Chemical kinetic data for reactions of O(3P) atoms with sulfur containing compounds are compiled and critically evaluated. Specifically, the reactions considered include the interactions of the ground electronic state of oxygen atoms, O(3P), with S2, SF2, SF5, SOF, S2O, SO, SO2, SO3, SH, H2S, D2S, H2SO4, CS, CS2, COS, CH3SH, C2H5SH, C4H9SH, C5H11SH, CH3SCH3, cy‐CH2SCH2, cy‐CHCHSCHCH, CH3SSCH3, SCF2, SCCl2, and cy‐CF2SCF2S. With one exception, the liquid phase reaction O(3P)+H2SO4→products, all the data considered were for gas phase reactions. Where possible, ‘‘Recommended’’ values of the rate parameters have been assessed and conservative uncertainty limits assigned to them.
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© 1988 American Institute of Physics for the National Institute of Standards and Technology.
1988
American Institute of Physics for the National Institute of Standards and Technology
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