Evaluated Chemical Kinetic Data for the Reactions of Atomic Oxygen O(³P) with Sulfur Containing Compounds

Chemical kinetic data for reactions of O(³P) atoms with sulfur containing compounds are compiled and critically evaluated. Specifically, the reactions considered include the interactions of the ground electronic state of oxygen atoms, O(³P), with S₂, SF₂, SF₅, SOF, S₂O, SO, SO₂, SO₃, SH, H₂S, D₂S, H₂SO₄, CS, CS₂, COS, CH₃SH, C₂H₅SH, C₄H₉SH, C₅H₁₁SH, CH₃SCH₃, cy‐CH₂SCH₂, cy‐CHCHSCHCH, CH₃SSCH₃, SCF₂, SCCl₂, and cy‐CF₂SCF₂S. With one exception, the liquid phase reaction O(³P)+H₂SO₄→products, all the data considered were for gas phase reactions. Where possible, ‘‘Recommended’’ values of the rate parameters have been assessed and conservative uncertainty limits assigned to them.