The data on thermodynamic and molecular properties of the lithium and sodium hydroxides have been collected, critically reviewed, analyzed, and evaluated. Tables of thermodynamic properties (C°p,Φ°=−(G°−H°(0)/T, S°, H°−H°(0), ΔfH°, ΔfG°) of these hydroxides in the condensed and gaseous states have been calculated using the results of the analysis and some estimated values. The recommendations are compared with earlier evaluations given in the JANAF Thermochemical Tables and Thermodynamic Properties of Individual Substances. The properties considered are: the temperature and enthalpy of phase transitions and fusion, heat capacities, spectroscopic data, structures, bond energies, and enthalpies of formation at 298.15 K. The thermodynamic functions in solid, liquid, and gaseous states are calculated from T=0 to 2000 K for substances in condensed phase and up to 6000 K for gases.
Skip Nav Destination
Article navigation
July 1996
Research Article|
July 01 1996
Thermodynamic Properties of Alkali Metal Hydroxides. Part 1. Lithium and Sodium Hydroxides
L. V. Gurvich;
L. V. Gurvich
Thermocenter of the Russian Academy of Sciences, Izhorskaya st. 13/19, IVTAN, Moscow, 127412, Russia
Search for other works by this author on:
G. A. Bergman;
G. A. Bergman
Thermocenter of the Russian Academy of Sciences, Izhorskaya st. 13/19, IVTAN, Moscow, 127412, Russia
Search for other works by this author on:
L. N. Gorokhov;
L. N. Gorokhov
Thermocenter of the Russian Academy of Sciences, Izhorskaya st. 13/19, IVTAN, Moscow, 127412, Russia
Search for other works by this author on:
V. S. Iorish;
V. S. Iorish
Thermocenter of the Russian Academy of Sciences, Izhorskaya st. 13/19, IVTAN, Moscow, 127412, Russia
Search for other works by this author on:
V. Ya. Leonidov;
V. Ya. Leonidov
Thermocenter of the Russian Academy of Sciences, Izhorskaya st. 13/19, IVTAN, Moscow, 127412, Russia
Search for other works by this author on:
V. S. Yungman
V. S. Yungman
Thermocenter of the Russian Academy of Sciences, Izhorskaya st. 13/19, IVTAN, Moscow, 127412, Russia
Search for other works by this author on:
J. Phys. Chem. Ref. Data 25, 1211–1276 (1996)
Article history
Received:
November 03 1993
Received:
November 30 1995
Citation
L. V. Gurvich, G. A. Bergman, L. N. Gorokhov, V. S. Iorish, V. Ya. Leonidov, V. S. Yungman; Thermodynamic Properties of Alkali Metal Hydroxides. Part 1. Lithium and Sodium Hydroxides. J. Phys. Chem. Ref. Data 1 July 1996; 25 (4): 1211–1276. https://doi.org/10.1063/1.555982
Download citation file:
Pay-Per-View Access
$40.00
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Citing articles via
Ab Initio Calculation of Fluid Properties for Precision Metrology
Giovanni Garberoglio, Christof Gaiser, et al.
Evaluation of Physicochemical Property Data in the ECHA Database
Juliane Glüge, Martin Scheringer
Survey of Hyperfine Structure Measurements in Alkali Atoms
Maria Allegrini, Ennio Arimondo, et al.
Related Content
Thermodynamic Properties of Alkali Metal Hydroxides. Part II. Potassium, Rubidium, and Cesium Hydroxides
J. Phys. Chem. Ref. Data (July 1997)
Lithium hydroxide, LiOH, at elevated densities
J. Chem. Phys. (July 2014)
CO 2 capture properties of alkaline earth metal oxides and hydroxides: A combined density functional theory and lattice phonon dynamics study
J. Chem. Phys. (August 2010)
Magnetic phenomena in Co-containing layered double hydroxides
Low Temp. Phys. (August 2017)
Density functional theory study of CO2 capture with transition metal oxides and hydroxides
J. Chem. Phys. (February 2012)