st. 13/19, IVTAN, Moscow 127412, Russia
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G. A. Bergman;
G. A. Bergman
Thermocenter of the Russian Academy of Sciences, Izhorskaya st. 13/19, IVTAN, Moscow 127412, Russia
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L. N. Gorokhov;
L. N. Gorokhov
Thermocenter of the Russian Academy of Sciences, Izhorskaya st. 13/19, IVTAN, Moscow 127412, Russia
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V. S. Iorish;
V. S. Iorish
Thermocenter of the Russian Academy of Sciences, Izhorskaya st. 13/19, IVTAN, Moscow 127412, Russia
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V. Ya. Leonidov;
V. Ya. Leonidov
Thermocenter of the Russian Academy of Sciences, Izhorskaya st. 13/19, IVTAN, Moscow 127412, Russia
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V. S. Yungman
V. S. Yungman
Thermocenter of the Russian Academy of Sciences, Izhorskaya st. 13/19, IVTAN, Moscow 127412, Russia
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J. Phys. Chem. Ref. Data 26, 1031–1110 (1997)
Article history
Received:
July 21 1995
Citation
L. V. Gurvich, G. A. Bergman, L. N. Gorokhov, V. S. Iorish, V. Ya. Leonidov, V. S. Yungman; Thermodynamic Properties of Alkali Metal Hydroxides. Part II. Potassium, Rubidium, and Cesium Hydroxides. J. Phys. Chem. Ref. Data 1 July 1997; 26 (4): 1031–1110. https://doi.org/10.1063/1.555996
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